Carbon nanostructures as sorbent materials in analytical processes

Over time, new materials have been used and incorporated in a wide variety of analytical processes. This century, technology has produced novel nanomaterials with unique properties whose use has increased in analytical sciences. Carbon nanostructures are among these new nanomaterials. This overview reports on the use of carbon nanomaterials, mainly fullerenes and carbon nanotubes, as sorbents in the analytical process. After a brief description of their main characteristics, we present their use in the development of selective membranes. Next, we describe their role as sorbent materials and stationary phases in chromatography and provide relevant examples. We also comment on the presence of carbon nanoparticles as components of electrophoretic buffers to improve both resolution and sensitivity of separations. Finally, we briefly describe other applications in which the sorption capabilities of carbon nanostructures play a role.

[1]  S. C. O'brien,et al.  C60: Buckminsterfullerene , 1985, Nature.

[2]  Yujie Ding,et al.  Simultaneous Determination of Cyanazine, Chlorotoluron and Chlorbenzuron in Environmental Water Samples with SPE Multiwalled Carbon Nanotubes and LC , 2006 .

[3]  D. Yuan,et al.  Evaluation of multi-walled carbon nanotubes as gas chromatographic column packing. , 2003, Journal of chromatography. A.

[4]  Craig A. Grimes,et al.  Gas sensing characteristics of multi-wall carbon nanotubes , 2001 .

[5]  G. Galli,et al.  Optical properties and structure of nanodiamonds , 2005 .

[6]  Guoguang Liu,et al.  Determination of atrazine and simazine in environmental water samples using multiwalled carbon nanotubes as the adsorbents for preconcentration prior to high performance liquid chromatography with diode array detector. , 2006, Talanta.

[7]  C. Wu,et al.  Use of polymeric fullerene as a new coating for solid-phase microextraction , 2000 .

[8]  S. Mitra,et al.  Gas chromatography on self-assembled, single-walled carbon nanotubes. , 2006, Analytical chemistry.

[9]  Mainak Majumder,et al.  Nanoscale hydrodynamics: Enhanced flow in carbon nanotubes , 2005, Nature.

[10]  M. Valcárcel,et al.  Speciation analysis of mercury and tin compounds in water and sediments by gas chromatography–mass spectrometry following preconcentration on C60 fullerene , 2005 .

[11]  M. Yudasaka,et al.  Adsorption and catalytic properties of single-wall carbon nanohorns , 2000 .

[12]  J. Xing,et al.  Hydroxyfullerene as a novel coating for solid-phase microextraction fiber with sol-gel technology. , 2002, Journal of chromatography. A.

[13]  David L. Carroll,et al.  Carbon Nanotubols from Mechanochemical Reaction , 2003 .

[14]  M Valcárcel,et al.  Role of carbon nanotubes in analytical science. , 2007, Analytical chemistry.

[15]  K. Bartle,et al.  HIGH-PRESSURE MICROCOLUMN GAS CHROMATOGRAPHY , 1998 .

[16]  Mainak Majumder,et al.  Nanoscale hydrodynamics: Enhanced flow in carbon nanotubes , 2005 .

[17]  W. Baeyens,et al.  Enhanced separation of purine and pyrimidine bases using carboxylic multiwalled carbon nanotubes as additive in capillary zone electrophoresis , 2006, Electrophoresis.

[18]  S. Mitra,et al.  Chromatography on self-assembled carbon nanotubes. , 2005, Analytical chemistry.

[19]  Miguel Valcárcel,et al.  Surfactant‐coated single‐walled carbon nanotubes as a novel pseudostationary phase in capillary EKC , 2007, Electrophoresis.

[20]  D. Sholl,et al.  Rapid transport of gases in carbon nanotubes. , 2002, Physical review letters.

[21]  A. Merkoçi Carbon Nanotubes in Analytical Sciences , 2006 .

[22]  M. Valcárcel,et al.  Effectiveness of fullerene as a sorbent for the determination of trace amounts of cobalt in wheat flour by electrothermal atomic absorption spectrometry , 1999 .

[23]  Jordi Riu,et al.  Nanosensors in environmental analysis. , 2006, Talanta.

[24]  M. Valcárcel,et al.  Fullerenes as Sorbent Materials for Metal Preconcentration , 1994 .

