Development of highly sensitive nitrogen dioxide monitoring device and its application to wide-area ubiquitous network

Abstract We have developed an NO2 sensing device with high time resolution for application to a wide-area ubiquitous network. The NO2 sensing device employs the colorimetric reaction between NO2 and diazo-coupling reagents. We estimated the formation and decomposition rate of the azo dye in the sensor elements and found that no decomposition occurred and that the formation rate was fast enough for us to measure NO2 concentration at 10 min intervals with a detection limit of 12 ppb. We have constructed sensing terminal units containing the NO2 sensing device, a GPS device, a compass, a switch, LEDs and a wireless terminal unit for a wide-area ubiquitous network. We successfully monitored the outdoor NO2 level at 10 min intervals using the developed terminal units mounted on a bicycle in certain areas of several cities. We also designed and implemented an application where bicycles collect geo-tagged air quality samples and post them on a map that other cyclists can use to determine their route.

[1]  Masahiro Umehira,et al.  Wide area ubiquitous network: the network operator's view of a sensor network , 2008, IEEE Communications Magazine.

[2]  Sotiris Vardoulakis,et al.  Assessment of traffic-related air pollution in two street canyons in Paris: implications for exposure studies , 2002 .

[3]  S. Muttamara,et al.  Monitoring and Assessment of Exhaust Emission in Bangkok Street Air , 2000 .

[4]  Ilias Mavroidis,et al.  Compliance with the annual NO2 air quality standard in Athens. Required NOx levels and expected health implications , 2008 .

[5]  Kengo Shimanoe,et al.  Cr-doped TiO2 gas sensor for exhaust NO2 monitoring , 2003 .

[6]  K. Nagashima,et al.  Development of a Detection Tablet for a Portable NO_2 Monitoring System , 2006, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[7]  Jérôme Brunet,et al.  An optimised gas sensor microsystem for accurate and real-time measurement of nitrogen dioxide at ppb level , 2008 .

[8]  D. Laxen,et al.  Nitrogen dioxide distribution in street canyons , 1987 .

[9]  H. Ishida,et al.  Gas sensor network for air-pollution monitoring , 2005 .

[10]  S. Vardoulakis,et al.  Comparative evaluation of nitrogen oxides and ozone passive diffusion tubes for exposure studies , 2009 .

[11]  Kerrie Mengersen,et al.  Methodology for assessing exposure and impacts of air pollutants in school children: Data collection, analysis and health effects – A literature review , 2011 .

[12]  Yasuko Yamada Maruo,et al.  Coloration reactions between NO2 and organic compounds in porous glass for cumulative gas sensor , 1998 .

[13]  Ki-Hyun Kim,et al.  Long-term trend in NO2 and NOx levels and their emission ratio in relation to road traffic activities in East Asia , 2011 .

[14]  T. Bush,et al.  Five years of nitrogen dioxide measurement with diffusion tube samplers at over 1000 sites in the UK , 2001 .

[15]  C. Johansson,et al.  The effects of congestions tax on air quality and health. , 2009 .

[16]  D. Niemeier,et al.  Near-roadway air quality: synthesizing the findings from real-world data. , 2010, Environmental science & technology.

[17]  Tiexiang Fu Novel NO2 Gas Sensor Based on Cr(III) Complex Thin Film , 2008 .

[18]  Ki-Hyun Kim,et al.  Long-term study of NOx behavior at urban roadside and background locations in Seoul, Korea , 2008 .

[19]  Yasuko Yamada Maruo,et al.  Measurement of local variations in atmospheric nitrogen dioxide levels in Sapporo, Japan, using a new method with high spatial and high temporal resolution , 2003 .

[20]  D. Carslaw Evidence of an increasing NO2/NOX emissions ratio from road traffic emissions , 2005 .

[21]  Emiliano Miluzzo,et al.  BikeNet: A mobile sensing system for cyclist experience mapping , 2009, TOSN.

[22]  Toshifumi Hotchi,et al.  Passive measurement of nitrogen oxides to assess traffic-related pollutant exposure for the East Bay Children's Respiratory Health Study , 2004 .

[23]  C. Malins,et al.  Optical NO2 sensing based on sol–gel entrapped azobenzene dyes , 1999 .

[24]  S. Ohira,et al.  Sensing parts per million levels of gaseous NO2 by a optical fiber transducer based on calix[4]arenes. , 2009, Talanta.

[25]  Manfred Kirchner,et al.  Modelling the decay of concentrations of nitrogenous compounds with distance from roads , 2008 .

[26]  Allison Woodruff,et al.  Common Sense Community: Scaffolding Mobile Sensing and Analysis for Novice Users , 2010, Pervasive.

[27]  Sukumar Devotta,et al.  Health risks of NO2, SPM and SO2 in Delhi (India) , 2005 .

[28]  P. Seakins,et al.  NO and NO2 interconversion downwind of two different line sources in suburban environments , 2011 .

[29]  Yoshika Sekine,et al.  Development of highly sensitive passive sampler for nitrogen dioxide using porous polyethylene membrane filter as turbulence limiting diffuser , 2008 .

[30]  A. Tardón,et al.  Outdoor NO2 and benzene exposure in the INMA (Environment and Childhood) Asturias cohort (Spain) , 2011 .

[31]  H. Hutter,et al.  Gas cooking and reduced lung function in school children , 2006 .

[32]  Pierre Sicard,et al.  Notice of RetractionAir Quality Trends and Potential Health Effects: Development of an Aggregate Risk Index , 2011, 2011 5th International Conference on Bioinformatics and Biomedical Engineering.

[33]  G. Coles,et al.  High sensitivity NO2 sensors for environmental monitoring produced using laser ablated nanocrystalline metal oxides , 2002 .

[34]  Multiparametric porous silicon gas sensors with improved quality and sensitivity , 2003 .

[35]  Ivan Stojmenovic,et al.  Sensor Networks , 2005 .

[36]  Pornpimol Kongtip,et al.  Health effects of metropolitan traffic-related air pollutants on street vendors , 2006 .