论文信息 - Diethyl {2-[(4-chlorophenoxy)methyl]-9-(methylsulfanyl)-7H-pyrazolo[4,3-d][1,2,4]-triazolo[1,5-d]pyrimidin-7-yl}(phenyl)methylphosphonate

Diethyl {2-[(4-chlorophenoxy)methyl]-9-(methylsulfanyl)-7H-pyrazolo[4,3-d][1,2,4]-triazolo[1,5-d]pyrimidin-7-yl}(phenyl)methylphosphonate

In the title compound, C25H26ClN6O4PS, the fused pyrazolotriazolopyrimidine ring system is almost planar. It makes dihedral angles of 78.1 (1) and 17.1 (1)°, respectively, with the attached phenyl ring and 4-chlorophenoxymethyl fragment. The P atom has a distorted tetrahedral configuration. Intra- and intermolecular C—H⋯O and C—H⋯N hydrogen bonds, together with strong π–π stacking interactions (interplanar distances 3.312–3.567 A), stabilize the structure.

De-Qing Shi | Lingyun Xiao

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Diethyl {2-[(4-chloro­phen­oxy)meth­yl]-9-(methyl­sulfanyl)-7H-pyrazolo[4,3-d][1,2,4]-triazolo[1,5-d]pyrimidin-7-yl}(phen­yl)methyl­phospho­nate

Diethyl {2-[(4-chlorophenoxy)methyl]-9-(methylsulfanyl)-7H-pyrazolo[4,3-d][1,2,4]-triazolo[1,5-d]pyrimidin-7-yl}(phenyl)methylphosphonate