ARAMIDS: ‘Disruptive’, open and continuous innovation

Abstract Aramids, sometimes associated with serendipity or an accidental discovery, are definitely to be recognised as a major disruptive innovation, now celebrating the 50th anniversary of its originating branded product. Open innovation was unavoidably promoted by the success of a broad range of applications where the aramids gave a new dimension to novel and/or improved designs insuring protection of people and of the environment, as well as of strategic equipment and settings. Transport and fossil energy preservation are also key areas which aramids are serving tremendously. The large breadth of applications and the blendability of the materials based on aramids have made them attractive either for smaller entertaining applications, such as music, or indispensable replacements, such as asbestos elimination, a welcome health contribution. Definitely in phase with smarter, bigger data and crowd sourcing approaches, aramids provide durable solutions and take part in the current industry trends; in the aeronautical and automotive new modular manufacturing for instance. Not only sometimes the best replacement of, aramids are often the most suitable partners of, harmonising well with steel and carbon or glass for examples. From chemistry to process, from improved applications to future innovations and from classic implementation to Collaboratory® developmental networks, this refreshed chapter covers the aforementioned attributes and impacts of aramids. Keeping in mind an educational focus, a dominantly illustrative and intuitively provocative approach is adopted. The systems engineering and supporting rational are taken into account. A large selection of foundation references is used and additional new ones are provided for reflection and creativity incitation purposes. Biomimicry and bigger data analyses are introduced as new dimensions which such high-performance materials are enticing.

[1]  S. Rebouillat,et al.  Characterization of KEVLAR fibers using selected probes , 1995 .

[2]  L. Treloar High-modulus wholly aromatic fibres: Edited by W. B. Black and J. Preston Marcel Dekker, New York, 1973. $22.50 , 1974 .

[3]  Loic Dussud,et al.  Mechanical behaviour of HMPE and aramid fibre ropes for deep sea handling operations , 2011 .

[4]  Young Gyu Jeong,et al.  Microstructure and performance of multiwalled carbon nanotube/m-aramid composite films as electric heating elements. , 2013, ACS applied materials & interfaces.

[5]  P. Flory Statistical Thermodynamics of Mixtures of Rodlike Particles. 6. Rods Connected by Flexible Joints , 1978 .

[6]  P. Flory,et al.  Statistical Thermodynamics of Mixtures of Rodlike Particles. 2. Ternary Systems , 1978 .

[7]  J. Donnet,et al.  Surface energy mapping of Kevlar® fibers by inverse gas chromatography , 1998 .

[8]  Development and characterization of fatigue resistant Aramid reinforced aluminium laminates (ARALL) for fatigue Critical aircraft components , 2014 .

[9]  Serge Rebouillat,et al.  Bio-inspired and Bio-inspiration: a Disruptive Innovation Opportunity or a Matter of "Semantic"? A Review of a "stronger than logic" Creative Path based on Curiosity and Confidence (4C22C©) , 2014 .

[10]  S. Olson,et al.  Thermal response characteristics of fire blanket materials , 2014 .

[11]  Kerim Duran,et al.  PROTECTIVE NONWOVEN TECHNICAL TEXTILES , 2007 .

[12]  B. Öztürk,et al.  Effects of Resin Type and Fiber Length on the Mechanical and Tribological Properties of Brake Friction Materials , 2011 .

[13]  Haoran Chen,et al.  Flexural strength and energy absorption of carbon-fiber–aluminum-honeycomb composite sandwich reinforced by aluminum grid , 2014 .

[14]  S. Rebouillat,et al.  Fluid–structure interaction in partially filled liquid containers: A comparative review of numerical approaches , 2010 .

[15]  H. Yang,et al.  Kevlar Aramid Fiber , 1993 .

[16]  D. Roylance Ballistics of Transversely Impacted Fibers , 1977 .

[17]  Werner Goldsmith,et al.  The mechanics of penetration of projectiles into targets , 1978 .

[18]  Joel Martinez-Frias,et al.  Analytical and experimental evaluation of insulated pressure vessels for cryogenic hydrogen storage , 2000 .

[19]  P. Flory Statistical Thermodynamics of Mixtures of Rodlike Particles. 5. Mixtures with Random Coils , 1978 .

