Controlled intensity emission from patterned porous silicon using focused proton beam irradiation

We have fabricated light emitting porous silicon micropatterns with controlled emission intensity. This has been achieved by direct write irradiation in heavily doped p-type silicon (0.02Ωcm) using a 2MeV proton beam, focused to a spot size of 200nm. After electrochemical etching in hydrofluoric acid, enhanced photoluminescence is observed from the irradiated regions. The intensity of light emission is proportional to the dose of the proton beam, so the PL intensity of the micropattern can be tuned and varied between adjacent regions on a single substrate. This behavior is in contrast to previous ion beam patterning of p-type silicon, as light is preferentially created as opposed to quenched at the irradiated regions.

[1]  Andrew A. Bettiol,et al.  The National University of Singapore high energy ion nano-probe facility: Performance tests☆ , 2003 .

[2]  I. Berbezier,et al.  Sub-micrometre luminescent porous silicon structures using lithographically patterned substrates , 1995 .

[3]  Andrew A. Bettiol,et al.  A LabVIEW™-based scanning and control system for proton beam micromachining , 2001 .

[4]  D. Dimos,et al.  Ion‐irradiation control of photoluminescence from porous silicon , 1991 .

[5]  M. Sailor,et al.  Photolithographic fabrication of micron‐dimension porous Si structures exhibiting visible luminescence , 1992 .

[6]  Z. Gaburro,et al.  EFFECT OF RESISTIVITY AND CURRENT DENSITY ON PHOTOLUMINESCENCE IN POROUS SILICON PRODUCED AT LOW HF CONCENTRATION , 1998 .

[7]  Andrew A. Bettiol,et al.  Three-dimensional microfabrication in bulk silicon using high-energy protons , 2004 .

[8]  A. Steckl,et al.  Doping-induced selective area photoluminescence in porous silicon , 1993 .

[9]  D. J. Lockwood,et al.  LIGHT EMITTING MICROPATTERNS OF POROUS SI CREATED AT SURFACE DEFECTS , 1998 .

[10]  L. Canham Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers , 1990 .

[11]  K. D. Hirschman,et al.  Silicon-based visible light-emitting devices integrated into microelectronic circuits , 1996, Nature.

[12]  Andrew A. Bettiol,et al.  Three-dimensional micromachining of silicon using a nuclear microprobe , 2004 .

[13]  Direct micropatterning of Si and GaAs using electrochemical development of focused ion beam implants , 1998 .

[14]  Control of porous silicon luminescent pattern formation by ion implantation , 1993 .

[15]  Improvement in the photoluminescence efficiency of porous silicon using high-energy silicon ion irradiation , 1996 .

[16]  S. Kurinec,et al.  Enhancement and suppression of the formation of porous silicon , 1995 .

[17]  Sumio Matsuda,et al.  High-energy and high-fluence proton irradiation effects in silicon solar cells , 1996 .