Electropolymerization of Bithienyl-appended Cerium(III) Triple Decker Porphyrin Complex

A cerium(III) triple decker porphyrin complex bearing bithienyl substituents (1) at the peripheral meso-positions was synthesized. Electrochemical polymerization of the triple decker porphyrin gave a unique polymer film on the ITO electrode surface without decomposition.

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