Technetium electrochemistry at the turn of the century

[1]  M. Chotkowski,et al.  Electrochemistry and spectroelectrochemistry of perrhenates in sulfuric acid solutions , 2020 .

[2]  M. Volkov,et al.  Electroreduction of pertechnetate ions in concentrated acetate solutions , 2020 .

[3]  A. V. Kopytin,et al.  An Ion Selective Electrode for the Determination of Pertechnetate Ions , 2020, Journal of Analytical Chemistry.

[4]  A. F. Zhukov,et al.  A tetradecylphosphonium compounds–based membrane sensor for potentiometric quantitation of pertechnetate-ions in cementitious radioactive waste , 2020, Sensors and Actuators B: Chemical.

[5]  Y. Einaga,et al.  Unusual electrochemical properties of low-doped boron-doped diamond electrodes containing sp2 carbon. , 2020, Journal of the American Chemical Society.

[6]  F. Poineau,et al.  Bis(tetraphenylarsonium) hexafluoridotechnetate(IV) dihydrate: preparation, structure and spectroscopic analysis. , 2019, Acta crystallographica. Section C, Structural chemistry.

[7]  J. McCloy,et al.  Properties of Pertechnic Acid. , 2019, Inorganic chemistry.

[8]  V. Volkovich,et al.  Electrochemical and Spectroscopic Properties of Technetium in Fused Alkali Metal Chlorides , 2010, ECS Transactions.

[9]  M. Chotkowski,et al.  Intermediate oxidation states of technetium in alkaline solutions , 2018, Journal of Electroanalytical Chemistry.

[10]  E. Walter,et al.  Surprising formation of quasi-stable Tc(VI) in high ionic strength alkaline media , 2018 .

[11]  S. Pellet-Rostaing,et al.  Electrochemical behavior of platinum and gold electrodes in the aprotic ionic liquid N,N-Trimethylbutylammonium Bis(trifluoromethanesulfonyl)imide , 2018, Journal of Electroanalytical Chemistry.

[12]  M. Chotkowski Redox interactions of technetium with neptunium in acid solutions , 2018, Journal of Radioanalytical and Nuclear Chemistry.

[13]  F. Poineau,et al.  Speciation and reactivity of heptavalent technetium in strong acids , 2018 .

[14]  M. Chotkowski,et al.  Intermediate oxidation states of technetium in concentrated sulfuric acid solutions , 2018 .

[15]  M. Drees,et al.  [TcII(NO)(trifluoroacetate)4F]2- - synthesis and reactions. , 2017, Dalton transactions.

[16]  Edward J. Mausolf,et al.  Electrochemical studies of technetium–ruthenium alloys in HNO3: Implications for the behavior of technetium waste forms , 2017, Radiochemistry.

[17]  F. Poineau,et al.  Technetium: The First Radioelement on the Periodic Table , 2017 .

[18]  D. Kolman,et al.  The Corrosion Behavior of Technetium Metal Exposed to Aqueous Sulfate and Chloride Solutions , 2017 .

[19]  P. Shearing,et al.  Predominance Diagrams of Spent Nuclear Fuel Materials in LiCl-KCl and NaCl-KCl Molten Salt Eutectics , 2016 .

[20]  K. German,et al.  The influence of deviations in process parameters on the purification of uranium from different radionuclides , 2016, Theoretical Foundations of Chemical Engineering.

[21]  M. Chotkowski,et al.  Stability of technetium in the moderate oxidation states in acidic media , 2016 .

[22]  K. Dardenne,et al.  Thermodynamic description of Tc(iv) solubility and hydrolysis in dilute to concentrated NaCl, MgCl2 and CaCl2 solutions. , 2016, Dalton transactions.

[23]  B. Liu,et al.  Technetium transmutation in thin layer coating on PWR fuel rods , 2015 .

[24]  Edward J. Mausolf,et al.  Nanostructure of metallic particles in light water reactor used nuclear fuel , 2015 .

[25]  Erli Lu,et al.  Group 7 Metal-Metal Bonds , 2015 .

