Programming structure into 3D nanomaterials

Programming three dimensional nanostructures into materials is becoming increasingly important given the need for ever more highly functional solids. Applications for materials with complex programmed structures include solar energy harvesting, energy storage, molecular separation, sensors, pharmaceutical agent delivery, nanoreactors and advanced optical devices. Here we discuss examples of molecular and optical routes to program the structure of three-dimensional nanomaterials with exquisite control over nanomorphology and the resultant properties and conclude with a discussion of the opportunities and challenges of such an approach.

[1]  A. Brzezinski,et al.  Three dimensional silicon-air photonic crystals with controlled defects using interference lithography , 2008 .

[2]  Tatiana N. Smirnova,et al.  Holographic patterning of luminescent photopolymer nanocomposites , 2008 .

[3]  X. Zhao,et al.  Immobilizing catalysts on porous materials , 2006 .

[4]  María Vallet-Regí,et al.  Mesoporous materials for drug delivery. , 2007, Angewandte Chemie.

[5]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[6]  J. S. Beck,et al.  Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism , 1992, Nature.

[7]  P. Kooyman,et al.  Ultrafiltration Membrane Made with Mesoporous MSU-X Silica , 2003 .

[8]  E. Costard,et al.  Photonic band gaps and holography , 1997 .

[9]  C. N. R. Rao,et al.  Chemistry of materials , 2009 .

[10]  E. Helfand,et al.  Theory of Copolymer Crystallization , 1973 .

[11]  Lalgudi V. Natarajan,et al.  Holographic Formation of Electro‐Optical Polymer–Liquid Crystal Photonic Crystals , 2002 .

[12]  P. Braun,et al.  Double direct templating of periodically nanostructured ZnS hollow microspheres. , 2005, Journal of the American Chemical Society.

[13]  E. Thomas,et al.  Fabrication of Quantum Dot/Polymer Composites: Phosphine-Functionalized Block Copolymers as Passivating Hosts for Cadmium Selenide Nanoclusters , 1997 .

[14]  U. Wiesner,et al.  Organically modified aluminosilicate mesostructures from block copolymer phases , 1997, Science.

[15]  Sol M Gruner,et al.  Ordered Mesoporous Materials from Metal Nanoparticle–Block Copolymer Self-Assembly , 2008, Science.

[16]  Kunlun Hong,et al.  Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers. , 2004, Angewandte Chemie.

[17]  Stephen A. Bagshaw,et al.  Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants , 1995, Science.

[18]  S. Stupp,et al.  Macroscopic Nanotemplating of Semiconductor Films with Hydrogen‐Bonded Lyotropic Liquid Crystals , 2005 .

[19]  A. Håkansson,et al.  Integrated optical devices design by genetic algorithm , 2003, cond-mat/0310142.

[20]  S. Stupp,et al.  Semiconducting superlattices templated by molecular assemblies , 1996, Nature.

[21]  John A. Rogers,et al.  Three‐Dimensional Nanofabrication with Rubber Stamps and Conformable Photomasks , 2004 .

[22]  Paul V. Braun,et al.  Nanostructure templating in inorganic solids with organic lyotropic liquid crystals , 1999 .

[23]  Inverse design for full control of spontaneous emission using light emitting scattering optical elements. , 2006, Physical review letters.

[24]  Sarah L. Sewell,et al.  Materials Science and Engineering C , 2009 .

[25]  A. Imhof,et al.  Ordered macroporous materials by emulsion templating , 1997, Nature.

[26]  T. Emrick,et al.  Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates. , 2006, Journal of the American Chemical Society.

[27]  Woo Soo Kim,et al.  Hierarchically Ordered Topographic Patterns via Plasmonic Mask Photolithography , 2009 .

[28]  E. Ruckenstein,et al.  Theory of surfactant self-assembly : a predictive molecular thermodynamic approach , 1991 .

[29]  E. Helfand,et al.  Block Copolymer Theory. III. Statistical Mechanics of the Microdomain Structure , 1975 .

[30]  Deng,et al.  Hierarchically ordered oxides , 1998, Science.

[31]  T. Valdés-Solís,et al.  Synthesis of Highly Uniform Mesoporous Sub-Micrometric Capsules of Silicon Oxycarbide and Silica , 2007 .

[32]  M. Pileni The role of soft colloidal templates in controlling the size and shape of inorganic nanocrystals , 2003, Nature materials.

[33]  Yasuo Tomita,et al.  Two-dimensional imaging of atomic distribution morphology created by holographically induced mass transfer of monomer molecules and nanoparticles in a silica-nanoparticle-dispersed photopolymer film. , 2006, Optics letters.

[34]  David C. Morton,et al.  High-filling-fraction inverted ZnS opals fabricated by atomic layer deposition , 2003 .

[35]  Sol M Gruner,et al.  The plumber's nightmare: a new morphology in block copolymer-ceramic nanocomposites and mesoporous aluminosilicates. , 2003, Journal of the American Chemical Society.

[36]  J. B. Higgins,et al.  A new family of mesoporous molecular sieves prepared with liquid crystal templates , 1992 .

[37]  D. Norris,et al.  Thermally Stable Organic–Inorganic Hybrid Photoresists for Fabrication of Photonic Band Gap Structures with Direct Laser Writing , 2008 .

[38]  Lalgudi V. Natarajan,et al.  One‐Step, Micrometer‐Scale Organization of Nano‐ and Mesoparticles Using Holographic Photopolymerization: A Generic Technique , 2001 .

