High quality sugarcane bagasse-citric acid particleboards

The productivity of Indonesian sugarcane plantation, especially in East Java province reached 1.186.515 tonnes in 2017. Sugarcane liquid is extracted as sugar raw material and set aside sugarcane bagasse as waste of about 30% from total sugarcane weight. Usually sugarcane bagasse is burned to operate boiler in sugarcane mill. Meanwhile, the utilization of sugarcane bagasse, combine with citric acid for high quality particleboards production would be highly recommended. In this study, effect of citric acid content and pressing temperature on sugarcane particleboards properties were analysed. The size and target density of particleboards were 300 x 300 x 9 mm and 0.8 g/cm3, respectively. Citric acid liquid (59%) were sprayed onto sugarcane particles, with varied citric acid content (10, 15, 20 % of sugarcane particle weight). To evaporate water, sugarcane particles which already contain citric acid were pre-dried in oven of 80°C for 6h until the moisture content in sugarcane particles-citric acid was less than 3%. Subsequently, the boards were produced under pressing temperature of 180°C and 200°C, for 10 min. The physical properties of boards produced using 25% citric acid and pressed at 200°C (thickness swelling 4.43%; water absorption 29.48%) were superior than the others boards. The infrared (IR) spectra analysis showed the presence of ester linkage, representing that the carboxyl groups of citric acid had reacted with the hydroxyl groups of the sugarcane particles, providing the boards good physical properties. The boards mechanical properties were fulfilled the requirement of the JIS A 5908:2003 for particleboards type 18 (modulus of rupture 21.88 N/mm2, modulus of elasticity 3944 N/mm2, internal bond 1.03 N/mm2, screw withdrawal 393 N).

[1]  Subyakto,et al.  Effect of pre-drying time and citric acid content on Imperata cylindrica particleboards properties , 2018, IOP Conference Series: Earth and Environmental Science.

[2]  T. Yoshimura,et al.  Utilization of sweet sorghum bagasse and citric acid in the manufacturing of particleboard. III: Influence of adding sucrose on the properties of particleboard , 2017, BioResources.

[3]  T. Yoshimura,et al.  Utilization of sweet sorghum bagasse and citric acid for manufacturing of particleboard II: influences of pressing temperature and time on particleboard properties , 2017, Journal of Wood Science.

[4]  Koichi Yoshioka,et al.  Utilization of sweet sorghum bagasse and citric acid for manufacturing of particleboard I: Effects of pre-drying treatment and citric acid content on the board properties , 2016 .

[5]  K. Umemura,et al.  Low Density Sugarcane Bagasse Particleboard Bonded with Citric Acid and Sucrose: Effect of board density and additive content , 2016 .

[6]  T. A. Prayitno,et al.  Manufacture and properties of citric acid-bonded particleboard made from bamboo materials , 2015, European Journal of Wood and Wood Products.

[7]  G. Moates,et al.  Wheat straw hemicellulose films as affected by citric acid , 2015 .

[8]  Daihui Zhang,et al.  A review of preparation of binderless fiberboards and its self-bonding mechanism , 2015, Wood Science and Technology.

[9]  Noureddine Abidi,et al.  Changes in the cell wall and cellulose content of developing cotton fibers investigated by FTIR spectroscopy. , 2014, Carbohydrate polymers.

[10]  F. Antunes,et al.  Bioconversion of Sugarcane Biomass into Ethanol: An Overview about Composition, Pretreatment Methods, Detoxification of Hydrolysates, Enzymatic Saccharification, and Ethanol Fermentation , 2012, Journal of biomedicine & biotechnology.

[11]  K. Umemura,et al.  Application of citric acid as natural adhesive for wood , 2012 .

[12]  K. Umemura,et al.  Characterization of wood-based molding bonded with citric acid , 2011, Journal of Wood Science.

[13]  R Maciel Filho,et al.  Production of bioethanol, methane and heat from sugarcane bagasse in a biorefinery concept. , 2011, Bioresource technology.

[14]  I. Stamatin,et al.  QUANTITATIVE INVESTIGATION OF WOOD COMPOSITION BY INTEGRATED FT-IR AND THERMOGRAVIMETRIC METHODS , 2011 .

[15]  Tatiana Todorciuc,et al.  CHARACTERIZATION OF NON-WOOD LIGNIN AND ITS HYDOXYMETHYLATED DERIVATIVES BY SPECTROSCOPY AND SELF-ASSEMBLING INVESTIGATIONS , 2010 .

[16]  Dong Il Yoo,et al.  FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. , 2005, Carbohydrate research.

[17]  J. Grdadolnik,et al.  An infrared spectroscopic study of H-bond network in hyperbranched polyester polyol , 2003 .

[18]  Charles Q. Yang,et al.  FT-IR spectroscopy study of the polycarboxylic acids used for paper wet strength improvement , 1996 .