[26]  L. V. Zakharova,et al.  Anodic dissolution of Tc metal in HNO3 solutions , 2015, Radiochemistry.

[27]  T. Gharbi,et al.  Electrochemistry of pertechnetate on ultramicroelectrode: A new quality control for radiopharmaceuticals manufactured at hospital in nuclear medicine , 2015 .

[28]  F. Poineau,et al.  Hydrothermal Synthesis and Solid-state Structures of Polynuclear Technetium Iodide Compounds , 2015 .

[29]  Andreas C Scheinost,et al.  Redox chemistry of Tc(VII)/Tc(IV) in dilute to concentrated NaCl and MgCl2 solutions , 2015 .

[30]  L. Gagliardi,et al.  A Decade of Dinuclear Technetium Complexes with Multiple Metal–Metal Bonds , 2014 .

[31]  M. Drees,et al.  Fluoridonitrosyl complexes of technetium(I) and technetium(II). Synthesis, characterization, reactions, and DFT calculations. , 2014, Inorganic chemistry.

[32]  Kirk J. Cantrell,et al.  Technetium Immobilization Forms Literature Survey , 2014 .

[33]  M. Chotkowski,et al.  Thin layer spectroelectrochemical studies of pertechnetate reduction on the gold electrodes in acidic media , 2014 .

[34]  F. Poineau,et al.  Recent advances in technetium halide chemistry. , 2014, Accounts of chemical research.

[35]  B. P. Sullivan,et al.  Photophysics and luminescence spectroelectrochemistry of [Tc(dmpe)3](+/2+) (dmpe = 1,2-bis(dimethylphosphino)ethane). , 2013, The journal of physical chemistry. A.

[36]  F. Poineau,et al.  Hydrothermal synthesis and solid-state structure of Tc2(μ-O2CCH3)4Cl2 , 2013 .

[37]  Kirk J. Cantrell,et al.  Solubility control of technetium release from Saltstone by TcO2·xH2O , 2013 .

[38]  F. Poineau,et al.  Chemical and electrochemical behavior of metallic technetium in acidic media , 2013, Journal of Radioanalytical and Nuclear Chemistry.

[39]  L. Gagliardi,et al.  A trigonal-prismatic hexanuclear technetium(II) bromide cluster: solid-state synthesis and crystallographic and electronic structure. , 2013, Inorganic chemistry.

[40]  Edward J. Mausolf,et al.  Technetium chemistry in the fuel cycle: combining basic and applied studies. , 2013, Inorganic chemistry.

[41]  F. Poineau,et al.  On the nature of heptavalent technetium in concentrated nitric and perchloric acid , 2013 .

[42]  Eunja Kim,et al.  Reactivity of HTcO(4) with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations. , 2013, Dalton transactions.

[43]  N. G. Kravchenko,et al.  Electrochemical study of corrosion and dissolution of Tc metal in 0.5–6.0 M HNO3 , 2013, Radiochemistry.

[44]  R. Essehli,et al.  Spectrophotometric study of the behaviour of pertechnetate in trifluoromethanesulfonic acid: effect of alpha irradiation on the stability of Tc(VII) , 2012, Journal of Radioanalytical and Nuclear Chemistry.

[45]  J. Poblet,et al.  99Tc and Re incorporated into metal oxide polyoxometalates: oxidation state stability elucidated by electrochemistry and theory. , 2012, Inorganic chemistry.

[46]  M. Chotkowski,et al.  Electrochemical and spectroelectrochemical studies of pertechnetate electroreduction in acidic media , 2012 .

[47]  A. Maslennikov Electrochemistry of Actinides and Selected Fission Products in the Head End of Spent Nuclear Fuel Reprocessing , 2012 .

[48]  W. Lukens,et al.  Photoreduction of 99Tc pertechnetate by nanometer-sized metal oxides: new strategies for formation and sequestration of low-valent technetium. , 2011, Journal of the American Chemical Society.

[49]  L. Liang,et al.  Dissolution of technetium(IV) oxide by natural and synthetic organic ligands under both reducing and oxidizing conditions. , 2011, Environmental science & technology.

