Electrical conductivity, thermal conductivity, and rheological properties of graphene oxide-based nanofluids

Highly stable graphene oxide (GO)-based nanofluids were simply prepared by dispersing graphite oxide with the average crystallite size of 20 nm, in polar base fluids without using any surfactant. Electrical conductivity, thermal conductivity, and rheological properties of the nanofluids were measured at different mass fractions and various temperatures. An enormous enhancement, 25,678 %, in electrical conductivity of distilled water was observed by loading 0.0006 mass fraction of GO at 25 °C. GO–ethylene glycol nanofluids exhibited a non-Newtonian shear-thinning behavior followed by a shear-independent region. This shear-thinning behavior became more pronounced at higher GO concentrations. The maximum ratio of the viscosity of nanofluid to that of the ethylene glycol as a base fluid was 3.4 for the mass fraction of 0.005 of GO at 20 °C under shear rate of 27.5 s−1. Thermal conductivity enhancement of 30 % was obtained for GO–ethylene glycol nanofluid for mass fraction of 0.07. The measurement of the transport properties of this new kind of nanofluid showed that it could provide an ideal fluid for heat transfer and electronic applications.

[1]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[2]  Alexander A. Balandin,et al.  Phonon thermal conduction in graphene: Role of Umklapp and edge roughness scattering , 2009 .

[3]  James M Tour,et al.  Graphene oxide. Origin of acidity, its instability in water, and a new dynamic structural model. , 2013, ACS nano.

[4]  G. Eda,et al.  Graphene oxide as a chemically tunable platform for optical applications. , 2010, Nature chemistry.

[5]  El Mokhtar Essassi,et al.  Piezoelectric β-polymorph formation and properties enhancement in graphene oxide – PVDF nanocomposite films , 2012 .

[6]  M. Dresselhaus,et al.  Raman spectroscopy in graphene , 2009 .

[7]  Stephen U. S. Choi,et al.  Role of Brownian motion in the enhanced thermal conductivity of nanofluids , 2004 .

[8]  Yanwu Zhu,et al.  Reduction Kinetics of Graphene Oxide Determined by Electrical Transport Measurements and Temperature Programmed Desorption , 2009 .

[9]  H. Azizi-Toupkanloo,et al.  Silver colloid nanoparticles: Ultrasound-assisted synthesis, electrical and rheological properties , 2013 .

[10]  U. Pal,et al.  Effects of crystallization and dopant concentration on the emission behavior of TiO2:Eu nanophosphors , 2012, Nanoscale Research Letters.

[11]  J. Maxwell A Treatise on Electricity and Magnetism , 1873, Nature.

[12]  W. Lu,et al.  Improved synthesis of graphene oxide. , 2010, ACS nano.

[13]  F. Carrique,et al.  Electrical conductivity of aqueous salt-free concentrated suspensions. Effects of water dissociation and CO2 contamination. , 2009, Journal of Physical Chemistry B.

[14]  Shuangfeng Wang,et al.  Silicone based nanofluids containing functionalized graphene nanosheets , 2013 .

[15]  Hui-Ming Cheng,et al.  Synthesis of high-quality graphene with a pre-determined number of layers , 2009 .

[16]  Aijun Du,et al.  A water-dielectric capacitor using hydrated graphene oxide film , 2012 .

[17]  Sang-Jae Kim,et al.  The chemical and structural analysis of graphene oxide with different degrees of oxidation , 2013 .

[18]  H. Azizi-Toupkanloo,et al.  Structural, electrical, and rheological properties of palladium/silver bimetallic nanoparticles prepared by conventional and ultrasonic-assisted reduction methods , 2014 .

[19]  J. Miyawaki,et al.  Preparation of nitrogen-doped graphene sheets by a combined chemical and hydrothermal reduction of graphene oxide. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[20]  G. Amato A new approach in the optical characterization of amorphous hydrogenated silicon-carbon alloys , 1991 .

[21]  H. Ahmadzadeh,et al.  NANOFLUIDS FOR HEAT TRANSFER ENHANCEMENT-A REVIEW , 2013 .

[22]  J. Ko,et al.  Hydrothermal preparation of nitrogen-doped graphene sheets via hexamethylenetetramine for application as supercapacitor electrodes , 2012 .