[20]  P. Morgan,et al.  Poly(1,4-phenyleneterephthalamides). Polymerization and Novel Liquid-Crystalline Solutions , 1977 .

[21]  Yuanfeng Wang,et al.  Size Effect of Concrete Short Columns Confined with Aramid FRP Jackets , 2011 .

[22]  Yudong Huang,et al.  Enhanced interfacial properties of domestic aramid fiber-12 via high energy gamma ray irradiation , 2015 .

[23]  Satish Kumar Structure and properties of high-performance polymeric and carbon fibers - an overview , 1989 .

[24]  S. Ogata,et al.  Further study of polyamide synthesis by direct polycondensation reaction with triphenyl phosphite and metal salts , 1983 .

[25]  J. R. Schaefgen,et al.  Synthesis, Anisotropic Solutions, and Fibers of Poly(1,4-benzamide) , 1977 .

[26]  M. Ertekin,et al.  BURNING BEHAVIOUR AND MECHANICAL PROPERTIES OF FABRICS WOVEN WITH RING SPUN ARAMID AND FLAME RETARDANT POLYESTER YARNS , 2014 .

[27]  B. Gu,et al.  A simplified microstructure model of bi-axial warp-knitted composite for ballistic impact simulation , 2010 .

[28]  L. Allard,et al.  On the morphology of aromatic polyamide fibers (Kevlar, Kevlar-49, and PRD-49) , 1983 .

[29]  Hiroshi Ito,et al.  STUDIES ON THE FINE STRUCTURE OF POLY(P-PHENYLENE TEREPHTHALAMIDE) FIBERS , 1975 .

[30]  Han-liang Wu,et al.  Reinforced high-strength concrete square columns confined by aramid FRP jackets. part I: experimental study , 2011 .

[31]  Onur Çoban,et al.  A review: Fibre metal laminates, background, bonding types and applied test methods , 2011 .

[32]  J. Hearle,et al.  Flexural fatigue and surface abrasion of Kevlar-29 and other high-modulus fibres , 1977 .

[33]  Min Young Kim,et al.  Performance Evaluation of Protective Clothing Materials for Welding in a Hazardous Shipbuilding Industry Work Environment , 2013 .

[34]  Peter Davies,et al.  Influence of Fibre Stiffness on Deepwater Mooring Line Response , 2008 .

[35]  P. Flory Phase changes in proteins and polypeptides , 1961 .

[36]  Michael R Wisnom,et al.  Investigation of trapezoidal corrugated aramid/epoxy laminates under large tensile displacements transverse to the corrugation direction , 2010 .

[37]  P. Flory,et al.  Theory of Systems of Rodlike Particles: I. Athermal systems , 1979 .

[38]  Stanislav Kmet,et al.  Vibrations of an aramid anchor cable subjected to turbulent wind , 2014, Adv. Eng. Softw..

[39]  A. Soahib,,et al.  ANALYSIS OF CURE REACTION KINETICS OF ARAMID/TOUGHENED-EPOXY PREPREG SYSTEM AIMING AT PROCESSING OF COMPOSITE MATERIAL FOR STRUCTURAL APPLICATIONS , 2007 .

[40]  Jie Yin,et al.  Aramid nanofiber-functionalized graphene nanosheets for polymer reinforcement. , 2012, Nanoscale.

[41]  J. Donnet,et al.  Surface microstructure of a Kevlar aramid fibre studied by direct atomic force microscopy , 1997 .

[42]  S. Ul-Haq Influence of moisture on dielectric strength in polyamide (aramid) paper , 2003, 2003 Annual Report Conference on Electrical Insulation and Dielectric Phenomena.

[43]  P. Flory,et al.  Phase equilibria in solutions of rod-like particles , 1956, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[44]  H. F. Schiefer,et al.  Stress-Strain Relationships. in Yarns Subjected to Rapid Impact Loading , 1960 .

[45]  E. Roche,et al.  Light diffraction effects from Kevlar aramid fibers , 1985 .

[46]  G. Heinrich,et al.  Influence of fiber type and coating on the composite properties of EPDM compounds reinforced with short aramid fibers , 2013 .

[47]  Alastair Johnson,et al.  MODELLING THE IMPACT BEHAVIOUR OF SANDWICH STRUCTURES WITH FOLDED COMPOSITE CORES , 2014 .

