Degradation of azo dyes under visible light with stable MOF based on tetrastyrene imidazole ligand.

In the present work, a new 3D metal-organic framework (MOF) has been synthesized and characterized. The MOF exhibits good chemical stability in aqueous solutions with the pH scale ranging from 3 to 11. Interestingly, the MOF shows high catalytic activities for the degradation of azo dyes (MO, CR and CBR) under visible light without H2O2. The Ea values of the MOF for MO, CR and CBR degradation are obtained to be 23.49, 52.68 and 15.19 kJ mol-1, respectively. In addition, the MOF can be reused in the catalytic process without the catalytic activity decreasing obviously.

[1]  Shuang Yao,et al.  Photosensitizing single-site metal−organic framework enabling visible-light-driven CO2 reduction for syngas production , 2019, Applied Catalysis B: Environmental.

[2]  Ki‐Hyun Kim,et al.  Photocatalysts for degradation of dyes in industrial effluents: Opportunities and challenges , 2019, Nano Research.

[3]  Fenglei Shen,et al.  Rational Design of MOF/COF Hybrid Materials for Photocatalytic H2 Evolution in the Presence of Sacrificial Electron Donors. , 2018, Angewandte Chemie.

[4]  Z. Su,et al.  A difunctional metal–organic framework with Lewis basic sites demonstrating turn-off sensing of Cu2+ and sensitization of Ln3+ , 2018 .

[5]  Fei Li,et al.  Simultaneous photoreduction of Uranium(VI) and photooxidation of Arsenic(III) in aqueous solution over g-C3N4/TiO2 heterostructured catalysts under simulated sunlight irradiation , 2018, Applied Catalysis B: Environmental.

[6]  Chun-sen Liu,et al.  Stable Layered Semiconductive Cu(I)-Organic Framework for Efficient Visible-Light-Driven Cr(VI) Reduction and H2 Evolution. , 2018, Inorganic chemistry.

[7]  Z. Su,et al.  A new triazine-based covalent organic polymer for efficient photodegradation of both acidic and basic dyes under visible light. , 2018, Dalton transactions.

[8]  Q. Cheng,et al.  Two pure MOF-photocatalysts readily prepared for the degradation of methylene blue dye under visible light. , 2018, Dalton transactions.

[9]  Guo-ping Sheng,et al.  Application of membrane bioreactor for sulfamethazine-contained wastewater treatment. , 2018, Chemosphere.

[10]  Yinghua Lu,et al.  Enhance wastewater biological treatment through the bacteria induced graphene oxide hydrogel. , 2018, Chemosphere.

[11]  Christopher A. Trickett,et al.  Plasmon-Enhanced Photocatalytic CO(2) Conversion within Metal-Organic Frameworks under Visible Light. , 2017, Journal of the American Chemical Society.

[12]  Xing Meng,et al.  A visible light-driven photocatalyst of a stable metal-organic framework based on Cu4Cl clusters and TIPE spacers. , 2016, Dalton transactions.

[13]  Z. Su,et al.  Highly efficient visible-light-driven CO2 reduction to formate by a new anthracene-based zirconium MOF via dual catalytic routes , 2016 .

[14]  S. Nakagawa,et al.  Novel degradation mechanism for triarylmethane dyes: Acceleration of degradation speed by the attack of active oxygen to halogen groups , 2016 .

[15]  Yadagiri Rachuri,et al.  Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: Crystal structure, photoluminescence and photocatalytic activity , 2014 .

[16]  Weilin Guo,et al.  Degradation of antibiotics amoxicillin by Co3O4‐catalyzed peroxymonosulfate system , 2013 .

[17]  Guangming Zeng,et al.  Risks of neonicotinoid pesticides. , 2013, Science.

[18]  Zhiyu Wang,et al.  A Zn4O-containing doubly interpenetrated porous metal-organic framework for photocatalytic decomposition of methyl orange. , 2011, Chemical communications.

[19]  Zhigang Xie,et al.  Doping metal-organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis. , 2011, Journal of the American Chemical Society.

[20]  Chuncheng Chen,et al.  Semiconductor-mediated photodegradation of pollutants under visible-light irradiation. , 2010, Chemical Society reviews.

[21]  M. Rafatullah,et al.  Scavenging behaviour of meranti sawdust in the removal of methylene blue from aqueous solution. , 2009, Journal of hazardous materials.

[22]  Z. Zou,et al.  Mechanism investigation of visible light-induced degradation in a heterogeneous TiO2/eosin Y/rhodamine B system. , 2009, Environmental science & technology.

[23]  Lili Wen,et al.  Structures, Photoluminescence, and Photocatalytic Properties of Six New Metal−Organic Frameworks Based on Aromatic Polycarboxylate Acids and Rigid Imidazole-Based Synthons , 2009 .

[24]  M. Doğan,et al.  Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters. , 2009, Journal of hazardous materials.

[25]  C. Du,et al.  FeVO4 as a highly active heterogeneous Fenton-like catalyst towards the degradation of Orange II , 2008 .

[26]  M. Anpo,et al.  Photocatalysis for new energy production: Recent advances in photocatalytic water splitting reactions for hydrogen production , 2007 .

[27]  X. Verykios,et al.  Visible light-induced photocatalytic degradation of Acid Orange 7 in aqueous TiO2 suspensions , 2004 .

[28]  G. Lettinga,et al.  The contribution of biotic and abiotic processes during azo dye reduction in anaerobic sludge. , 2003, Water research.

[29]  M Y Mollah,et al.  Electrocoagulation (EC)--science and applications. , 2001, Journal of hazardous materials.

[30]  T Robinson,et al.  Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. , 2001, Bioresource technology.

[31]  Sixto Malato,et al.  The photo-fenton reaction and the TiO2/UV process for waste water treatment − novel developments , 1999 .

[32]  J. Lubchenco.  Entering the Century of the Environment: A New Social Contract for Science , 1998 .

[33]  D. T. Sawyer,et al.  How super is superoxide , 1981 .