[25]  Guibin Jiang,et al.  Multiwalled carbon nanotubes as a solid-phase extraction adsorbent for the determination of bisphenol A, 4-n-nonylphenol, and 4-tert-octylphenol. , 2003, Analytical chemistry.

[26]  M. Valcárcel,et al.  Surfactant coated fullerenes C60 as pseudostationary phase in electrokinetic chromatography. , 2007, Journal of chromatography. A.

[27]  D. L. Baldwin,et al.  Single-walled carbon nanotube paper as a sorbent for organic vapor preconcentration. , 2006, Analytical chemistry.

[28]  R. T. Yang,et al.  Carbon nanotubes as superior sorbent for dioxin removal. , 2001, Journal of the American Chemical Society.

[29]  R. Pereiro,et al.  The use of luminescent quantum dots for optical sensing , 2006 .

[30]  G. Luo,et al.  Carbon nanotubes as separation carrier in capillary electrophoresis , 2003, Electrophoresis.

[31]  Xiu‐Ping Yan,et al.  Multiwalled carbon nanotubes coated fibers for solid-phase microextraction of polybrominated diphenyl ethers in water and milk samples before gas chromatography with electron-capture detection. , 2006, Journal of chromatography. A.

[32]  Baena,et al.  Speciation of inorganic lead and ionic alkyllead compounds by GC/MS in prescreened rainwaters , 2000, Analytical chemistry.

[33]  J. Kong,et al.  On‐chip chiral separation based on bovine serum albumin‐conjugated carbon nanotubes as stationary phase in a microchannel , 2006, Electrophoresis.

[34]  S. Sinnott,et al.  Separation of Organic Molecular Mixtures in Carbon Nanotubes and Bundles: Molecular Dynamics Simulations , 2001 .

[35]  Zhongyi Jiang,et al.  Novel ploy(vinyl alcohol)/carbon nanotube hybrid membranes for pervaporation separation of benzene/cyclohexane mixtures , 2007 .

[36]  C. Basheer,et al.  Development and application of porous membrane-protected carbon nanotube micro-solid-phase extraction combined with gas chromatography/mass spectrometry. , 2006, Analytical chemistry.

[37]  M. Prato,et al.  Carbon nanotubes on HPLC silica microspheres , 2006 .

[38]  M. Valcárcel,et al.  Analytical potential of fullerene as adsorbent for organic and organometallic compounds from aqueous solutions. , 2000, Journal of chromatography. A.

[39]  Qingxiang Zhou,et al.  Using multi-walled carbon nanotubes as solid phase extraction adsorbents to determine dichlorodiphenyltrichloroethane and its metabolites at trace level in water samples by high performance liquid chromatography with UV detection. , 2006, Journal of chromatography. A.

[40]  Mool C. Gupta,et al.  The fabrication and electrical properties of carbon nanofibre–polystyrene composites , 2004 .

[41]  K. Pyrzyńska Application of Carbon Sorbents for the Concentration and Separation of Metal Ions , 2007, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[42]  L. Kubota,et al.  Solid-phase extraction system for Pb (II) ions enrichment based on multiwall carbon nanotubes coupled on-line to flame atomic absorption spectrometry. , 2007, Talanta.

[43]  S. Han,et al.  Application of the polysilicone fullerene coating for solid-phase microextraction in the determination of semi-volatile compounds. , 2001, Journal of chromatography. A.

[44]  M. Valcárcel,et al.  Evaluation of carbon nanostructures as chiral selectors for direct enantiomeric separation of ephedrines by EKC , 2007, Electrophoresis.

[45]  Hongjie Dai,et al.  Carbon nanotubes: opportunities and challenges , 2002 .

[46]  Rodney Andrews,et al.  Aligned Multiwalled Carbon Nanotube Membranes , 2004, Science.

[47]  M. Valcárcel,et al.  Development of a method for the determination of inorganic cadmium and cadmium metallothioneins in fish liver by continuous preconcentration on fullerene and flame atomic absorption spectrometry , 2002 .

[48]  Qixin Zheng,et al.  Synthesis and application of new fullerene derivative , 2005 .

[49]  Charles M. Lieber,et al.  Probing Electrical Transport in Nanomaterials: Conductivity of Individual Carbon Nanotubes , 1996, Science.