[48]  Wei Huang,et al.  An experimental investigation on nonlinear behaviors of synthetic fiber ropes for deepwater moorings under cyclic loading , 2014 .

[49]  A. Rafie,et al.  High velocity impact response of Kevlar-29/epoxy and 6061-T6 aluminum laminated panels , 2013 .

[50]  R. Robson,et al.  Role of microvoids in aramid fibres , 1992, Journal of Materials Science.

[51]  A. Waas,et al.  Reactive Aramid Nanostructures as High‐Performance Polymeric Building Blocks for Advanced Composites , 2013 .

[52]  J. Schultz,et al.  Structure and property development in poly(p‐phenylene terephthalamide) during heat treatment under tension , 1995 .

[53]  A. Beukers,et al.  Optimal cross sections of filament-wound toroidal hydrogen storage vessels based on continuum lamination theory , 2010 .

[54]  Young Ha Kim,et al.  Preparation of Aromatic Polyamide Polyanions : A Novel Processing Strategy for Aromatic Polyamides , 1990 .

[55]  David Saltmarsh,et al.  Seeking to teach equitably: Australian teacher education in a globalised world , 2013 .

[56]  P. Morgan Synthesis and Properties of Aromatic and Extended Chain Polyamides , 1977 .

[57]  Xiaozhi Hu,et al.  Energy-absorption enhancement in carbon-fiber aluminum-foam sandwich structures from short aramid-fiber interfacial reinforcement , 2013 .

[58]  Soojin Park,et al.  The study of efficiency of Al2O3 drop coated electrospun meta-aramid nanofibers as separating membrane in lithium-ion secondary batteries , 2014 .

[59]  D. Stenvers,et al.  Some recent developments of rope technologies - Further enhancements of high performance ropes , 2008, OCEANS 2008.

[60]  Y. Termonia Theoretical study of the stress transfer in single fibre composites , 1987 .

[61]  S. Ogata,et al.  High‐molecular‐weight poly(p‐phenyleneterephthalamide) by the direct polycondensation reaction with triphenyl phosphite , 1982 .

[62]  Jihui Wang,et al.  Structural design and experimental investigation on filament wound toroidal pressure vessels , 2015 .

[63]  A. Patnaik,et al.  Hybrid composite friction materials reinforced with combination of potassium titanate whiskers and aramid fibre: Assessment of fade and recovery performance , 2011 .

[64]  S. R. Allen Tensile recoil measurement of compressive strength for polymeric high performance fibres , 1987 .

[65]  P. Flory,et al.  Statistical Thermodynamics of Mixtures of Rodlike Particles. 1. Theory for Polydisperse Systems , 1978 .

[66]  A. Patnaik,et al.  Performance sensitivity of hybrid phenolic composites in friction braking: Effect of ceramic and aramid fibre combination , 2010 .

[67]  F. Pla,et al.  State of the Art Manufacturing and Engineering of Nanocellulose: A Review of Available Data and Industrial Applications , 2013 .

[68]  Matthijs van Leeuwen,et al.  Endless Winding Technology for lightweight synthetic mooring lines , 2009 .

[69]  M. Karahan,et al.  An investigation into ballistic performance and energy absorption capabilities of woven aramid fabrics , 2008 .

[70]  S. Peters Handbook of Composites , 1998 .

[71]  C. Y. Tham,et al.  Ballistic impact of a KEVLAR® helmet: Experiment and simulations , 2008 .

[72]  A. Isihara Theory of Anisotropic Colloidal Solutions , 1951 .

[73]  J. Preston,et al.  Preparation of poly amides via the phosphorylation reaction. I. Wholly aromatic polyamides and polyamide‐hydrazides , 2007 .

[74]  N. Du,et al.  Study on Properties of Pressure Vessels Based on CF/AF Hybrid Fiber Reinforced Epoxy Composites , 2006 .

[75]  James W. Lyons,et al.  Impact Phenomena in Textiles , 1963 .

[76]  A. Tokarev,et al.  Russian aramid fibres: past − present − future* , 2013, Fibre Chemistry.

[77]  Bhavani V. Sankar,et al.  Relation between Interfacial Fracture Toughness and Mode-mixity in Honeycomb Core Sandwich Composites , 2006 .

