Mercury removal from drinking water by single iron and binary iron-manganese oxyhydroxides

In this study, single iron oxyhydroxides (FeOOH) and binary iron/manganese (FeMnOOH) oxyhydroxides were used to serve as potential mercury adsorbents. The selection of the optimum adsorbent and the corresponding conditions of the synthesis was based not only on its maximum Hg(II) adsorption capacity but also on its ability to achieve the mercury health regulation limit for drinking water in National Sanitation Foundation challenge water matrix. The experimental results revealed improved adsorption capacity for Hg by the FeMnOOH compared to FeOOH. In addition, the synthesis parameters of FeMnOOH, pH, and redox showed a significant influence on Hg removal efficiency. High redox values and mild alkaline pH improve mercury removal capacity of binary ferric manganese oxyhydroxides.

[1]  G. Vourlias,et al.  Tetravalent manganese feroxyhyte: a novel nanoadsorbent equally selective for As(III) and As(V) removal from drinking water. , 2013, Environmental science & technology.

[2]  R. Semiat,et al.  Selenium removal from water and its recovery using iron (Fe3+) oxide/hydroxide-based nanoparticles sol (NanoFe) as an adsorbent , 2013 .

[3]  I. Manariotis,et al.  Removal of mercury from aqueous solutions by malt spent rootlets , 2012 .

[4]  G. Vourlias,et al.  Kilogram-scale synthesis of iron oxy-hydroxides with improved arsenic removal capacity: study of Fe(II) oxidation--precipitation parameters. , 2012, Water research.

[5]  C. Banks,et al.  Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water. , 2012, Water research.

[6]  B. Zargar,et al.  Fast and efficient removal of mercury from water samples using magnetic iron oxide nanoparticles modified with 2-mercaptobenzothiazole. , 2012, Journal of hazardous materials.

[7]  E. Faulconer,et al.  Optimization of magnetic powdered activated carbon for aqueous Hg(II) removal and magnetic recovery. , 2012, Journal of hazardous materials.

[8]  Feng-ying Zheng,et al.  Thorough removal of inorganic and organic mercury from aqueous solutions by adsorption on Lemna minor powder. , 2011, Journal of hazardous materials.

[9]  W. Horwath,et al.  Removal of inorganic mercury and methylmercury from surface waters following coagulation of dissolved organic matter with metal-based salts. , 2011, The Science of the total environment.

[10]  J. Barriada,et al.  A dynamic proof of mercury elimination from solution through a combined sorption-reduction process. , 2010, Bioresource technology.

[11]  R. Mason,et al.  Global mercury emissions to the atmosphere from anthropogenic and natural sources , 2010 .

[12]  T. Pradeep,et al.  Manganese dioxide nanowhiskers: A potential adsorbent for the removal of Hg(II) from water , 2010 .

[13]  Carlos M. Silva,et al.  Priority pollutants (Hg2+ and Cd2+) removal from water by ETS-4 titanosilicate , 2009 .

[14]  R. Mason,et al.  Global Mercury Emissions to the Atmosphere from Natural and Anthropogenic Sources , 2009 .

[15]  D. Atwood,et al.  The removal of mercury from water by open chain ligands containing multiple sulfurs. , 2008, Journal of hazardous materials.

[16]  K. A. Matis,et al.  Removal of zinc ion from water by sorption onto iron-based nanoadsorbent. , 2007, Journal of hazardous materials.

[17]  Y. Ho Review of second-order models for adsorption systems. , 2006, Journal of hazardous materials.

[18]  D. Karatza,et al.  Capture of mercury ions by natural and industrial materials. , 2006, Journal of hazardous materials.

[19]  J. Arunachalam,et al.  Removal and preconcentration of inorganic and methyl mercury from aqueous media using a sorbent prepared from the plant Coriandrum sativum. , 2005, Journal of hazardous materials.

[20]  D. Tiwari,et al.  Inorganic particulates in removal of heavy metal toxic ions IX. Rapid and efficient removal of Hg(II) by hydrous manganese and tin oxides. , 2004, Journal of colloid and interface science.

[21]  E. Robens,et al.  Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. , 2004, Chemosphere.

[22]  G. Brown,et al.  EXAFS study of mercury(II) sorption to Fe- and Al-(hydr)oxides. I. Effects of pH. , 2004, Journal of colloid and interface science.

[23]  N. Petrov,et al.  Removal of mercury (II) from aqueous solution by activated carbon obtained from furfural. , 2003, Chemosphere.

[24]  A. Zouboulis,et al.  Removal of arsenic from contaminated water sources by sorption onto iron-oxide-coated polymeric materials. , 2002, Water research.

[25]  K. Ragnarsdóttir,et al.  Surface Complexation of Hg2+ on Goethite: Mechanism from EXAFS Spectroscopy and Density Functional Calculations , 1999 .

[26]  S. Sjöberg,et al.  Surface Complexation in the H+-Goethite (α-FeOOH)-Hg (II)-Chloride System , 1993 .

[27]  S. Mitra,et al.  Mercury in the Ecosystem , 1985 .

[28]  S. Ramamoorthy,et al.  Heavy Metals in Natural Waters , 1984 .

[29]  S. Ramamoorthy,et al.  Heavy Metals in Natural Waters: Applied Monitoring and Impact Assessment , 1983 .

[30]  W. Stumm,et al.  The interaction of anions and weak acids with the hydrous goethite (α-FeOOH) surface , 1981 .

[31]  J. Quirk,et al.  The specific adsorption of inorganic Hg(II) species and Co(III) complex ions on goethite , 1974 .