Experimental investigations on gas desorption and transport in stressed coal under isothermal conditions

Abstract The present paper focuses on the transport process of adsorbed gas within the raw coal, to understand the complex physical mechanism over the gas emission with the gradual development of coal damage. A uniaxial test apparatus for stressed coal was especially developed to simultaneously measure deformation and gas pressure as well as gas flux during test, taking the characteristics of gas transport into consideration under stress–temperature conditions. Gas composition and its concentration were detected at different time intervals by chromatography technique. The uniaxial compressive tests for the coal samples from Nanshan coalmine of northeast of China were conducted to investigate the desorption process of adsorbed and free gas under different isothermal conditions. An X-ray computer tomography technique was used to visualize the spatial distribution of porous structures and mesocracks for the coal sample at the pre- and post-test. At the failure stage, the pressure of desorption gas released from the stressed coal underwent a rapid transition from negative to positive, which can be described as a “breathing effect”. By using the bidisperse model, it was calculated that gas pressure exhibited a jump phenomenon corresponding to the zero point of volumetric strain for the coal samples, commonly accompanied with the propagation of cracks. As a consequence, the clustered cracks enhanced the gas reservoir and also influenced the gas pressure within the coal samples. After failing, the porous structures and voids were squeezed under confined pressure so that gases were expelled, while the concentrations of methane, carbon dioxide and ethane in the released gases were sharply increased. These test results may help us to gain an insight into the coupling mechanism between coal and gas.

[1]  Jerzy Ziętek,et al.  Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics, volumetric strain and acoustic emission , 2009 .

[2]  Hua Guo,et al.  Displacement, stress and seismicity in roadway roofs during mining-induced failure , 2008 .

[3]  A. Alexeev Alteration of methane pressure in the closed pores of fossil coals , 2000 .

[4]  Greg Duffy,et al.  Temperature dependence of sorption of gases by coals and charcoals , 2008 .

[5]  A. A. Reznik,et al.  An analysis of the effect of CO2 injection on the recovery of in situ methane from bituminous coal: an experimental simulation , 1984 .

[6]  P. Jacobs,et al.  Applications of X-ray computed tomography in the geosciences , 2003, Geological Society, London, Special Publications.

[7]  A. Ingraffea,et al.  FINITE ELEMENT MODELS FOR ROCK FRACTURE MECHANICS , 1980 .

[8]  Carlo D. Montemagno,et al.  Fracture network versus single fractures: Measurement of fracture geometry with X-ray tomography , 1999 .

[9]  Andreas Busch,et al.  Investigation of high-pressure selective adsorption/desorption behaviour of CO2 and CH4 on coals: An experimental study , 2006 .

[10]  Rudy Swennen,et al.  Application of microfocus computed tomography in carbonate reservoir characterization: Possibilities and limitations , 2008 .

[11]  Christopher R. Clarkson,et al.  Application of the mono/multilayer and adsorption potential theories to coal methane adsorption isotherms at elevated temperature and pressure , 1997 .

[12]  M. Cai,et al.  Earthquake-induced unusual gas emission in coalmines — A km-scale in-situ experimental investigation at Laohutai mine , 2007 .

[13]  C. Özgen Karacan,et al.  Degasification system selection for US longwall mines using an expert classification system , 2009, Comput. Geosci..

[14]  Grant S. Bromhal,et al.  Influence of carbon dioxide on coal permeability determined by pressure transient methods , 2009 .

[15]  C. Özgen Karacan,et al.  Swelling-Induced Volumetric Strains Internal to a Stressed Coal Associated with CO2 Sorption , 2007 .

[16]  R. Ketcham,et al.  Acquisition, optimization and interpretation of X-ray computed tomographic imagery: applications to the geosciences , 2001 .

[17]  Jean-Pierre Petit,et al.  Can natural faults propagate under Mode II conditions , 1988 .

[18]  Goodarz Ahmadi,et al.  A new friction factor correlation for laminar, single-phase flows through rock fractures , 2006 .

[19]  D. Charrière,et al.  Effect of pressure and temperature on diffusion of CO2 and CH4 into coal from the Lorraine basin (France) , 2010 .

[20]  Basil Beamish,et al.  Coalbed methane sorption related to coal composition , 1998 .

[21]  P. Walker,et al.  Activated diffusion of methane from coals at elevated pressures , 1975 .

[22]  Philip L. Walker,et al.  Activated diffusion of methane in coal , 1970 .

[23]  Brett Poulsen,et al.  Stress analysis of longwall top coal caving , 2010 .

[24]  Yuhua Wu,et al.  Changes in infrared radiation with rock deformation , 2002 .

[25]  J. Litwiniszyn,et al.  A model for the initiation of coal-gas outbursts , 1985 .

[26]  Frank L. Williams,et al.  Diffusional Effects in the Recovery of Methane From Coalbeds , 1984 .

[27]  Eli Ruckenstein,et al.  Sorption by solids with bidisperse pore structures , 1971 .

[28]  R. T. Yang,et al.  Adsorption of gases on coals and heattreated coals at elevated temperature and pressure: 1. Adsorption from hydrogen and methane as single gases , 1985 .

[29]  O. Duliu Computer axial tomography in geosciences: an overview , 1999 .

[30]  W. R. Kaiser,et al.  Thermogenic and Secondary Biogenic Gases, San Juan Basin, Colorado and New Mexico--Implications for Coalbed Gas Producibility , 1994 .

[31]  A. Busch,et al.  Methane and carbon dioxide adsorption–diffusion experiments on coal: upscaling and modeling , 2004 .

[32]  M. Cai,et al.  Influence of intermediate principal stress on rock fracturing and strength near excavation boundaries : Insight from numerical modeling , 2008 .

[33]  I. W. Farmer,et al.  A hypothesis to explain the occurrence of outbursts in coal, based on a study of west wales outburst coal , 1967 .

[34]  Christopher R. Clarkson,et al.  The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study. 2. Adsorption rate modeling , 1999 .

[35]  C. Karacan,et al.  An effective method for resolving spatial distribution of adsorption kinetics in heterogeneous porous media: application for carbon dioxide sequestration in coal , 2003 .