[78]  Yicheng Du,et al.  Light-weight honeycomb core sandwich panels containing biofiber-reinforced thermoset polymer composite skins: Fabrication and evaluation , 2012 .

[79]  S. Ozawa A New Approach to High Modulus, High Tenacity Fibers , 1987 .

[80]  Z. Stempien Effect of Velocity of the Structure-Dependent Tension Wave Propagation on Ballistic Performance of Aramid Woven Fabricslication , 2011 .

[81]  Alastair Johnson,et al.  Prediction of impact damage on sandwich composite panels , 2005 .

[82]  Ho Jang,et al.  Synergistic effects of aramid pulp and potassium titanate whiskers in the automotive friction material , 2001 .

[83]  K. B. Mertes,et al.  Strategy for the synthesis of unsymmetrical N-substituted polyazamacrocycles , 1989 .

[84]  J. Donnet,et al.  Surface structure of Kevlar® fiber studied by atomic force microscopy and inverse gas chromatography , 1999 .

[85]  H. Kawai,et al.  Moisture Sorption Mechanism of Aromatic Polyamide Fibers: Stoichiometry of the Water Sorbed in Poly(para-phenylene Terephthalamide ) Fibers1 , 1991 .

[86]  Alexis Faure,et al.  Dynamic effects of a 9 mm missile on cadaveric skull protected by aramid, polyethylene or aluminum plate: an experimental study. , 2004, The Journal of trauma.

[87]  Duane S. Cronin,et al.  Ballistic impact response of laminated composite panels , 2008 .

[88]  T. Vu-khanh,et al.  Photochemical aging of an e-PTFE/NOMEX® membrane used in firefighter protective clothing , 2013 .

[89]  S. Rebouillat,et al.  Aramid, steel, and glass: characterization via cut performance testing, of composite knitted fabrics and their constituent yarns, with a review of the art , 2010 .

[90]  F. Higashi,et al.  High‐molecular‐weight polyterephthalamide by direct polycondensation reaction in the presence of poly(ethylene oxide) , 1980 .

[91]  Paul W. Morgan,et al.  Condensation polymers: by interfacial and solution methods , 1965 .

[92]  L. Onsager THE EFFECTS OF SHAPE ON THE INTERACTION OF COLLOIDAL PARTICLES , 1949 .

[93]  J. Preston,et al.  Preparation of polyamides via the phosphorylation reaction. II. Modification of wholly aromatic polyamides with trifunctional monomers , 1979 .

[94]  W. Pringle Mono-acylation of piperazine and homopiperazine via ionic immobilization , 2008 .

[95]  Statistical Mechanics Of Chain Molecules , 1970 .

[96]  M. Northolt Tensile deformation of poly(p-phenylene terephthalamide) fibres, an experimental and theoretical analysis , 1980 .

[97]  S. Rebouillat,et al.  New experimental device to test the dynamic behavior of fiber assemblies and fibrous composite structures with a focus on larger industrial‐scale‐like samples , 2012 .

[98]  J. J. Aartsen,et al.  Chain orientation distribution and elastic properties of poly (p‐phenylene terephthalamide), a “rigid rod” polymer , 2007 .

[99]  Jennifer Markarian Strengthening compounds through fibre reinforcement , 2007 .

[100]  A. Çavdar Investigation of freeze–thaw effects on mechanical properties of fiber reinforced cement mortars , 2014 .

[101]  R. Porter,et al.  The Strength and stiffness of polymers , 1983 .

[102]  H. N. Garden Use of advanced composites in civil engineering infrastructure , 2004 .

[103]  P. Flory Molecular theory of liquid crystals , 1984 .

[104]  M. Northolt X-ray diffraction study of poly(p-phenylene terephthalamide) fibres , 1974 .

[105]  Christian Boller,et al.  Performance of SMA-reinforced composites in an aerodynamic profile , 2002, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[106]  S. Bourbigot,et al.  Progress in safety, flame retardant textiles and flexible fire barriers for seats in transportation , 2005 .

[107]  N. Yamazaki,et al.  Studies on reactions of the N-phosphonium salts of pyridines—VII , 1974 .

[108]  T. Chiao,et al.  Chemical characterization of a high-performance organic fibre , 1976 .

[109]  T. Mower Sheave-bending and tensile fatigue of aramid-fiber strength members for communications cables , 2000 .

