Processing of a Polyamide-12/carbon nanofibre composite by laser sintering

Additive layer techniques, such as laser sintering, are increasingly being considered for the production of fully functioning end-use parts due to the significant advantages they hold in the design and implementation of products. However, one of the main obstacles to widespread adoption of this technology is the limited range of materials that can currently be processed using additive techniques. This paper presents initial research into the reinforcement of laser sintered polyamides with carbon nanofibres (CNFs). The effects of CNF addition on the processing parameters and mechanical properties of laser sintered parts have been investigated. A 3wt % carbon nanofibre-polyamide 12 composite (CNF-PA12) powder was prepared using melt mixing and cryogenic milling. Following laser sintering, characterisation of the polymer nanocomposite parts by SEM and dynamic mechanical testing showed that the nanofibres were well dispersed within the polymer matrix and gave a 22% increase in the storage modulus compared to the base material. However, the cryogenic fracturing method used in this research did not produce powder with suitable morphology for laser sintering. If improved powder production can be achieved, the use of CNF reinforcements to improve mechanical properties in laser sintering holds promise.

[1]  Duc Truong Pham,et al.  Deterioration of polyamide powder properties in the laser sintering process , 2008 .

[2]  Suprakas Sinha Ray,et al.  POLYMER/LAYERED SILICATE NANOCOMPOSITES: A REVIEW FROM PREPARATION TO PROCESSING , 2003 .

[3]  A. Pires,et al.  Selective laser sintering of PA12/HDPE blends: Effect of components on elastic/plastic behavior , 2008 .

[4]  C K Chua,et al.  Selective laser sintering of biocompatible polymers for applications in tissue engineering. , 2005, Bio-medical materials and engineering.

[5]  F. E. Wiria,et al.  Poly-ε-caprolactone/hydroxyapatite for tissue engineering scaffold fabrication via selective laser sintering , 2007 .

[6]  F. Klocke,et al.  Consolidation phenomena in laser and powder-bed based layered manufacturing , 2007 .

[7]  S. Das,et al.  Processing and properties of glass bead particulate-filled functionally graded Nylon-11 composites produced by selective laser sintering , 2006 .

[8]  Neil Hopkinson,et al.  Rapid manufacturing : an industrial revolution for the digital age , 2006 .

[9]  Shi Yusheng,et al.  Development of a polymer alloy of polystyrene (PS) and polyamide (PA) for building functional part based on selective laser sintering (SLS) , 2004 .

[10]  T. Childs,et al.  Selective laser sintering of a crystalline and a glass-filled crystalline polymer: Experiments and simulations , 2001 .

[11]  Shi Yusheng,et al.  A Nanosilica/Nylon-12 Composite Powder for Selective Laser Sintering , 2009 .

[12]  Ian Gibson,et al.  Effects of graphite powder on the laser sintering behaviour of polycarbonate , 2002 .

[13]  Chee Kai Chua,et al.  Rapid Prototyping:Principles and Applications , 2010 .

[14]  Alida Mazzoli,et al.  Characterization of an aluminum-filled polyamide powder for applications in selective laser sintering , 2007 .

[15]  Yu. V. Khlopkov,et al.  Absorptance of powder materials suitable for laser sintering , 2000 .

[16]  Jerry Y. H. Fuh,et al.  Selective Laser Sintering , 2001 .

[17]  T. Gill,et al.  Experimental investigation into the selective laser sintering of silicon carbide polyamide composites , 2004 .

[18]  L. Pilato,et al.  Innovative selective laster sintering rapid manufacturing using nanotechnology , 2005 .

[19]  Jian Zhang,et al.  Effect of core–shell composite particles on the sintering behavior and properties of nano-Al2O3/polystyrene composite prepared by SLS , 2006 .

[20]  S. Huang,et al.  Selective laser sintering of polyamide-rectorite composite , 2005 .

[21]  Haseung Chung,et al.  Functionally graded Nylon-11/silica nanocomposites produced by selective laser sintering , 2008 .

[22]  Pulak M. Pandey,et al.  Selective laser sintering of clay-reinforced polyamide , 2009 .

[23]  Terry S. Creasy,et al.  Selective laser sintering characteristics of nylon 6/clay-reinforced nanocomposite , 2004 .

[24]  R. Hague *,et al.  Material and design considerations for rapid manufacturing , 2004 .

[25]  K. Hon,et al.  Selective Laser Sintering of SiC/Polyamide Composites , 2003 .

[26]  P. Bowen,et al.  Fracture behaviour of selective laser sintered Rapidsteel 2.0 under static and dynamic loading , 2003 .