Sol–gel synthesis of transition-metal doped ferrite compounds with potential flexible, dielectric and electromagnetic properties

A compact and flexible dielectric substrate with efficient electromagnetic performances both in flat and bending conditions are presented in this paper. The proposed substrates, for potential microwave radiator applications have been fabricated from Mn doped zinc ferrite compounds by sol–gel method. Prepared MnxZn(1−x)Fe2O4, (x = 0.0, 0.2, 0.4, 0.6, 0.8) substrates were analysed structurally by X-ray diffraction spectroscopy and morphologically studied by scanning electron microscopy. We studied the optical and dielectric properties in the microwave range to evaluate the new material as a dielectric substrate for microwave applications. The prepared flexible substrates exhibit high dielectric permittivity and low dielectric loss in the microwave frequency range. For the proof of concept, the electromagnetic performances both at flat and bending conditions were verified by loading an electromagnetic radiator. We report the detailed measured performances of the reflection coefficient below −10 dB, average efficiency above 73% and average realized gain above 1.5 dBi within the operational bandwidth for the first time. The measured stable omnidirectional radiation patterns both in flat and bending conditions also confirm the potential of the proposed material to be used as a new flexible dielectric substrate.

[1]  K. M. Jadhav,et al.  Structural and optical properties of nanocrystalline Ni–Zn ferrite thin films , 2010 .

[2]  M. Gharagozlou Synthesis, characterization and influence of calcination temperature on magnetic properties of nanocrystalline spinel Co-ferrite prepared by polymeric precursor method , 2009 .

[3]  Jiantao Feng,et al.  Synthesis and excellent electromagnetic absorbing properties of copolymer (N-methylpyrrole-co-pyrrole) and Ba–Nd–Cr ferrite , 2015 .

[4]  M. Siddique,et al.  Investigation on the structural, dielectric and impedance analysis of manganese substituted cobalt ferrite i.e., Co1−xMnxFe2O4 (0.0 ≤ x ≤ 0.4) , 2016 .

[5]  M. Barati,et al.  The role of surfactant in synthesis of magnetic nanocrystalline powder of NiFe2O4 by sol–gel auto-combustion method , 2008 .

[6]  H. Abdelmoneim Dielectric properties of TixLi1-xLa0.1Fe1.9O4 ferrite thin films , 2010 .

[7]  Arash Takshi,et al.  Multilayer Stretchable Conductors on Polymer Substrates for Conformal and Reconfigurable Antennas , 2013, IEEE Antennas and Wireless Propagation Letters.

[8]  Christophe Fumeaux,et al.  A Compact, Highly Efficient and Flexible Polymer Ultra-Wideband Antenna , 2015, IEEE Antennas and Wireless Propagation Letters.

[9]  M. Khraisheh,et al.  Structural and magnetic properties of Ni1-xZnxFe2O4 (x=0, 0.5 and 1) nanopowders prepared by sol-gel method , 2013 .

[10]  A. Delimitis,et al.  Hydrothermally prepared nanocrystalline Mn-Zn ferrites: Synthesis and characterization , 2008 .

[11]  C. Brinker,et al.  Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing , 1990 .

[12]  A. Ghasemi,et al.  Influence of multiwalled carbon nanotube addition on the magnetic and reflection-loss characteristics of Mn–Sn–Ti substituted strontium ferrite nanoparticles , 2014 .

[13]  V. Murthy,et al.  Dielectric properties of some nickel‐zinc ferrites at radio frequency , 1976 .

[14]  F. Ivanauskas,et al.  Aqueous sol-gel synthesis route for the preparation of YAG: Evaluation of sol-gel process by mathematical regression model , 2007 .

[15]  X. Jiao,et al.  Preparation of ZnFe2O4 Nanofibers by Sol‐Gel Related Electrospinning Method , 2006 .

[16]  W. Lei,et al.  Phase Composition and Microwave Dielectric Properties of ZnAl2O4–Co2TiO4 Low‐Permittivity Ceramics with High Quality Factor , 2011 .

[17]  A. Baykal,et al.  Synthesis and magneto-optical properties of triethylene glycol stabilized Mn1−xZnxFe2O4 nanoparticles , 2015 .

