Nitrite complexes of uranium and thorium.

The first examples of inorganic nitrite complexes of the natural actinides are described, including the structures of the homoleptic thorium(IV) [PPh(4)](2)[Th(NO(2))(6)] and the uranyl(VI) [PPh(4)](2)[UO(2)(NO(2))(4)] complexes; the nitrite ligand can adopt two different coordination modes in the coordination sphere of the uranyl ion and is unstable towards reduction.

[1]  P. Carroll,et al.  Reductive cleavage of nitrite to form terminal uranium mono-oxo complexes. , 2013, Journal of the American Chemical Society.

[2]  Marisa J. Monreal,et al.  UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry , 2011 .

[3]  Di Sun,et al.  A new clover-shaped trinuclear uranium(VI) complex: Synthesis, structure and photoluminescence property , 2010 .

[4]  W. Liaw,et al.  Roles of the distinct electronic structures of the {Fe(NO)(2)}(9) and {Fe(NO)(2)}(10) dinitrosyliron complexes in modulating nitrite binding modes and nitrite activation pathways. , 2010, Journal of the American Chemical Society.

[5]  B. Scott,et al.  Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials. , 2010, Chemical communications.

[6]  Xia Zhu,et al.  Poly[bis[μ2-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene-κ2 N 4:N 4′]bis(nitrito-κO)cobalt(II)] , 2009, Acta crystallographica. Section E, Structure reports online.

[7]  N. Budantseva,et al.  First structural evidence of actinide-nitrite coordination. , 2008, Inorganic chemistry.

[8]  Lester R. Morss,et al.  The chemistry of the actinide and transactinide elements , 2006 .

[9]  H. Görls,et al.  The Relationship between the Structure and Magnetic Properties of Bioinspired Iron(ii/iii) Complexes with Schiff-Base-Like Chelate Ligands, Part I: Complexes with Dianionic [N4] Macrocycles , 2005 .

[10]  X. Bu,et al.  Chromium(III) complexes for photochemical nitric oxide generation from coordinated nitrite: synthesis and photochemistry of macrocyclic complexes with pendant chromophores, trans-[Cr(L)(ONO)(2)]BF(4). , 2005, Inorganic chemistry.

[11]  Mark D. Smith,et al.  Two-dimensional hydrogen-bonded networks based on bent oxadiazole bridging organic spacers , 2005 .

[12]  S. Tyagi,et al.  The crystal structures and electronic properties of three new [Cu(bipy)2(ONO)][Y] complexes. The structural pathway of the [Cu(bipy)2(ONO)][Y] series of complexes. Further insights into the Pseudo Jahn–Teller model , 2004 .

[13]  A. Neves,et al.  A structural model for oxidized type II copper nitrite reductase with a polyimidazole tripodal ligand , 2004 .

[14]  L. Long,et al.  La(NO2)(3), a novel (3,9)-connected lanthanide-based network , 2004 .

[15]  B. Scott,et al.  Convenient Synthesis, Structure, and Reactivity of (C5Me5)U(CH2C6H5)3: A Simple Strategy for the Preparation of Monopentamethylcyclopentadienyl Uranium(IV) Complexes , 2002 .

[16]  S. Alvarez,et al.  Spin densities in a ferromagnetic bimetallic chain compound: polarized neutron diffraction and DFT calculations. , 2002, Journal of the American Chemical Society.

[17]  D. Lovley,et al.  Multiple influences of nitrate on uranium solubility during bioremediation of uranium-contaminated subsurface sediments. , 2002, Environmental microbiology.

[18]  J. Suflita,et al.  In-situ evidence for uranium immobilization and remobilization. , 2002, Environmental science & technology.

[19]  K. Aoki,et al.  Metal ion and anion coordination in the thiamine–[PtII(NO2)4]2− system. Structures of a metal complex, Pt(thiamine)(NO2)3, and two salts, (H-thiamine)[Pt(NO2)4]·2H2O and (thiamine monophosphate)2[Pt(NO2)4]·2H2O , 2001 .

[20]  Hae Namgung,et al.  Bis[N-methylphenazinium(1+)] Tetranitropalladate(II) , 1998 .

[21]  A. J. Blake,et al.  Unique cationic, neutral and anionic copper(II) nitrite species in a single compound , 1998 .

[22]  C. Mathonière,et al.  Metamagnetic Behavior of the Novel Bimetallic Ferromagnetic Chain Compound MnNi(NO(2))(4)(en)(2) (en = Ethylenediamine). , 1997, Inorganic chemistry.

[23]  C. Gatti,et al.  Theoretical and experimental (113 K) electron-density study of lithium bis(tetramethylammonium) hexanitrocobaltate(III) , 1996 .

[24]  V. Adovasio,et al.  Lithium bis(tetramethyllammonium) hexanitrocobaltate(III) at 113 and 293 K , 1994 .

[25]  Y. Hama,et al.  Photochemical formation of oxochromium(IV) tetraphenylporphyrin from nitritochromium(III) tetraphenylporphyrin in benzene , 1992 .

[26]  S. Konishi,et al.  Photochemistry of molybdenum(V) tetraphenylporphyrin studied by laser flash photolysis: light-induced homolysis of the molybdenum-oxygen bond of oxoalkoxo- and oxo(nitrito)molybdenum(V) tetraphenylporphyrin , 1992 .

[27]  K. Suslick,et al.  Photochemical Reduction of Nitrate and Nitrite by Manganese and Iron Porphyrins , 1991 .

[28]  M. Wang,et al.  Structure of the extraction complex bis[(dicyclohexano-18-crown-6)oxonium] hexanitratothorate(IV) isomer A , 1988 .

[29]  D. Fenske,et al.  Synthesen und Kristallstrukturen von [PPh3Me]NO2 und [PPh3 Me]HCO2H2O / Syntheses and Crystal Structures of [PPh3Me]NO2 and [PPh3Me]HCO2H2O , 1988 .

[30]  C. Raston,et al.  Structural and spectroscopic studies of transition metal nitrite complexes. IX.Crystal structures and spectroscopic properties of polymeric [Ni(C2H8N2)2-(NO2)] ClO4, its mononuclear zinc analogue, cis-Bis(ethane-1,2-diamine)(nitrito-O,O')zinc(II) perchlorate, and the complexes cis-(N,N,N',N'-Tetrame , 1981 .

[31]  F. J. Miner,et al.  Radiation Chemistry of Plutonium Nitrate Solutions , 1967 .

[32]  G. Schweitzer,et al.  Radiation-induced nitrite formation from concentrated nitrate solutions , 1958 .