论文信息 - The novel linear-polymeric organolithium compound {(Me2NMe2Si)3CLi}∞

The novel linear-polymeric organolithium compound {(Me2NMe2Si)3CLi}∞

The compound (Me2Nme2Si)3CH is readily metallated by MeLi in THF to give the linear-polymeric {(Me2Nme2Si)3Cli}∞, in which two of the N atoms in each planar carbanionic unit (Me2Nme2Si)3C– are attached to one lithium atom and the remaining N atom to another Li atom; each Li shows planar three-coordination.

P. Hitchcock | Farook Adam | C. Eaborn | J. Smith

[1] K. Izod,et al. Synthesis, structure and reactions of organometallic compounds of Groups 1–3 containing bulky silicon-substituted alkyl groups , 1995 .

[2] P. Hitchcock,et al. The Synthesis and Crystal Structures of RbC(SiMe3)3 and CsC(SiMe3)3·3.5 C6H6: A One‐dimensional Ionic Solid and an Ionic Solid with a Molecular Structure , 1995 .

[3] J. I. Brauman,et al. .alpha.-Silyl-Substituent Stabilization of Carbanions and Silyl Anions , 1994 .

[4] P. Hitchcock,et al. Metalation of Tris(trimethylsilyl)‐ and Tris(dimethylphenylsilyl)methane with Methylsodium: The First Dialkylsodate , 1994 .

[5] P. Hitchcock,et al. Crystal Structures of (Tris(trimethylsilyl)methyl)- and (Tris(dimethylphenylsilyl)methyl)potassium , 1994 .

[6] E. Weiss. Structures of Organo Alkali Metal Complexes and Related Compounds , 1993 .

[7] P. Hitchcock,et al. The crystal structure of tris (phenyldimethylsilyl) methane , 1984 .

[8] P. Hitchcock,et al. Some derivatives of tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure , 1983 .