Logarithmic based optical delay for time-resolved data collection.

A method has been established that generates values spaced according to a mathematical function, specifically the logarithm function that can be applied to a stepper motor. Here, it is applied to yield logarithmically spaced time delay points for subnanosecond interferometric time-resolved experiments using a stepper motor controlled translation stage. Application of this method is discussed in terms of three input parameters: the optical delay stage time resolution, dt; the time of maximum delay, d(stop); and the desired number of data points, N. The method improves the efficiency of interferometric time-resolved data collection while providing data collection effective to determine decay parameters. In principle, this technique could be generalized to any mathematical function.

[1]  P. R. Bevington,et al.  Data Reduction and Error Analysis for the Physical Sciences , 1969 .

[2]  S O Reza Moheimani,et al.  Invited review article: accurate and fast nanopositioning with piezoelectric tube scanners: emerging trends and future challenges. , 2008, The Review of scientific instruments.

[3]  A. Goun,et al.  Deprotonation dynamics and stokes shift of pyranine (HPTS). , 2007, The journal of physical chemistry. A.

[4]  U. Keller Recent developments in compact ultrafast lasers , 2003, Nature.

[5]  Charles G. Durfee,et al.  High power ultrafast lasers , 1998 .

[6]  Bin Liu,et al.  Single-wafer-processed nano-positioning XY-stages with trench-sidewall micromachining technology , 2006 .

[7]  D. Huppert,et al.  Excited-state proton transfer: indication of three steps in the dissociation and recombination process. , 2005, The journal of physical chemistry. A.

[8]  O. Kel,et al.  Site-dependent excited-state dynamics of a fluorescent probe bound to avidin and streptavidin. , 2009, Chemphyschem : a European journal of chemical physics and physical chemistry.

[9]  P. Bucksbaum,et al.  The Future of Attosecond Spectroscopy , 2007, Science.

[10]  Graham R. Fleming,et al.  Chemical applications of ultrafast spectroscopy , 1986 .

[11]  R. S. Coleman,et al.  Complex local dynamics in DNA on the picosecond and nanosecond time scales. , 2002, Physical review letters.

[12]  M. Kling,et al.  Attosecond electron dynamics. , 2008, Annual review of physical chemistry.

[13]  M. Maroncelli,et al.  Subpicosecond Measurements of Polar Solvation Dynamics: Coumarin 153 Revisited , 1995 .