论文信息 - Interactions at the interface between thermoplastic rubber and polychloroprene adhesive

Interactions at the interface between thermoplastic rubber and polychloroprene adhesive

The interface produced between a chlorinated thermoplastic styrene‐butadiene‐styrene rubber and a polychloroprene (PCP) adhesive has been studied and compared to the interface produced using a polyurethane (PU) adhesive. Chlorination of the rubber was produced by spin coating solutions of trichloroisocyanuric acid in methyl ethyl ketone. The adhesive solution was spin coated on to the chlorinated rubber and the interface between the chlorinated rubber and the adhesive was analyzed by infrared spectroscopy.

J. Martín-Martínez | M. M. Pastor-Blas | M. V. Navarro-Bañón

[1] E. T. Thachil,et al. Studies on Metal-to-Metal Adhesives Based on CNSL Resins , 2006 .

[2] V. Jankauskaitė,et al. The effect of surface properties on the adhesion of modified polychloroprene used as adhesive , 2005 .

[3] L. Varghese,et al. Studies on the adhesive properties of neoprene–phenolic blends , 2004 .

[4] L. Varghese,et al. Adhesive properties of blends of phenol/cardanol–formaldehyde copolymer resin with polychloroprene rubber , 2004 .

[5] J. Martín-Martínez,et al. Mechanisms of Adhesion in Surface Chlorinated Thermoplastic Rubber/Thermoplastic Polyurethane Adhesive Joints , 2002 .

[6] R. Font,et al. Reduction of solvent content in toluene–neoprene adhesives and in acetone–polyurethane adhesives , 2001 .

[7] J. Martín-Martínez,et al. Surface Characterization of Chlorinated Synthetic Vulcanized Styrene-Butadiene Rubber Using Contact Angle Measurements, Infra-Red Spectroscopy and XPS , 1997 .

[8] J. Martín-Martínez,et al. Failure analysis of surface-treated unvulcanized SBS rubber/polyurethane adhesive joints , 1997 .

[9] D. K. Owens,et al. Estimation of the surface free energy of polymers , 1969 .

[10] J. Martín-Martínez,et al. Elimination of the reactivation process in the adhesion of chlorinated SBS rubber with polychloroprene adhesives , 2007 .

[11] J. Martín-Martínez,et al. Chlorination of SBS rubbers with different styrene contents using trichloro-isocyanuric acid , 1999 .