[18]  Microwave dielectric properties of (Mg(1-x) Cox)2Sn04 ceramics for application in dual- band inverted-E-shaped monopole antenna , 2011, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[19]  S. Mahalakshmi,et al.  ac electrical conductivity and dielectric behavior of nanophase nickel ferrites , 2008 .

[20]  B. Boyanov,et al.  Dielectric properties of polycrystalline mixed nickel–zinc ferrites , 1999 .

[21]  Nur Amin Hoque,et al.  Sol–gel synthesis of transition-metal ion conjugated alumina-rich mullite nanocomposites with potential mechanical, dielectric and photoluminescence properties , 2015 .

[22]  S. Nahm,et al.  Crystal structure and microwave dielectric properties of (1 − x)ZnTa2O6–xTiO2 ceramics , 2012 .

[23]  Leslie A. Rusch,et al.  Flexible 16 Antenna Array for Microwave Breast Cancer Detection , 2015, IEEE Transactions on Biomedical Engineering.

[24]  Jing Zhang,et al.  Preparation and microwave absorption mechanisms of the NiZn ferrite nanofibers , 2015 .

[25]  Mohammad Tariqul Islam,et al.  Preparation and Characterization of Flexible Substrate Material from Phenyl-Thiophene-2-Carbaldehyde Compound , 2016, Materials.

[26]  J. Vanfleteren,et al.  Elastic and Conformable Electronic Circuits and Assemblies using MID in polymer , 2007, Polytronic 2007 - 6th International Conference on Polymers and Adhesives in Microelectronics and Photonics.

[27]  Xinyong Li,et al.  ZnFe2O4 multi-porous microbricks/graphene hybrid photocatalyst: Facile synthesis, improved activity and photocatalytic mechanism , 2013 .

[28]  D. Chrisey,et al.  The magnetic and structural properties of pulsed laser deposited epitaxial MnZn–ferrite films , 1994 .

[29]  Mohammad Tariqul Islam,et al.  Synthesis and characterization of gahnite-based microwave dielectric ceramics (MDC) for microstrip antennas prepared by a sol–gel method , 2015, Journal of Sol-Gel Science and Technology.

[30]  G. Mangamma,et al.  EFFECTS OF SILICA ADDITIONS ON H2S SENSING PROPERTIES OF CUO-SNO2 SENSORS , 1998 .

[31]  Shaorong Xiao,et al.  The Cobalt Zinc Spinel Ferrite Nanofiber: Lightweight and Efficient Microwave Absorber , 2014 .

[32]  G. Lazzi,et al.  Flexible Liquid Metal Alloy (EGaIn) Microstrip Patch Antenna , 2012, IEEE Transactions on Antennas and Propagation.

[33]  Sergei A. Tretyakov,et al.  Experimental studies on antenna miniaturisation using magneto-dielectric and dielectric materials , 2009, 0910.4060.

[34]  B. Song,et al.  Effect of pH value on electromagnetic loss properties of Co–Zn ferrite prepared via coprecipitation method , 2016 .

[35]  M. A. Señarís-Rodríguez,et al.  A simple solvothermal synthesis of MFe2O4 (M=Mn, Co and Ni) nanoparticles , 2009 .

[36]  H. Hong,et al.  Thick-film zinc-oxide gas sensor for the control of lean air-to-fuel ratio in domestic combustion systems , 1995 .

[37]  A. Xia,et al.  Effects of excessive Zn2+ ions on intrinsic magnetic and structural properties of Ni0.2Zn0.6Cu0.2Fe2O4 powder prepared by chemical coprecipitation method , 2010 .

[38]  M. Toprak,et al.  Synthesis and magnetic characterization of Zn0.7Ni0.3Fe2O4 nanoparticles via microwave-assisted combustion route , 2010 .

[39]  B. Song,et al.  Facile preparation and microwave absorption properties of porous hollow BaFe12O19/CoFe2O4 composite microrods , 2015 .

[40]  Bo Song,et al.  Tunable electromagnetic properties and enhanced microwave absorption ability of flaky graphite/cobalt zinc ferrite composites , 2016 .

[41]  Selestina Gorgieva,et al.  Mechanically strong, flexible and thermally stable graphene oxide/nanocellulosic films with enhanced dielectric properties , 2016 .

[42]  H. Abdullah,et al.  Synthesis and fabrication of GPS patch antennas by using Zn(1 − x)TixAl2O4 thin films , 2015, Journal of Sol-Gel Science and Technology.