Plasmonic Scattering by Metal Nanoparticles for Solar Cells

We investigate on absorption and scattering from metal nanoparticles in view of possible applications to photovoltaic cells. The analysis, accounting for most of the parameters involved in the physical mechanism of scattering, is split into two parts. In the first part, scattering from a metallic sphere is treated analytically to investigate the dependence on sphere size, sphere metal, and surrounding medium. In the second part, scattering from a metallic particle is investigated as a function of particle shape (spheroids, hemispheres, and cylinders) via numerical simulations based on the finite-difference time-domain method. The aim of the work is to provide a systematic study on scattering and absorption by metal nanoparticles, exploring several combinations of material and geometrical parameters in order to identify those combinations that could play a key role in solar cell efficiency improvement.

[1]  Peter Nordlander,et al.  Substrates matter: influence of an adjacent dielectric on an individual plasmonic nanoparticle. , 2009, Nano letters.

[2]  E. Yu,et al.  Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles , 2005 .

[3]  K. Kunz,et al.  A frequency-dependent finite-difference time-domain formulation for transient propagation in plasma , 1991 .

[4]  Harry A. Atwater,et al.  Erratum: Plasmonics for improved photovoltaic devices , 2010 .

[5]  Meir Orenstein,et al.  How front side plasmonic nanostructures enhance solar cell efficiency , 2011 .

[6]  M. Green,et al.  Surface plasmon enhanced silicon solar cells , 2007 .

[7]  E. Palik Handbook of Optical Constants of Solids , 1997 .

[8]  H. Atwater,et al.  Plasmonics for improved photovoltaic devices. , 2010, Nature materials.

[9]  D. A. Dunnett Classical Electrodynamics , 2020, Nature.

[10]  Martin A. Green,et al.  The effect of dielectric spacer thickness on surface plasmon enhanced solar cells for front and rear side depositions , 2011 .

[11]  Thierry Laroche,et al.  Comparison of gold and silver dispersion laws suitable for FDTD simulations , 2008 .

[12]  Tristan L. Temple,et al.  Influence of localized surface plasmon excitation in silver nanoparticles on the performance of silicon solar cells , 2009 .

[13]  Stephen D. Gedney,et al.  Convolution PML (CPML): An efficient FDTD implementation of the CFS–PML for arbitrary media , 2000 .

[14]  L. Cristoforetti,et al.  The frequency dependent FDTD method for multi-frequency results in microwave hyperthermia treatment simulation , 1993 .

[15]  M. Green,et al.  Plasmonics for photovoltaic applications , 2010 .

[16]  S. Egashira,et al.  Sleeve antenna with ground wires , 1991 .

[17]  Allen Taflove,et al.  Computational Electrodynamics the Finite-Difference Time-Domain Method , 1995 .

[18]  L. Cristoforetti,et al.  A robust and efficient subgridding algorithm for finite-difference time-domain simulations of Maxwell's equations , 2004 .

[19]  Er-Ping Li,et al.  Surface Plasmon Enhancement of Optical Absorption in Thin-Film Silicon Solar Cells , 2009 .

[20]  K. Yee Numerical solution of initial boundary value problems involving maxwell's equations in isotropic media , 1966 .

[21]  George C. Schatz,et al.  The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment , 2003 .

[22]  Garnett W. Bryant,et al.  Metal‐nanoparticle plasmonics , 2008 .

[23]  Naomi J. Halas,et al.  Optimized plasmonic nanoparticle distributions for solar spectrum harvesting , 2006 .

[24]  W. Steen Absorption and Scattering of Light by Small Particles , 1999 .