Electrochemical corrosion studies and pitting corrosion sensitivity of a self‐pierce rivet joint of carbon fibre reinforced polymer (CFRP) – laminate and EN AW‐6060‐T6

The galvanic corrosion of a self-pierce rivet joint of EN AW-6060-T6 and a carbon fibre reinforced plastic (CFRP) laminate joint by an Almac®-coated self-pierce steel rivet was electrochemically investigated in a 5 wt.% sodium chloride solution. Furthermore, the joint was examined in a climate chamber according to the VDA 621-415 (VDA = Verein Deutscher Automobilhersteller) standard test and microscopically observed. Electrochemical tests of the single components already reveal that a rivet joint of the materials can lead to pitting corrosion on the aluminium alloy surface and enforces the dissolution of the anti-corrosion layer Almac® of the rivet. This predicted corrosion behaviour was confirmed by the microscopic observations after the exposure of the joint in the climate chamber.

[1]  David W. Hoeppner,et al.  Pit-to-crack transition in pre-corroded 7075-T6 aluminum alloy under cyclic loading , 2005 .

[2]  M. Stevanovic,et al.  Non-Hookean Elastic Behavior and Crystallite Orientation in Carbon Fibers , 2010 .

[3]  P. Grant,et al.  An electrochemical study of repassivation of aluminium alloys with SEM examination of the pit interiors using resin replicas , 2008 .

[4]  K. Friedrich,et al.  Galvanic corrosion of polyacrylnitrile (PAN) and pitch based short carbon fibres in polyetheretherketone (PEEK) composites , 2009 .

[5]  C. Blanc,et al.  Pit propagation rate on the 2024 and 6056 aluminium alloys , 1998 .

[6]  D. Saidi,et al.  Effects of pH and chloride concentration on pitting corrosion of AA6061 aluminum alloy , 2008 .

[7]  Weifeng Xu,et al.  Microstructure and pitting corrosion of friction stir welded joints in 2219-O aluminum alloy thick plate , 2009 .

[8]  Andrej Atrens,et al.  Influence of geometry on galvanic corrosion of AZ91D coupled to steel , 2006 .

[9]  N. Warrior,et al.  Fiber Alignment in Directed Carbon Fiber Preforms - Mechanical Property Prediction , 2010 .

[10]  D. Chung Comparison of submicron-diameter carbon filaments and conventional carbon fibers as fillers in composite materials , 2001 .

[11]  J. Gal,et al.  Corrosion by galvanic coupling between carbon fiber posts and different alloys. , 2000, Dental materials : official publication of the Academy of Dental Materials.

[12]  D. StJohn,et al.  Galvanic corrosion of magnesium alloy AZ91D in contact with an aluminium alloy, steel and zinc , 2004 .

[13]  C. Blanc,et al.  Susceptibility to pitting corrosion of 6056 aluminium alloy , 1997 .

[14]  H. Çelikkan,et al.  Electrochemical corrosion properties of metal alloys used in orthopaedic implants , 2009 .

[15]  D. Weng,et al.  Characteristics of pit growth on aluminium in seawater , 1990 .

[16]  C. Dong,et al.  Effect of microcrystallization on pitting corrosion of pure aluminium , 2009 .

[17]  H. Çelikkan,et al.  Galvanic corrosion of titanium-based dental implant materials , 2008 .

[18]  M. Ates,et al.  Electrochemical impedance spectroscopy and morphological analyses of pyrrole, phenylpyrrole and methoxyphenylpyrrole on carbon fiber microelectrodes , 2008 .

[19]  M. N. Alias,et al.  Corrosion behavior of carbon fiber composites in the marine environment , 1993 .

[20]  D. Draẑić,et al.  The correlation between accelerated laboratory corrosion tests and atmospheric corrosion station tests on steels , 1989 .

[21]  G. Song,et al.  Degradation of the surface appearance of magnesium and its alloys in simulated atmospheric environments , 2007 .

[22]  F. Mansfeld,et al.  Galvanic corrosion of bare and coated Al alloys coupled to stainless steel 304 or Ti-6Al-4V , 1973 .