Selective Detection of Formaldehyde Gas Using a Cd-Doped TiO2-SnO2 Sensor

We report the microstructure and gas-sensing properties of a nonequilibrium TiO2-SnO2 solid solution prepared by the sol-gel method. In particular, we focus on the effect of Cd doping on the sensing behavior of the TiO2-SnO2 sensor. Of all volatile organic compound gases examined, the sensor with Cd doping exhibits exclusive selectivity as well as high sensitivity to formaldehyde, a main harmful indoor gas. The key gas-sensing quantities, maximum sensitivity, optimal working temperature, and response and recovery time, are found to meet the basic industrial needs. This makes the Cd-doped TiO2-SnO2 composite a promising sensor material for detecting the formaldehyde gas.

[1]  N. Yamazoe,et al.  Oxide Semiconductor Gas Sensors , 2003 .

[2]  Gian Carlo Cardinali,et al.  An electronic nose based on solid state sensor arrays for low-cost indoor air quality monitoring applications , 2004 .

[3]  J. Goschnick,et al.  Air quality monitoring and fire detection with the Karlsruhe electronic micronose KAMINA , 2002 .

[4]  Li Tang,et al.  Sensitive and selective acetone sensor based on its cataluminescence from nano-La2O3 surface , 2008 .

[5]  Ralf Moos,et al.  Amperometric Enzyme-based Gas Sensor for Formaldehyde: Impact of Possible Interferences , 2008, Sensors.

[6]  Pelagia-Irene Gouma,et al.  Sensing of Organic Vapors by Flame-Made TiO2 Nanoparticles , 2006 .

[7]  Yoshio Suzuki,et al.  Portable sick house syndrome gas monitoring system based on novel colorimetric reagents for the highly selective and sensitive detection of formaldehyde. , 2003, Environmental science & technology.

[8]  Wu Xinghui,et al.  Electrical and gas-sensing properties of perovskite-type CdSnO3 semiconductor material , 2003 .

[9]  K. Nagashima,et al.  An automatic monitor of formaldehyde in air by a monitoring tape method. , 1999, Journal of environmental monitoring : JEM.

[10]  Julian W. Gardner,et al.  The role of the electronic nose in condition monitoring , 1997 .

[11]  W. Y. Wang,et al.  Improvement in gas sensitivity of ZnO thick film to volatile organic compounds (VOCs) by adding TiO2 , 2004 .

[12]  R. Wood,et al.  Behavioral evaluation of the irritant properties of formaldehyde. , 1995, Toxicology and applied pharmacology.

[13]  Hengfu Shui,et al.  Investigation on formaldehyde gas sensor with ZnO thick film prepared through microwave heating method , 2009 .

[14]  Pallavi Shah,et al.  Synthesis of nanocrystalline SnO2 powder by amorphous citrate route , 2003 .

[15]  A. Konno,et al.  Effect of formaldehyde on the expression of adhesion molecules in nasal microvascular endothelial cells: the role of formaldehyde in the pathogenesis of sick building syndrome , 2002, Clinical and experimental allergy : journal of the British Society for Allergy and Clinical Immunology.

[16]  G. Neri,et al.  Role of the Au oxidation state in the CO sensing mechanism of Au/iron oxide-based gas sensors , 2003 .

[17]  Sheikh A. Akbar,et al.  Selective detection of ethanol vapor using xTiO2–(1 − x)WO3 based sensor , 2003 .

[18]  Duk-Dong Lee,et al.  Recognition of volatile organic compounds using SnO2 sensor array and pattern recognition analysis , 2001 .

[19]  A. K. Srivastava,et al.  Detection of volatile organic compounds (VOCs) using SnO2 gas-sensor array and artificial neural network , 2003 .

[20]  David E. Williams Semiconducting oxides as gas-sensitive resistors , 1999 .

[21]  H. S. Wolff,et al.  iRun: Horizontal and Vertical Shape of a Region-Based Graph Compression , 2022, Sensors.

[22]  M. Odlyha,et al.  Microclimate monitoring of indoor environments using piezoelectric quartz crystal humidity sensors. , 2000, Journal of environmental monitoring : JEM.

[23]  B. L. Zhua,et al.  Improvement in gas sensitivity of ZnO thick film to volatile organic compounds ( VOCs ) by adding TiO 2 , 2003 .

[24]  Xiaohua Jia,et al.  Selective detection of HCHO gas using mixed oxides of ZnO/ZnSnO3 , 2007 .