[39]  Chen,et al.  Hollow Spheres of Mesoporous Aluminosilicate with a Three-Dimensional Pore Network and Extraordinarily High Hydrothermal Stability , 2003 .

[40]  P. Bartlett,et al.  The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases , 2002 .

[41]  R. Rosenfeld Nature , 2009, Otolaryngology--head and neck surgery : official journal of American Academy of Otolaryngology-Head and Neck Surgery.

[42]  G. Fredrickson,et al.  Block copolymer thermodynamics: theory and experiment. , 1990, Annual review of physical chemistry.

[43]  H. Wennerström The relation between micelle size and shape and the stability of liquid crystalline phases in surfactant systems , 1979 .

[44]  M. Nakata,et al.  Preparation of a High Surface Area Nickel Electrode by Alloying and Dealloying in a ZnCl2 ­ NaCl Melt , 2003 .

[45]  Gordon J. T. Tiddy,et al.  Phase behaviour of polyoxyethylene surfactants with water. Mesophase structures and partial miscibility (cloud points) , 1983 .

[46]  H. Kunieda,et al.  Self-Organizing Structures in Poly(oxyethylene) Oleyl Ether−Water System , 1997 .

[47]  T. Ohsuna,et al.  Vapor Infiltration of a Reducing Agent for Facile Synthesis of Mesoporous Pt and Pt-Based Alloys and Its Application for the Preparation of Mesoporous Pt Microrods in Anodic Porous Membranes , 2008 .

[48]  B. Ninham,et al.  Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers , 1976 .

[49]  E. Coker,et al.  Synthesis of platinum nanowire networks using a soft template. , 2007, Nano letters.

[50]  P. Wiltzius,et al.  Inverse design for phase mask lithography. , 2008, Optics express.

[51]  A. Barbetta,et al.  High internal phase emulsions (HIPEs) containing divinylbenzene and 4-vinylbenzyl chloride and the morphology of the resulting PolyHIPE materials , 2000 .

[52]  Elton Graugnard,et al.  Infiltration and Inversion of Holographically Defined Polymer Photonic Crystal Templates by Atomic Layer Deposition , 2006 .

[53]  M. Antonietti,et al.  Non‐aqueous Synthesis of Tin Oxide Nanocrystals and Their Assembly into Ordered Porous Mesostructures , 2005 .

[54]  M. Antonietti,et al.  Generation of Self‐Assembled 3D Mesostructured SnO2 Thin Films with Highly Crystalline Frameworks , 2006 .

[55]  Yufang Zhu,et al.  Stimuli-responsive controlled drug release from a hollow mesoporous silica sphere/polyelectrolyte multilayer core-shell structure. , 2005, Angewandte Chemie.

[56]  John A Rogers,et al.  Fabricating complex three-dimensional nanostructures with high-resolution conformable phase masks. , 2004, Proceedings of the National Academy of Sciences of the United States of America.

[57]  Zvi Kotler,et al.  Chalcogenide glass-based three-dimensional photonic crystals , 2000 .

[58]  Jinwoo Lee,et al.  Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores. , 2008, Nature materials.

[59]  G. Lu,et al.  Periodic mesoporous organosilica hollow spheres with tunable wall thickness. , 2006, Journal of the American Chemical Society.

[60]  B. Sfez,et al.  Three-dimensional simple cubic woodpile photonic crystals made from chalcogenide glasses , 2003 .

[61]  Michael J. Birnkrant,et al.  Layer-in-layer hierarchical nanostructures fabricated by combining holographic polymerization and block copolymer self-assembly. , 2007, Nano letters (Print).

[62]  A. J. Forty,et al.  A micromorphological study of the dissolution of silver-gold alloys in nitric acid , 1980 .

[63]  A. Cooper,et al.  Emulsion Templating Using High Internal Phase Supercritical Fluid Emulsions , 2001 .

[64]  Todd Emrick,et al.  Self-directed self-assembly of nanoparticle/copolymer mixtures , 2005, Nature.

[65]  John A Rogers,et al.  Molded transparent photopolymers and phase shift optics for fabricating three dimensional nanostructures. , 2007, Optics express.

[66]  D. Pine,et al.  Photonic Crystals from Emulsion Templates , 2001 .

[67]  E. Helfand,et al.  Block Copolymer Theory. 4. Narrow Interphase Approximation , 1976 .

[68]  Philip N. Bartlett,et al.  Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases , 1997 .

[69]  C. Tanford Macromolecules , 1994, Nature.

[70]  J. Rogers,et al.  Direct fabrication of 3D periodic inorganic microstructures using conformal phase masks. , 2009, Angewandte Chemie.

[71]  George S. Attard,et al.  Liquid-crystalline phases as templates for the synthesis of mesoporous silica , 1995, Nature.

[72]  M. Wegener,et al.  Highly Selective Wet Etch for High-Resolution Three-Dimensional Nanostructures in Arsenic Sulfide All-Inorganic Photoresist , 2007 .

[73]  R. G. Denning,et al.  Fabrication of photonic crystals for the visible spectrum by holographic lithography , 2000, Nature.

[74]  P. Sun,et al.  Silica Hollow Spheres with Ordered and Radially Oriented Amino-Functionalized Mesochannels , 2009 .

[75]  Pierre Wiltzius,et al.  Design of holographic structures using genetic algorithms. , 2006, Optics express.

[76]  F. Bates,et al.  Polymer-Polymer Phase Behavior , 1991, Science.