Crystal structures of salen-type ligands 2-[(1E)-({1-(3-chlorophenyl)-2-[(E)-(2-hydroxybenzylidene)amino]propyl}imino)methyl]phenol and 2-[(1E)-({1-(4-chlorophenyl)-2-[(E)-(2-hydroxybenzylidene)amino]propyl}imino)methyl]phenol

The title compounds are differing only by the position of the chlorine atom in the benzene ring. The molecular structures are very similar, except for the relative position of the hydroxyphenyl rings.

[1]  P. Freire,et al.  Spectroscopy studies on Schiff base N,N′-bis(salicylidene)-1,2-phenylenediamine by NMR, infrared, Raman and DFT calculations , 2015 .

[2]  S. K. Prasad,et al.  Synthesis and aggregation behaviour of luminescent mesomorphic zinc(II) complexes with 'salen' type asymmetric Schiff base ligands. , 2015, Dalton transactions.

[3]  G. Sheldrick Crystal structure refinement with SHELXL , 2015, Acta crystallographica. Section C, Structural chemistry.

[4]  Chandini R. Nayar,et al.  Review: Second order nonlinearities of Schiff bases derived from salicylaldehyde and their metal complexes , 2014 .

[5]  Tugrul C. Zeyrek Theoretical Study of the N-(2,5-Methylphenyl)salicylaldimine Schiff Base Ligand: Atomic Charges, Molecular Electrostatic Potential, Nonlinear Optical (NLO) Effects and Thermodynamic Properties , 2013 .

[6]  C. Wan,et al.  A turn-on and reversible Schiff base fluorescence sensor for Al3+ ion. , 2013, The Analyst.

[7]  Louis J. Farrugia,et al.  WinGX and ORTEP for Windows: an update , 2012 .

[8]  Yixiang Cheng,et al.  Enantioselective fluorescent recognition of mandelic acid by unsymmetrical salalen and salan sensors. , 2011, Organic & biomolecular chemistry.

[9]  Anthony L. Spek,et al.  Structure validation in chemical crystallography , 2009, Acta crystallographica. Section D, Biological crystallography.

[10]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[11]  J D Gans,et al.  Qmol: a program for molecular visualization on Windows-based PCs. , 2001, Journal of molecular graphics & modelling.