[23]  Shashi Jain,et al.  Brownian dynamic simulation for the prediction of effective thermal conductivity of nanofluid , 2009 .

[24]  M I Katsnelson,et al.  Modeling of graphite oxide. , 2008, Journal of the American Chemical Society.

[25]  E. Goharshadi,et al.  Effect of calcination temperature on structural, vibrational, optical, and rheological properties of zirconia nanoparticles , 2012 .

[26]  H. Fu,et al.  Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage , 2012 .

[27]  E. Goharshadi,et al.  Preparation, characterization, and rheological properties of graphene–glycerol nanofluids , 2013 .

[28]  S. Chakraborty,et al.  Anomalous electrical conductivity of nanoscale colloidal suspensions. , 2008, ACS nano.

[29]  Seyed Mojtaba Zebarjad,et al.  Fabrication, characterization and measurement of thermal conductivity of Fe3O4 nanofluids , 2010 .

[30]  Madhusree Kole,et al.  Thermal conductivity and viscosity of Al2O3 nanofluid based on car engine coolant , 2010 .

[31]  Jacek Klinowski,et al.  Structure of Graphite Oxide Revisited , 1998 .

[32]  M. Iqbal,et al.  Rheology and microstructure of dilute graphene oxide suspension , 2013, Journal of Nanoparticle Research.

[33]  Qiang Zhang,et al.  Enhanced rifampicin delivery to alveolar macrophages by solid lipid nanoparticles , 2013, Journal of Nanoparticle Research.

[34]  M. Dresselhaus,et al.  Studying disorder in graphite-based systems by Raman spectroscopy. , 2007, Physical chemistry chemical physics : PCCP.

[35]  A. Shih,et al.  Investigation of the electrical conductivity of propylene glycol-based ZnO nanofluids , 2011, Nanoscale research letters.

[36]  R. J. Hunter Zeta potential in colloid science : principles and applications , 1981 .

[37]  Michael S Strano,et al.  Understanding the pH-dependent behavior of graphene oxide aqueous solutions: a comparative experimental and molecular dynamics simulation study. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[38]  Jun Tang,et al.  Functional graphene oxide as a plasmid-based Stat3 siRNA carrier inhibits mouse malignant melanoma growth in vivo , 2013, Nanotechnology.

[40]  Z. Dohcevic-Mitrovic,et al.  Influence of Fe3+-doping on optical properties of CeO2−y nanopowders , 2013 .

[41]  Alina Adriana Minea,et al.  Investigations on electrical conductivity of stabilized water based Al2O3 nanofluids , 2012 .

[42]  Mohammad Mahdi Heyhat,et al.  Enhancement of thermal conductivity of silver nanofluid synthesized by a one-step method with the effect of polyvinylpyrrolidone on thermal behavior , 2013 .

[43]  J. Hao,et al.  Thermal conductivity and rheological properties of graphite/oil nanofluids , 2012 .

[44]  Neelkanth M. Bardhan,et al.  Scalable enhancement of graphene oxide properties by thermally driven phase transformation. , 2014, Nature chemistry.

[45]  S. Ramaprabhu,et al.  Synthesis and nanofluid application of silver nanoparticles decorated graphene , 2011 .

[46]  R. Ruoff,et al.  Chemical methods for the production of graphenes. , 2009, Nature nanotechnology.

[47]  Somnath Basu,et al.  Experimental investigation of the effective electrical conductivity of aluminum oxide nanofluids , 2009 .

[48]  C. Reynaud,et al.  Thermal and electrical conductivities of water-based nanofluids prepared with long multiwalled carbon nanotubes , 2008 .

[49]  Helmut Schaefer,et al.  Inkjettable conductive adhesive for use in microelectronics and microsystems technology , 2005, Polytronic 2005 - 5th International Conference on Polymers and Adhesives in Microelectronics and Photonics.

[50]  A. Ganguli,et al.  Enhanced functionalization of Mn2O3@SiO2 core-shell nanostructures , 2011, Nanoscale research letters.

[51]  Fude Nie,et al.  Facile solvothermal synthesis of graphene–MnOOH nanocomposites , 2010 .

[52]  C. Nan,et al.  Effective thermal conductivity of particulate composites with interfacial thermal resistance , 1997 .