[50]  Edward J. Mausolf,et al.  Characterization of Electrodeposited Technetium on Gold Foil , 2011 .

[51]  T. Srinivasan,et al.  Electrodeposition of metallic uranium at near ambient conditions from room temperature ionic liquid , 2011 .

[52]  B. Scott,et al.  Synthesis and structure of technetium trichloride. , 2010, Journal of the American Chemical Society.

[53]  W. Lukens,et al.  Speciation and reactivity of technetium in sulfuric acid , 2010 .

[54]  L. Gagliardi,et al.  Radioactive electron-rich metal-metal triple bonds: the Tc2X4(PMe3)4 complexes (X=Cl, Br) , 2010 .

[55]  L. Gagliardi,et al.  Structural, spectroscopic, and multiconfigurational quantum chemical investigations of the electron-rich metal-metal triple-bonded Tc(2)X(4)(PMe(3))(4) (X = Cl, Br) complexes. , 2010, Inorganic chemistry.

[56]  Y. Kino,et al.  Synthesis, spectroscopic and electrochemical properties, and electronic structures of octahedral hexatechnetium(III) clusters [Tc6Q8(CN)6]4- (Q = S, Se). , 2010, Inorganic chemistry.

[57]  N. Sato,et al.  Synthesis, Structures, and Properties of New Chalcogenide‐Capped Octahedral Hexatechnetium(III) Complexes [Tc6S8X6]4– (X = Br, I), [Tc6Se8I2], and [Tc6Te15] , 2010 .

[58]  Rubel Chakravarty,et al.  A novel electrochemical technique for the production of clinical grade 99mTc using (n, gamma)99Mo. , 2010, Nuclear medicine and biology.

[59]  C. Sergeant,et al.  Physicochemical behavior of uranium and technetium in some new stages of the nuclear fuel cycle , 2008 .

[60]  R. Alberto,et al.  Technetium and rhenium: coordination chemistry and nuclear medical applications , 2006 .

[61]  A. Azqueta,et al.  Design and evaluation of "3 + 1" mixed ligand oxorhenium and oxotechnetium complexes bearing a nitroaromatic group with potential application in nuclear medicine oncology. , 2006, European journal of medicinal chemistry.

[62]  C. Hennig,et al.  Speciation of technetium and rhenium complexes by in situ XAS-electrochemistry , 2006 .

[63]  J. A. Rard Current Status of the Thermodynamic Data for Technetium and Its Compounds and Aqueous Species , 2005 .

[64]  X. Deschanels,et al.  Transmutation in Reactor and Aqueous Corrosion Resistance of Technetium Metal , 2005 .

[65]  B. Lewis,et al.  Thermodynamic considerations and prediction of the primary coolant activity of 99Tc , 2005 .

[66]  V. Peretroukhine,et al.  Technetium transmutation and production of artificial stable ruthenium , 2004 .

[67]  A. V. Kopytin,et al.  An Ion-Selective Plasticized PVC Membrane Electrode for Tc(VII) Determination , 2003 .

[68]  Chang K. Park,et al.  A preliminary design study for the HYPER system , 2003 .

[69]  B. Fourest,et al.  Electrochemical dissolution of simulated "white inclusions" in nitric acid. Linear voltammetry study with Mo, Re, Ru metals and their alloys electrodes , 2003 .

[70]  W. Lukens,et al.  Products of pertechnetate radiolysis in highly alkaline solution: structure of TcO2 x xH2O. , 2001, Environmental science & technology.

[71]  G. Ouvrard,et al.  XAS study of technetium(IV) polymer formation in mixed sulphate/chloride media , 2002 .

[72]  S. Williams,et al.  Technetium behaviour in Boom Clay – a laboratory and field study , 2002 .

[73]  M. Harada,et al.  New Approach to the Nuclear Fuel Reprocessing in Non-acidic Aqueous Solutions , 2001 .

[74]  Jerome J. Bucher,et al.  Radiolysis of TcO4- in Alkaline, Nitrate Solutions: Reduction by NO32- , 2001 .

