Measuring thermal conductivities of anisotropic synthetic graphite-liquid crystal polymer composites

In this study, synthetic graphite particles were added to a liquid crystal polymer and the resulting composites were tested for both the through-plane thermal conductivity kthru and the in-plane thermal conductivity kin using the transient plane source method. The end use application for these composites is in fuel cell bipolar plate fabrication. The goal of this work was to expand upon a previously developed simple empirical model for the in-plane thermal conductivity, which is easily measured with the transient plane source method. The results show that the square root of the product of the through-plane and in-plane thermal conductivities is an exponential function of the volume percent of filler, ϕ. As the through-plane thermal conductivity of these composites is accurately predicted with a modified Nielsen model, this empirical relationship can be used to estimate in-plane thermal conductivities for a range of applications. POLYM. COMPOS., 27:388–394, 2006. © 2006 Society of Plastics Engineers

[1]  Donald R Paul,et al.  Gas transport in a thermotropic liquid‐crystalline polyester , 1987 .

[2]  Donald M. Bigg Battelle Conductive polymeric compositions , 1977 .

[3]  J. King,et al.  Development of an additive equation for predicting the electrical conductivity of carbon‐filled composites , 2003 .

[4]  Yi He,et al.  Rapid thermal conductivity measurement with a hot disk sensor: Part 1. Theoretical considerations , 2005 .

[5]  Julia A. King,et al.  Evaluation of electrical conductivity models for conductive polymer composites , 2002 .

[6]  Julia A. King,et al.  Factorial design approach applied to electrically and thermally conductive nylon 6,6 , 2001 .

[7]  Jason M. Keith,et al.  Comparison of the guarded-heat-flow and transient-plane-source methods for carbon-filled nylon 6,6 composites: Experiments and modeling , 2006 .

[8]  S. Gustafsson,et al.  Parameter estimations for measurements of thermal transport properties with the hot disk thermal constants analyzer , 2000 .

[9]  M. Narkis,et al.  New injection moldable electrostatic dissipative (ESD) composites based on very low carbon black loadings , 1999 .

[10]  S. Gustafsson,et al.  THERMAL CONDUCTIVITY, THERMAL DIFFUSIVITY, AND SPECIFIC HEAT OF THIN SAMPLES FROM TRANSIENT MEASUREMENTS WITH HOT DISK SENSORS , 1994 .

[11]  K. Nagata,et al.  Effect of particle size of graphites on electrical conductivity of graphite/polymer composite , 1998 .

[12]  J. King,et al.  Thermally conductive nylon 6,6 and polycarbonate based resins. I. Synergistic effects of carbon fillers , 2003 .

[13]  Jason M. Keith,et al.  Measuring and predicting in-plane thermal conductivity of carbon-filled nylon 6,6 polymer composites , 2006 .

[14]  J. King,et al.  Thermally conductive carbon filled nylon 6,6 , 2004 .

[15]  Torgrim Log,et al.  Transient plane source (TPS) technique for measuring thermal transport properties of building materials , 1995 .

[16]  R. Spontak,et al.  Bridged double percolation in conductive polymer composites: an electrical conductivity, morphology and mechanical property study , 2002 .

[17]  J. King,et al.  Thermally conductive nylon 6,6 and polycarbonate based resins. II. Modeling , 2003 .

[18]  Y. Agari,et al.  Thermal conductivity of polymer filled with carbon materials: Effect of conductive particle chains on thermal conductivity , 1985 .

[19]  D. Bigg The effect of compounding on the conductive properties of EMI shielding compounds , 1984 .