Effect of substrate temperature on the properties of deep ultraviolet transparent conductive ITO/Ga2O3 films

ITO/Ga2O3 bi-layer films were deposited on quartz glass substrates by magnetron sputtering. The effect of substrate temperature on the structure, surface morphology, optical and electrical properties of ITO/Ga2O3 films was investigated by an X-ray diffractometer, a scanning electron microscope, a double beam spectrophotometer and the Hall system, respectively. The structural characteristics showed a dependence on substrate temperature. The resistivity of the films varied from 6.71 × 10−3 to 1.91 × 10−3 Ω·cm as the substrate temperature increased from 100 to 350 °C. ITO (22 nm)/Ga2O3 (50 nm) films deposited at 300 °C exhibited a low sheet resistance of 373.3 Ω/□ and high deep ultraviolet transmittance of 78.97% at the wavelength of 300 nm.

[1]  B. Chiou,et al.  Effect of annealing on electrical and optical properties of RF magnetron sputtered indium tin oxide films , 1993 .

[2]  Hideo Hosono,et al.  Synthesis and control of conductivity of ultraviolet transmitting β-Ga2O3 single crystals , 1997 .

[3]  Hamberg,et al.  Band-gap tailoring of ZnO by means of heavy Al doping. , 1988, Physical review. B, Condensed matter.

[4]  K. Itoyama Properties of Sn-Doped Indium Oxide Prepared by High Rate and Low Temperature RF Sputtering , 1978 .

[5]  Li-Jian Meng,et al.  Properties of indium tin oxide films prepared by rf reactive magnetron sputtering at different substrate temperature , 1998 .

[6]  C. Guillén,et al.  Influence of oxygen in the deposition and annealing atmosphere on the characteristics of ITO thin films prepared by sputtering at room temperature , 2006 .

[7]  N. G. Patel,et al.  Conducting transparent indium-tin oxide films by post-deposition annealing in different humidity environments , 1992 .

[8]  J. Tauc,et al.  Amorphous and liquid semiconductors , 1974 .

[9]  K. Ellmer,et al.  Carrier transport in polycrystalline ITO and ZnO:Al II: The influence of grain barriers and boundaries , 2008 .

[10]  M. Al-Kuhaili,et al.  Optical properties of gallium oxide films deposited by electron-beam evaporation , 2003 .

[11]  El-Hang Lee,et al.  Dependence of the resistivity and the transmittance of sputter-deposited Ga-doped ZnO films on oxygen partial pressure and sputtering temperature , 2007 .

[12]  H. Ohta,et al.  Preparation of highly conductive, deep ultraviolet transparent β-Ga2O3 thin film at low deposition temperatures , 2002 .

[13]  Hyoun-woo Kim,et al.  Growth of gallium oxide thin films on silicon by the metal organic chemical vapor deposition method , 2004 .

[14]  Hideo Hosono,et al.  Deep-ultraviolet transparent conductive β-Ga2O3 thin films , 2000 .

[15]  K. Ellmer,et al.  Carrier transport in polycrystalline transparent conductive oxides: A comparative study of zinc oxide and indium oxide , 2008 .