[50]  M Valcárcel,et al.  Determination of non-steroidal anti-inflammatory drugs in urine by combining an immobilized carboxylated carbon nanotubes minicolumn for solid-phase extraction with capillary electrophoresis-mass spectrometry. , 2007, Journal of chromatography. A.

[51]  L. Pfefferle,et al.  Incorporation of single-wall carbon nanotubes into an organic polymer monolithic stationary phase for mu-HPLC and capillary electrochromatography. , 2005, Analytical chemistry.

[52]  Zheng-Yu Li,et al.  Single-walled carbon nanotubes used as stationary phase in GC. , 2006, Analytical chemistry.

[53]  L. Kartsova,et al.  New Fullerene-Based Stationary Phases for Gas Chromatography , 2004 .

[54]  Yan Liu,et al.  Multiwalled carbon nanotubes as solid-phase extraction adsorbent for the preconcentration of trace metal ions and their determination by inductively coupled plasma atomic emission spectrometry , 2004 .

[55]  Guozhen Fang,et al.  Multiwalled carbon nanotubes as sorbent for on-line coupling of solid-phase extraction to high-performance liquid chromatography for simultaneous determination of 10 sulfonamides in eggs and pork. , 2006, Journal of chromatography. A.

[56]  Marek Trojanowicz,et al.  Analytical applications of carbon nanotubes : a review , 2006 .

[57]  I. Alexandrou,et al.  Characterisation of carbon nano-onions using Raman spectroscopy , 2003 .

[58]  M. Valcárcel,et al.  Surfactant-coated carbon nanotubes as pseudophases in liquid-liquid extraction. , 2007, The Analyst.

[59]  F. Borrull,et al.  New hydrophilic materials for solid-phase extraction , 2005 .

[60]  J. H. Whealton,et al.  Controlled alignment of carbon nanofibers in a large-scale synthesis process , 2002 .

[61]  Liping Wang,et al.  Multiwalled carbon nanotubes as a solid-phase extraction adsorbent for the determination of three barbiturates in pork by ion trap gas chromatography-tandem mass spectrometry (GC/MS/MS) following microwave assisted derivatization. , 2007, Analytica chimica acta.

[62]  R. A. McGill,et al.  Fullerene as an adsorbent for gases and vapours , 1993 .

[63]  Jang‐Kyo Kim,et al.  Effects of silane functionalization on the properties of carbon nanotube/epoxy nanocomposites , 2007 .

[64]  P. Liang,et al.  Application of multiwalled carbon nanotubes as solid phase extraction sorbent for preconcentration of trace copper in water samples. , 2005, Journal of separation science.

[65]  A. Serrano,et al.  Fullerenes as sorbent materials for benzene, toluene, ethylbenzene, and xylene isomers preconcentration. , 2006, Journal of separation science.

[66]  Qingxiang Zhou,et al.  Comparison of Multiwalled Carbon Nanotubes and a Conventional Absorbent on the Enrichment of Sulfonylurea Herbicides in Water Samples , 2007, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[67]  H. Kanoh,et al.  Structures and stability of water nanoclusters in hydrophobic nanospaces. , 2005, Nano letters.

[68]  S. Shinkai,et al.  Ring Closure of Carbon Nanotubes , 2001, Science.

[69]  C. Poole New trends in solid-phase extraction , 2003 .

[70]  W. Baeyens,et al.  On the use of dispersed nanoparticles modified with single layer beta-cyclodextrin as chiral selecor to enhance enantioseparation of clenbuterol with capillary electrophoresis. , 2006, Talanta.

[71]  N. Chopra,et al.  Reversible Biochemical Switching of Ionic Transport through Aligned Carbon Nanotube Membranes , 2005 .

[72]  A. Noy,et al.  Ultrafast gas chromatography on single-wall carbon nanotube stationary phases in microfabricated channels. , 2006, Analytical chemistry.

[73]  Mainak Majumder,et al.  Effect of tip functionalization on transport through vertically oriented carbon nanotube membranes. , 2005, Journal of the American Chemical Society.

[74]  P. Brown,et al.  Novel approach to the analysis and use of fullerenes in capillary electrophoresis. , 2000, Journal of chromatography. A.

[75]  Yan Xu,et al.  Carbon nanotube‐enhanced separation of DNA fragments by a portable capillary electrophoresis system with contactless conductivity detection , 2006, Electrophoresis.