Palladium(II) and Palladium(II)–Platinum(II) Mixed Metal Complexes with Mercapto-1,3,4-thiadiazolate

Mononuclear and dinuclear Pd(II) complexes with mercapto-1,3,4-thiadiazolate were prepared by reacting [Pd(OH)(terpy)](PF6) with 2-amino-5-mercapto-1,3,4-thiadiazole (Hamct) and 2,5-dimercapto-1,3,...

[1]  P. Akrivos Recent studies in the coordination chemistry of heterocyclic thiones and thionates , 2001 .

[2]  Xiaoming Liu,et al.  The structures and decomposition products of palladium(II) and platinum(II) terpyridine phenoxide complexes , 2003 .

[3]  Eric S. Raper,et al.  Complexes of heterocyclic thionates. Part 1. Complexes of monodentate and chelating ligands , 1996 .

[4]  C. Che,et al.  Structures and photoluminescence of dinuclear platinum(II) and palladium(II) complexes with bridging thiolates and 2,2′-bipyridine or 2,2′∶6′,2″-terpyridine ligands , 1999 .

[5]  E. Castellano,et al.  Preparation and crystal structure of a binuclear compound of methylmercury(II) containing bismuthiol I as a bridging ligand , 1989 .

[6]  Parr,et al.  Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. , 1988, Physical review. B, Condensed matter.

[7]  E. S. Raper Complexes of heterocyclic thione donors , 1985 .

[8]  N. Oyama,et al.  Monodentate and bridging coordination of 2,5-dimercapto-1,3,4-thiadiazolate to a (2,2′:6′,2″-terpyridine)platinum(II) center , 2003 .

[9]  Ž. Bugarčić,et al.  Kinetics and mechanism of the reaction of chelated Pd(II) complexes with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pd(bpma)Cl]Cl·H2O (bpma = bis(2-pyridylmethyl)amine) , 2002 .

[10]  W. R. Wadt,et al.  Ab initio effective core potentials for molecular calculations , 1984 .

[11]  A. Becke Density-functional thermochemistry. III. The role of exact exchange , 1993 .

[12]  S. Teat,et al.  Transformation of sulfur dioxide to sulfate at a palladium centre , 2002 .

[13]  H. Schmidbaur,et al.  Crystal Engineering of Gold(I) Thiolate Based Compounds via Cooperative Aurophilic and Hydrogen-Bonding Interactions , 1999 .

[14]  H. Schmidbaur,et al.  The Close-Knit Supramolecular Network of Bis[(tert-butyl isocyanide)gold(I)] 1,3,4-Thiadiazole-2,5-disulfide , 2001 .

[15]  F. Dahan,et al.  Aqueous chemistry of platinum and palladium complexes. Part 2. Synthesis and crystal structure of a palladium hydroxo complex [Pd(terpy)(OH)]ClO4·H2O (terpy = 2,2′:6′,2″-terpyridine) , 1990 .

[16]  Da-qi Wang,et al.  Synthesis and crystal structure of a novel pentanuclear complex of tin (IV) with heterocyclic sulfur and nitrogen donor ligands , 2003 .

[17]  Eric S. Raper,et al.  Copper complexes of heterocyclic thioamides and related ligands , 1994 .

[18]  Eric S. Raper,et al.  Complexes of heterocyclic thionates Part 2: complexes of bridging ligands , 1997 .

[19]  H. Schmidbaur,et al.  Diversity in the structural chemistry of (phosphine)gold(I) 1,3,4-thiadiazole-2,5-dithiolates (bismuthiolates I). , 2001, Inorganic chemistry.

[20]  Junhong Zhang,et al.  Syntheses and Crystal Structures of Diorganotin Derivatives of 2,5-Dimercapto-1,3,4-thiadiazole , 2004 .

[21]  K. Okamoto,et al.  Structural Characteristics of S-Bridged Trinuclear Complexes [{Pd(terpy)}2{Pd(aet)2}]4+ (terpy = 2,2′ : 6′,2′′-Terpyridine, aet = 2-Aminoethanethiolate): Effects of Counter Anions and Solvent on Intra- and Intermolecular Stacking Arrangements , 2000 .

[22]  A. Becke,et al.  Density-functional exchange-energy approximation with correct asymptotic behavior. , 1988, Physical review. A, General physics.

[23]  S. D. Robinson,et al.  1,3,4,-Thiadiazole-2,5-dithiol complexes of the platinum group metals; the molecular structure of carbonylbis(1,3,4-thiadiazole-2,5-dithiolato)bis(triphenylphosphine)ruthenium(II) , 1985 .

[24]  W. R. Wadt,et al.  Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals , 1985 .

[25]  E. Freisinger,et al.  MONO- AND DI-NUCLEAR COMPLEXES OF (TRPY)MII (M = PD, PT) WITH THE MODEL NUCLEOBASE 1-METHYLCYTOSINE. CRYSTAL STRUCTURE AND NMR SOLUTION STUDIES , 1999 .

[26]  E. Castellano,et al.  Spectroscopic and X-ray studies of bis[dimethylthallium(III)]-1,3,4-thiodiazole-2,5-dithiolato , 1992 .

[27]  W. R. Wadt,et al.  Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi , 1985 .

[28]  Ž. Bugarčić,et al.  Kinetics and mechanism of the reactions of [Pt(terpy)H2O]2+ with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pt(terpy)(tu)](ClO4)2 (tu = thiourea) , 2002 .

[29]  Hidenori Tannai,et al.  Switching of the electronic communication between two {Ru(trpy)(bpy)} (trpy = 2,2':6',2' '-terpyridine and bpy = 2,2'-bipyridine) centers by protonation on the bridging dimercaptothiadiazolato ligand. , 2005, Inorganic chemistry.

[30]  V. Miskowski,et al.  SPECTROELECTROCHEMISTRY AND DIMERIZATION EQUILIBRIA OF CHLORO(TERPYRIDINE)PLATINUM(II). NATURE OF THE REDUCED COMPLEXES , 1996 .

[31]  David R. McMillin,et al.  Tuning solid emission by salts of the [Pt{4′-(o-CH3–Ph)trpy}Cl]+ and [Pt{4′-(o-CF3–Ph)trpy}Cl]+ luminophores: crystal structures of [Pt{4′-(o-CH3–Ph)trpy}Cl]A (A = BF4 or SbF6) and [Pt{4′-(o-CF3–Ph)trpy}Cl]SbF6 (trpy = 2,2′:6′,2″-terpyridine) , 2002 .