Replacement of fresh water use by final effluent recovery in a highly optimized 100% recovered paper mill.

A further closure of the water circuit in paper mills with a relative high optimization of their water network is limited by the increase of contamination in the water and runnability problems of the paper machine. Therefore, new strategies for saving water must be focussed on the treatment of final effluents of the paper mill, aiming to obtain high quality water that may replace fresh water use in some applications. An appropriate treatment train performed at pilot scale, consisting on a previous clarification stage followed by anaerobic and aerobic treatments, ultrafiltration, and reverse osmosis, made possible producing the highest water quality from the final effluent of the mill. Anaerobic pre-treatment showed very good performance assisting the aerobic stage on removing organics and sulphates, besides it produced enough biogas for being considered as cost-effective. Permeate recovery depended on the silica content of the paper mill effluent, and it was limited to a 50-60%. The reject of the membranes fully met the legislation requirements imposed to effluents arriving to municipal wastewater treatment plants.

[1]  Essam E.A. Ghafour Enhancing RO system performance utilizing antiscalants , 2003 .

[2]  Malik Al-Ahmad,et al.  Biofuoling in RO membrane systems Part 1: Fundamentals and control , 2000 .

[3]  A. E. Greenberg,et al.  Standard methods for the examination of water and wastewater : supplement to the sixteenth edition , 1988 .

[4]  A. Andreadakis PHYSICAL AND CHEMICAL PROPERTIES OF ACTIVATED SLUDGE FLOC , 1993 .

[5]  L. P. A. A. Joore,et al.  Links between process water qualities and product properties : an integral approach to water management in papermaking , 2000 .

[6]  G. Lettinga,et al.  Influent calcium removal by crystallization reusing anaerobic effluent alkalinity , 1997 .

[7]  R. Miranda,et al.  Separation of Contaminants from Deinking Process Water by Dissolved Air Flotation: Effect of Flocculant Charge Density , 2008 .

[8]  Simon Judd,et al.  Membranes for industrial wastewater recovery and re-use , 2003 .

[9]  J.H.J.M. van der Graaf,et al.  Membrane bioreactor technology for wastewater treatment and reuse , 2006 .

[10]  Angeles Blanco,et al.  Accumulation of dissolved and colloidal material in papermaking—Application to simulation , 2009 .

[11]  Usama F. Mahmood,et al.  UASB/EGSB APPLICATIONS FOR INDUSTRIAL WASTEWATER TREATMENT , 2003 .

[12]  Bart Van der Bruggen,et al.  A review of pressure‐driven membrane processes in wastewater treatment and drinking water production , 2003 .

[13]  Oliver J. Hao,et al.  Sulfate‐reducing bacteria , 1996 .

[14]  H. Sirén,et al.  On-line process monitoring of water-soluble ions in pulp and paper machine waters by capillary electrophoresis. , 2004, Journal of chromatography. A.

[15]  C. Forster,et al.  Bulking in activated sludge plants treating paper mill wastewaters. , 2003, Water research.

[16]  A. Garg,et al.  Treatment of pulp and paper mill effluent , 2004 .

[17]  G Thompson,et al.  The treatment of pulp and paper mill effluent: a review. , 2001, Bioresource technology.

[18]  Emmanuel Dialynas,et al.  Integration of a membrane bioreactor coupled with reverse osmosis for advanced treatment of municipal wastewater , 2009 .

[19]  Álvaro Andrés Cajigas Cerón,et al.  IMPORTANCIA DEL pH Y LA ALCALINIDAD EN EL TRATAMIENTO ANAEROBIO DE LAS AGUAS RESIDUALES DEL PROCESO DE EXTRACCIÓN DE ALMIDÓN DE YUCA , 2005 .

[20]  Gatze Lettinga,et al.  Anaerobic Sewage Treatment: A Practical Guide for Regions with a Hot Climate , 1995 .

[21]  Y. H. Kim,et al.  Removal of organics and calcium hardness in liner paper wastewater using UASB and CO2 stripping system , 2003 .

[22]  D. Batstone,et al.  The influence of calcium on granular sludge in a full-scale UASB treating paper mill wastewater. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[23]  Thomas M. Peters,et al.  Membrane bioreactors in wastewater treatment , 2000 .

[24]  Grietje Zeeman,et al.  Anaerobic sewage treatment , 2005 .

[25]  Dieter Pauly Kidney technology for whitewater treatment , 2001 .

[26]  G. Czapar,et al.  [Water quality]. , 1992, Verhandelingen - Koninklijke Academie voor Geneeskunde van Belgie.

[27]  H. Xia,et al.  Relationship between sludge settleability and membrane fouling in a membrane bioreactor , 2007 .

[28]  Grietje Zeeman,et al.  Effect of temperature on anaerobic treatment of black water in UASB-septic tank systems. , 2007, Bioresource technology.

[29]  Gatze Lettinga,et al.  Anaerobic treatment of sulphate-rich wastewaters , 2004, Biodegradation.

[30]  N. Hilal,et al.  A comparative study of the flocculation behaviour and final properties of synthetic and activated sludge in wastewater treatment , 2007 .

[31]  Yulin Deng,et al.  Effects of water-soluble inorganic salts and organic materials on the performance of different polymer retention aids , 1998 .

[32]  C. Negro,et al.  Slime problems in the paper and board industry , 1996, Applied Microbiology and Biotechnology.

[33]  Awwa,et al.  Standard Methods for the examination of water and wastewater , 1999 .