论文信息 - catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-μ-sulfato-κ4O:O′]]

catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-μ-sulfato-κ4O:O′]]

The title compound, [C5H14N2][UO2(H2O)(SO4)2], contains anionic [UO2(H2O)(SO4)2]2− chains with 1-methylpiperazinium cations balancing the charge. Each UVI atom is seven-coordinate in a pentagonal bipyramidal geometry, and each sulfate tetrahedron bridges two adjacent uranium centres. Neighbouring chains hydrogen bond to one another though the bound water molecules.

Clair L. Stuart | D. O′Hare | A. Norquist | M. Doran

[1] Dermot O'Hare,et al. Organically templated uranium(VI) sulfates: understanding phase stability using composition space , 2003 .

[2] C. Rao,et al. Amine-templated linear vanadium sulfates with different chain structures. , 2003, Inorganic chemistry.

[3] C. Rao,et al. Organically Templated Linear and Layered Iron Sulfates , 2003 .

[4] D. Louër,et al. Two new diamine templated lanthanum sulfates, La2(H2O)2(C4H12N2)(SO4)4 and La2(H2O)2(C2H10N2)3(SO4)6·4H2O, with 3D and 2D crystal structures , 2002 .

[5] C. Rao,et al. Organically templated mixed-valent iron sulfates possessing kagomé and other types of layered networks. , 2002, Angewandte Chemie.

[6] D. O′Hare,et al. Synthesis of Cyclical Diamine Templated Uranium Sulfates , 2002 .

[7] R. Doedens,et al. Hydrothermal synthesis and characterization of a new vanadyl sulfate compound: crystal structure of [V(IV)OSO4(H2O)4]·SO4·[H2N(C2H4)2NH2] , 1999 .

[8] R. Ewing,et al. The crystal chemistry of hexavalent uranium; polyhedron geometries, bond-valence parameters, and polymerization of polyhedra , 1997 .

[9] J. Carruthers,et al. A weighting scheme for least-squares structure refinement , 1979 .

catena-Poly­[1-methyl­piperazinium [[aquadioxouranium(VI)]-di-μ-sulfato-κ4O:O′]]

catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-μ-sulfato-κ4O:O′]]