EVALUATION OF CHARACTERIZATION TECHNIQUES FOR BENEFICIAL USE OF UNDERUTILIZED SLAG MATERIALS

Wisely using byproduct materials in beneficial use applications such as highway construction is becoming more important in the United States as virgin materials are depleted and landfill capacity declines. Slags are byproducts of the steel and iron industries found in the Midwestern United States. Historically, many of these materials have historically been used in construction applications, but methods for characterizing their environmental risk are limited. This research considers a series of steps used to identify whether a particular slag poses an environmental or human health risk. The first step involves identifying the appropriate use of the material. The second step involves identifying the site-specific parameters such as precipitation rates and expected pH conditions. The third step involves characterizing the material with a set of leaching procedures that test the material under the range of expected site-specific conditions. The majority of this research focused on this characterization step. The final step involves fate and transport modeling of the appropriate leaching data to identify the ultimate constituent concentrations expected at a receptor. (Abstract shortened by UMI.).

[1]  Jiwan D. Gupta,et al.  Characterization of base and subbase iron and steel slag aggregates causing deposition of calcareous tufa in drains : Subsurface drainage , 1994 .

[2]  T. Taylor Eighmy,et al.  An approach for estimation of contaminant release during utilization and disposal of municipal waste combustion residues , 1996 .

[3]  H. Inyang,et al.  Relating Batch and Column Diffusion Coefficients for Leachable Contaminants in Particulate Waste Materials , 2003 .

[4]  B. W. Boyer ALKALINE LEACHATE AND CALCAREOUS TUFA ORIGINATING FROM SLAG IN A HIGHWAY EMBANKMENT NEAR BALTIMORE, MARYLAND , 1994 .

[5]  S Mathur,et al.  Utilization of Industrial Wastes in Low-Volume Roads , 1999 .

[6]  G. J. de Groot,et al.  Determination of Leaching Characteristics of Waste Materials Leading to Environmental Product Certification , 1992 .

[7]  David S. Kosson,et al.  An Integrated Framework for Evaluating Leaching in Waste Management and Utilization of Secondary Materials , 2002 .

[8]  J. Geiseler,et al.  Products of steel slags an opportunity to save natural resources , 2000 .

[9]  Paul F. Ziemkiewicz,et al.  STEEL SLAG: APPLICATIONS FOR AMD CONTROL , 1998 .

[10]  Luciana Rohde,et al.  Electric Arc Furnace Steel Slag: Base Material for Low-Volume Roads , 2003 .

[11]  I. Neretnieks,et al.  Evaluation of the time-dependent neutralising behaviours of MSWI bottom ash and steel slag , 1998 .

[12]  J. Sencindiver,et al.  Physical Properties of Minesoils in West Virginia and Their Influence on Wastewater Treatment , 1998 .

[13]  Paul F. Ziemkiewicz,et al.  Long-term Performance of Passive Acid Mine Drainage Treatment Systems , 2003 .

[14]  Fredrik P. Glasser,et al.  The Chemical Environment in Cement Matrices , 1985 .

[15]  I. Neretnieks,et al.  The long-term acid neutralizing capacity of steel slag , 1997 .

[16]  John J. Emery,et al.  Technology of Slag Utilization in Highway Construction , 2004 .

[17]  Rian J Dippenaar,et al.  Industrial uses of slag (the use and re-use of iron and steelmaking slags) , 2005 .

[18]  T. Mueller,et al.  Concentration and Distribution of Six Trace Metals in Northern Kentucky Soils , 2004 .

[19]  J. Hartlén,et al.  Leaching of slags and ashes - controlling factors in field experiments versus in laboratory tests , 1994 .

[20]  J. Sansalone,et al.  Heavy Metal Contamination in Soils of Urban Highways Comparison Between Runoff and Soil Concentrations at Cincinnati, Ohio , 2001 .

[21]  Geert-Jan Witkamp,et al.  Mineral CO2 sequestration by steel slag carbonation. , 2005, Environmental science & technology.

[22]  H. A. van der Sloot,et al.  Systematic Leaching Behaviour of Trace Elements from Construction Materials and Waste Materials. , 1991 .

[23]  David S. Kosson,et al.  Integration of Testing Protocols for Evaluation of Contaminant Release From Monolithic and Granular Wastes , 1997 .

[24]  Marko Mäkikyrö,et al.  Converting raw materials into the products–Road base material stabilized with slag-based binders , 2004 .

[25]  R. Barna,et al.  Leaching of inorganic contaminants from cement-based waste materials as a result of carbonation during intermittent wetting. , 2002, Waste management.

[26]  B. Lemass SLAG SOLUTIONS FOR HEAVY DUTY ROAD PAVEMENTS , 1992 .

[27]  Jinying Yan,et al.  The long-term acid neutralizing capacity of steel slag , 2000 .

[28]  J. Ball,et al.  An assessment of the availability of pollutant constituents on road surfaces , 1998 .

[29]  H G Johansson,et al.  PERFORMANCE-RELATED TESTS ON AIR-COOLED BLAST-FURNACE SLAG AND CRUSHED CONCRETE, VTI ACTIVITIES IN THE EUROPEAN ALT-MAT PROJECT , 2001 .

[30]  L. M. Juckes,et al.  The volume stability of modern steelmaking slags , 2003 .

[31]  T. O. Shepker,et al.  Physical and chemical characteristics of blast furnace, basic oxygen furnace, and electric arc furnace steel industry slags. , 2000 .

[32]  H. V. Oss SLAG—IRON AND STEEL , 2002 .

[33]  Lotta Lind,et al.  Leaching results of reactive materials , 2008 .

[34]  F Sanchez,et al.  Probabilistic approach for estimating the release of contaminants under field management scenarios. , 2005, Waste management.

[35]  H. D. Sloot Comparison of the characteristic leaching behavior of cements using standard (EN 196-1) cement mortar and an assessment of their long-term environmental behavior in construction products during service life and recycling , 2000 .

[36]  J. Allison,et al.  MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems: Version 3. 0 user's manual , 1991 .

[37]  am Fallman,et al.  LEACHING FROM SLAGS AND ASHES IN LYSIMETERS , 2001 .

[38]  Hans A. van der Sloot,et al.  Chemical Processes at A Reoox/Ph Interface Arising from the Use of Steel Slag in the Aquatic Environment , 1991 .

[39]  Y. Comeau,et al.  Phosphorus removal by electric arc furnace steel slag and serpentinite. , 2006, Water research.

[40]  P. M. Erickson,et al.  Comprehensive Approach toward Understanding Element Speciation and Leaching Behavior in Municipal Solid Waste Incineration Electrostatic Precipitator Ash. , 1995, Environmental science & technology.

[41]  E. Mulder TEST METHODS TO ASSESS ENVIRONMENTAL PROPERTIES OF AGGREGATES IN DIFFERENT APPLICATIONS: THE ROLE OF EN 1744-3 , 2002 .

[42]  Robert B. Ambrose,et al.  PARTITION COEFFICIENTS FOR METALS IN SURFACE WATER, SOIL, AND WASTE , 1999 .