New solutions to the fragmentation equation

A new general class of exact, explicit scaling solutions to the fragmentation equation is given. This class is described by a breakage rate a(x)=xlambda and the daughter distribution function yb(x mod y)=a gamma (xy)gamma -2+(1-a) delta (x/y)delta -2, and includes as special cases all previously-known scaling solutions to the fragmentation equation. For a subset of this class, with gamma = lambda and a= delta /( delta - lambda ), the complete time-dependent solution for a monodisperse initial condition is also given.

[1]  H. Jellinek,et al.  The degradation of long‐chain molecules by ultrasonic waves. I. Theoretical , 1951 .

[2]  P. C. Kapur A similarity solution to an integro-differential equation describing batch grinding , 1970 .

[3]  B. Wolf,et al.  Degradation of chain molecules. 1. Exact solution of the kinetic equations , 1981 .

[4]  Robert M. Ziff,et al.  Kinetics of polymer degradation , 1986 .

[5]  Z. A. Melzak A scalar transport equation , 1957 .

[6]  E. Montroll,et al.  Theory of Depolymerization of Long Chain Molecules , 1940 .

[7]  K. Almin,et al.  Length reduction of fibres subject to breakage , 1966 .

[8]  Doraiswami Ramkrishna Drop-breakage in agitated liquid—liquid dispersions , 1974 .

[9]  Edwards,et al.  Rate equation and scaling for fragmentation with mass loss. , 1990, Physical review. A, Atomic, molecular, and optical physics.

[10]  M. Williams An Exact Solution of the Fragmentation Equation , 1990 .

[11]  S. Goren Distribution of lengths in the breakage of fibres or linear polymers , 1968 .

[12]  O. Saito On the Effect of High Energy Radiation to Polymers I. Cross-linking and Degradation , 1958 .

[13]  M. A. Mostafa,et al.  Degradation of addition polymers by ultrasonic waves , 1956 .

[14]  H. Kehlen,et al.  Continuous kinetics of first order degradation reactions in polydisperse mixtures , 1988 .

[15]  A. Charlesby Molecular-weight changes in the degradation of long-chain polymers , 1954, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[16]  A. F. Filippov On the Distribution of the Sizes of Particles which Undergo Splitting , 1961 .

[17]  Klaus H. Ebert,et al.  Kinetic Studies on the Acid Hydrolysis of Dextran , 1978 .

[18]  Cheng,et al.  Scaling theory of fragmentation. , 1988, Physical review letters.

[19]  Thomas W. Peterson,et al.  Similarity Solutions for the Population Balance Equation Describing Particle Fragmentation , 1986 .

[20]  Leonard G. Austin,et al.  Introduction to the mathematical description of grinding as a rate process , 1971 .

[21]  Robert M. Ziff,et al.  The kinetics of cluster fragmentation and depolymerisation , 1985 .

[22]  R. Ziff,et al.  "Shattering" transition in fragmentation. , 1987, Physical review letters.

[23]  S. Redner,et al.  Kinetics of fragmentation , 1990 .

[24]  Robert Simha,et al.  Kinetics of Degradation and Size Distribution of Long Chain Polymers , 1941 .