[75]  V. Peretroukhine,et al.  Differential pulse voltammetric determination of U(VI)-Tc(VII) and U(VI)-Cr(VI) in alkaline solutions , 2001 .

[76]  K. Schwochau Technetium: Chemistry and Radiopharmaceutical Applications , 2000 .

[77]  F. Cotton,et al.  Metal–metal multiply-bonded complexes of technetium. , 1999 .

[78]  C. L. Naour,et al.  Electrochemical behaviour of technetium in acetic buffer , 1999 .

[79]  J. Fabryka-Martin,et al.  Nature`s uncommon elements: Plutonium and technetium , 1998 .

[80]  V. Peretroukhine,et al.  Technetium Ëlectrodeposition from Aqueous Formate Solutions : Electrolysis Kinetics and Material Balance Study , 1998 .

[81]  J. I. Kim,et al.  Activity coefficients and pitzer parameters in the systems Na+/Cs+/Cl-/TcO4- or ClO4-/H2O at 25°C , 1997 .

[82]  F. Cotton,et al.  Metal−Metal Multiply-Bonded Complexes of Technetium. 4.1 Photodissociation of the Tc≡Tc Triple Bond in [Tc2(CH3CN)10][BF4]4 , 1996 .

[83]  F. Cotton,et al.  METAL-METAL MULTIPLY-BONDED COMPLEXES OF TECHNETIUM. 3. PREPARATION AND CHARACTERIZATION OF PHOSPHINE COMPLEXES OF TECHNETIUM POSSESSING A METAL-METAL BOND ORDER OF 3.5 , 1996 .

[84]  S. V. Kryutchkov Chemistry of technetium cluster compounds , 1996 .

[85]  A. Pombeiro,et al.  Mixed-ligand complexes of technetium XIII. A new and facile synthesis, structure and electrochemical behaviour of trans-[Tc(dppe)2(butNC)2](PF6)· ethanol (dppe = bis(diphenylphosphino)ethane, butNC= tert-butylisocyanide)☆ , 1995 .

[86]  F. Cotton,et al.  Metal-Metal Multiply-Bonded Complexes of Technetium. 2. Preparation and Characterization of the Fully Solvated Ditechnetium Cation [Tc2(CH3CN)10]4+ , 1995 .

[87]  F. Cotton,et al.  Metal-Metal Multiply Bonded Complexes of Technetium. 1. Synthesis and Structural Characterization of Phosphine Complexes That Contain a Tc-Tc Multiple Bond , 1994 .

[88]  M. Grigoriev,et al.  Molecular and Electronic Structure of New Technetium Complexes , 1993 .

[89]  A. Taylor,et al.  Evaluation of biomatrix hydroxyapatite ocular implants with technetium-99m-MDP. , 1993, Journal of nuclear medicine : official publication, Society of Nuclear Medicine.

[90]  W. Preetz,et al.  Darstellung, Schwingungsspektren und Normalkoordinatenanalyse der Acetatochloroditechnetate(III), cis-Tc2(O2CCH3)2Cl4L2 (L = axiale Donorbase) sowie Kristallstruktur von cis-Tc2(O2CCH3)2Cl4((CH3)2NCOCH3)2 / Preparation, Vibrational Spectra and Normal Coordinate Analysis of Acetatochloroditechnetates , 1991 .

[91]  E. Deutsch,et al.  Technetium electrochemistry. 7. Electrochemical and spectroelectrochemical studies on technetium(III) and -(II) complexes containing polypyridyl ligands , 1991 .

[92]  R. Meyer,et al.  The Electrode Potential of the Tc(IV)-Tc(VII) Couple , 1991 .

[93]  J. Dewan,et al.  Technetium bis(.mu.-oxo) dimers of 1,4,7-triazacyclonane-N,N',N''-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(.mu.-O)2Tc(TCTA)]n- (n = 2, 3) and the crystal structure of Ba2[(TCTA)Tc(.mu.-O)2Tc(TCTA)](ClO4).9H2O , 1989 .