[110]  H. Yang Aromatic High-Strength Fibers , 1989 .

[111]  D. J. Johnson,et al.  Lattice resolution in an electron-beam sensitive polymer , 1975, Nature.

[112]  J. Bijwe,et al.  Potential exploration of novel green resins as binders for NAO friction composites in severe operating conditions , 2009 .

[113]  T. Kang,et al.  Independent environmental effects on durability of fiber-reinforced polymer wraps in civil applications: A review , 2013 .

[114]  R. S. Frost,et al.  Statistical Thermodynamics of Mixtures of Rodlike Particles. 3. The Most Probable Distribution , 1978 .

[115]  R. Young Monitoring Deformation Processes in High-performance Fibres using Raman Spectroscopy , 1995 .

[116]  D. Chase,et al.  Dynamic structure and aqueous accessibility of poly(p-phenylene terephthalamide) crystallites , 1994 .

[117]  Richard J. Farris,et al.  A modeling and experimental study of the influence of twist on the mechanical properties of high‐performance fiber yarns , 2000 .

[118]  Wei Huang,et al.  Modeling nonlinear creep and recovery behaviors of synthetic fiber ropes for deepwater moorings , 2013 .

[119]  Damien Lapray,et al.  "Bigger Data" Visualization to Visual Analytics: a path to Innovation. "Happening, definitely! Misleading, possibly?" A review of some examples applicable to IP Discovery , 2014 .

[120]  Y. Termonia Computer model for the elastic properties of short fibre and particulate filled polymers , 1987 .

[121]  Werner Hufenbach,et al.  Hybrid 3D-textile reinforced composites with tailored property profiles for crash and impact applications , 2009 .

[122]  C. Sotiriou-Leventis,et al.  One Pot Synthesis of Multifunctional Aramid Aerogels , 2012 .

[123]  Y. Jeong,et al.  Electric heating films based on m-aramid nanocomposites containing hybrid fillers of graphene and carbon nanotube , 2013, Journal of Materials Science.

[124]  S. Rebouillat,et al.  Thermally induced changes in Kevlar fibre surface evidenced by inverse gas chromatography , 1995 .

[125]  M. Stamm,et al.  Comparative analysis of structure and temperature behaviour of two copolyamides - Regular KEVLAR and statistical ARMOS , 1999 .

[126]  Yentl Swolfs,et al.  Fibre hybridisation in polymer composites: a review , 2014 .

[127]  L. C. Hollaway,et al.  The evolution of and the way forward for advanced polymer composites in the civil infrastructure , 2003 .

[128]  M. N. Raftenberg,et al.  Kevlar KM2 Yarn and Fabric Strength Under Quasi-Static Tension , 2002 .

[129]  M. Takayanagi,et al.  Effect of coagulation conditions on crystal modification of poly(p‐phenylene terephthalamide) , 1979 .

[130]  R. Marlowe,et al.  A Novel Lightweight Sandwich Panel WithSubstantial Resistance To Ballistic Penetration , 2006 .

[131]  D. J. Johnson,et al.  Supramolecular structure of a high‐modulus polyaromatic fiber (Kevlar 49) , 1977 .

[132]  Hydrophilic porous asymmetric ultrafiltration membranes of aramid-g-PEO copolymers , 2014 .

[133]  Togay Ozbakkaloglu,et al.  Behavior of FRP-Confined Normal- and High-Strength Concrete under Cyclic Axial Compression , 2012 .

[134]  Milad Mehranpour,et al.  Improvements in tribological properties of polyoxymethylene by aramid short fiber and polytetrafluoroethylene , 2012, Iranian Polymer Journal.

[135]  Serge Rebouillat,et al.  Tribological properties of woven para-aramid fabrics and their constituent yarns , 1998 .

[136]  A. A. Krikanov,et al.  Composite pressure vessels with higher stiffness , 2000 .

[137]  T. Gierke,et al.  Morphology of poly(p‐phenylene terephthalamide) fibers , 1983 .

[138]  R. J. Morgan,et al.  The relationship between the physical structure and the microscopic deformation and failure processes of poly(p-phenylene terephthalamide) fibers , 1983 .

[139]  G. Savage,et al.  Formula 1 Composites Engineering , 2010 .