[53]  Huaqing Xie,et al.  Silicon oil based multiwalled carbon nanotubes nanofluid with optimized thermal conductivity enhancement , 2009 .

[54]  Pawan K. Singh,et al.  Electrical conductivity of ceramic and metallic nanofluids , 2013 .

[55]  E. Mijowska,et al.  Controlled oxidation of graphite to graphene oxide with novel oxidants in a bulk scale , 2012, Journal of Nanoparticle Research.

[56]  J. J. Gracio,et al.  Surface Modification of Graphene Nanosheets with Gold Nanoparticles: The Role of Oxygen Moieties at Graphene Surface on Gold Nucleation and Growth , 2009 .

[57]  S. Ramaprabhu,et al.  Investigation of thermal and electrical conductivity of graphene based nanofluids , 2010 .

[58]  A. Jacobi,et al.  Ultrasonication effects on thermal and rheological properties of carbon nanotube suspensions , 2012, Nanoscale Research Letters.

[59]  E. Goharshadi,et al.  Volume fraction and temperature variations of the effective thermal conductivity of nanodiamond fluids in deionized water , 2010 .

[60]  Solomon,et al.  Band structure of carbonated amorphous silicon studied by optical, photoelectron, and x-ray spectroscopy. , 1988, Physical review. B, Condensed matter.

[61]  Ado Jorio,et al.  General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy , 2006 .

[62]  Shaomin Liu,et al.  Fabrication, characterization, and photocatalytic property of α-Fe2O3/graphene oxide composite , 2013, Journal of Nanoparticle Research.

[63]  Brian B. Glover,et al.  Effective electrical conductivity of functional single-wall carbon nanotubes in aqueous fluids , 2008 .

[64]  R. C. Weast CRC Handbook of Chemistry and Physics , 1973 .

[65]  T. K. Dey,et al.  Investigation of thermal conductivity, viscosity, and electrical conductivity of graphene based nanofluids , 2013 .

[66]  F. Tuinstra,et al.  Raman Spectrum of Graphite , 1970 .

[67]  E. Goharshadi,et al.  Fabrication, characterization, and measurement of some physicochemical properties of ZnO nanofluids , 2010 .

[68]  Wei Chen,et al.  Experimental investigation on thermal conductivity of nanofluids containing graphene oxide nanosheets , 2010 .

[69]  Álvaro Somoza,et al.  Synthesis and surface modification of uniform MFe2O4 (M = Fe, Mn, and Co) nanoparticles with tunable sizes and functionalities , 2012, Journal of Nanoparticle Research.

[70]  Fangfang Wu,et al.  Graphene oxide: the mechanisms of oxidation and exfoliation , 2012, Journal of Materials Science.

[71]  Huaqing Xie,et al.  Significant thermal conductivity enhancement for nanofluids containing graphene nanosheets , 2011 .

[72]  Y. Chabal,et al.  A Review on Reducing Graphene Oxide for Band Gap Engineering , 2012 .

[73]  M. Mehrali,et al.  Investigation of thermal conductivity and rheological properties of nanofluids containing graphene nanoplatelets , 2014, Nanoscale Research Letters.

[74]  Thirumalachari Sundararajan,et al.  An experimental investigation into the thermal conductivity enhancement in oxide and metallic nanofluids , 2010 .

[75]  Y. Hwang,et al.  Photoluminescence characteristics of Cd1-xMnxTe single crystals grown by the vertical Bridgman method , 2012, Nanoscale Research Letters.

[76]  Huaqing Xie,et al.  Enhanced thermal conductivities of nanofluids containing graphene oxide nanosheets , 2010, Nanotechnology.

[77]  T. V. Venkatesha,et al.  Preparation and corrosion behavior of Ni and Ni–graphene composite coatings , 2013 .

[78]  Hanbin Wang,et al.  Investigation on the electrical conductivity of transformer oil-based AlN nanofluid , 2013 .

[79]  L. P. Shen,et al.  Solvothermal synthesis and electrical conductivity model for the zinc oxide-insulated oil nanofluid , 2012 .

[80]  H. Shin,et al.  Control of size and physical properties of graphene oxide by changing the oxidation temperature , 2012 .