[94]  W. Heineman,et al.  Technetium electrochemistry. 6. Electrochemical behavior of cationic rhenium and technetium complexes in aqueous and aqueous micellar solutions , 1988 .

[95]  W. Heineman,et al.  Technetium electrochemistry. 5. Spectroelectrochemical studies on the hexachlorotechnetate(IV) and hexabromotechnetate(IV) complexes in aqueous media , 1987 .

[96]  H. M. Clark,et al.  Mechanism and kinetics of the stepwise voltammetric reduction of pertechnetate in alkaline solution to Tc(VI, Tc(V) and Tc(IV) , 1987 .

[97]  H. Gray,et al.  Electrochemistry of quadruply bonded molybdenum dimers. Evidence for metal-to-halide back-bonding , 1986 .

[98]  K. Lieser,et al.  Properties and Solubility of Technetium Dioxide , 1986 .

[99]  W. Heineman,et al.  Technetium electrochemistry. 3. Spectroelectrochemical studies on the mixed-ligand technetium(III) complexes trans-[Tc(PR2R')2L]+ where L is a tetradentate Schiff base ligand and PR2R' is a monodentate tertiary phosphine ligand , 1985 .

[100]  W. Heineman,et al.  Technetium electrochemistry. 2. Electrochemical and spectroelectrochemical studies of the bis(tertiary phosphine) (D) complexes trans-(Tc/sup III/D/sub 2/X/sub 2/)/sup +/ (X = Cl, Br) and (Tc/sub I/D/sub 3/)/sup +/ , 1984 .

[101]  J. A. Rard Critical review of the chemistry and thermodynamics of technetium and some of its inorganic compounds and aqueous species , 1983 .

[102]  E. Merz NUCLEAR WASTE: A SOURCE OF VALUABLE RAW MATERIAL OR JUST A TROUBLESOME POLLUTANT? , 1982 .

[103]  W. Heineman,et al.  Technetium electrochemistry. 1. Spectroelectrochemical studies of halogen, diars, and diphos complexes of technetium in nonaqueous media , 1981 .

[104]  B. Pihlar Electrochemical behaviour of technetium(VII) in acidic medium , 1979 .

[105]  A. Davison,et al.  NoteElectrochemical studies on halide and pseudo-halide complexes of technetium and rhenium , 1979 .

[106]  W. Heineman,et al.  Production, detection, and characterization of transient hexavalent technetium in aqueous alkaline media by pulse radiolysis and very fast scan cyclic voltammetry , 1978 .

[107]  H. Taube,et al.  Chemistry of trans-aquonitrosyltetraamminetechnetium(I) and related studies , 1976 .

[108]  L. Astheimer,et al.  Electrochemical reduction of MnO4−, TcO4− and ReO4− in organic solvents: Preparation of tetraoxomanganate(VI), -technetate(VI) and -rhenate(VI) , 1976 .

[109]  F. Cotton,et al.  Magnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. I. Octachloroditechnetate(n-) and octachlorodirhenate(n-) with n = 2 and 3 , 1975 .

[110]  S. Feldberg,et al.  Disproportionation of the technetate ion in aqueous alkaline media. An electrochemical study , 1969 .

[111]  R. Sharpe,et al.  Metallic fission-product inclusions in irradiated oxide fuels , 1968 .

[112]  J. R. Peterson,et al.  SOME CHEMICAL PROPERTIES OF ELEMENT 97 , 1967 .

[113]  R. Hirsch,et al.  Pertechnic Acid : an Aperiodic Variation in Acid Strength , 1963, Nature.

[114]  I. Scott,et al.  Some aspects of the polarographic behaviour of technetium and rhenium , 1959 .

[115]  W. T. Smith,et al.  Thermodynamic Properties of Technetium and Rhenium Compounds. II. Heats of Formation of Technetium Heptoxide and Pertechnic Acid, Potential of the Technetium-(IV)-Technetium(VII) Couple, and a Potential Diagram for Technetium1,2 , 1953 .

[116]  E. Segre,et al.  Some Chemical Properties of Element 43. II , 1937 .

[117]  E. Meusel Nitritbildung durch Bacterien , 1875 .