Post-functionalization of novolac resins by introducing thermo-crosslinkable –OCFCF2 groups as the side chains: a new strategy for production of thermosetting polymers without releasing volatiles

Post-functionalization of a commercial novolac resin by introducing thermo-crosslinkable trifluorovinylether groups as the side chains offers a new polymer, which can form a cross-linked network without releasing volatiles during thermal curing. The cured resin shows a lower dielectric constant and higher thermostability than those of most commercial novolac resins.

[1]  Samaresh Ghosh,et al.  Design of novolac resin-based network polymers for adsorptive removal of azo dye molecules , 2016 .

[2]  Jiajia Wang,et al.  New Fluoropolymers Having Both Low Water Uptake and a Low Dielectric Constant , 2015 .

[3]  C. Yuan,et al.  A novel one-pot synthesized organosiloxane: synthesis and conversion to directly thermo-crosslinked polysiloxanes with low dielectric constants and excellent thermostability , 2015 .

[4]  B. Kandola,et al.  Fire and mechanical properties of a novel free-radically cured phenolic resin based on a methacrylate-functional novolac and of its blends with an unsaturated polyester resin , 2015 .

[5]  C. Yuan,et al.  Variable Polymer Properties Driven by Substituent Groups: Investigation on a Trifluorovinylether‐Functionalized Polyfluorene at the C‐9 Position , 2015 .

[6]  B. Kandola,et al.  Blends of unsaturated polyester and phenolic resins for application as fire-resistant matrices in fibre-reinforced composites. Part 2: Effects of resin structure, compatibility and composition on fire performance , 2015 .

[7]  Jiajia Wang,et al.  Postpolymerization of Functional Organosiloxanes: An Efficient Strategy for Preparation of Low-k Material with Enhanced Thermostability and Mechanical Properties , 2014 .

[8]  L. Pilato Phenolic resins: 100Years and still going strong , 2013 .

[9]  L. Pilato,et al.  Phenolic Resins: A Century of Progress , 2010 .

[10]  E. T. Thachil,et al.  Epoxidized phenolic novolac: A novel modifier for unsaturated polyester resin , 2006 .

[11]  C. R. Nair Advances in addition-cure phenolic resins , 2004 .

[12]  P. Adriaensens,et al.  Fully quantitative carbon-13 NMR characterization of resol phenol–formaldehyde prepolymer resins , 2004 .

[13]  T. Zhao,et al.  Thermosetting resin system based on novolak and bismaleimide for resin-transfer molding , 2002 .

[14]  C. R. Nair Non-conventional phenolic resins: An overview on recent advances , 2002 .

[15]  D. Mathew,et al.  Imido-phenolic-triazine network polymers derived from maleimide-functional novolac , 2001 .

[16]  C. R. Nair,et al.  Thermal characteristics of addition-cure phenolic resins , 2001 .

[17]  M. Sankarapandian,et al.  Structure–property relationships of void-free phenolic–epoxy matrix materials , 2000 .

[18]  F. Harris,et al.  Synthesis and thermal properties of fluorosilicones containing perfluorocyclobutane rings , 2000 .

[19]  P. Adriaensens,et al.  Quantitative carbon-13 solid-state n.m.r. and FT–Raman spectroscopy in novolac resins , 1998 .

[20]  C. R. Nair,et al.  Cyanate esters based on cardanol modified‐phenol‐formaldehyde resins: Syntheses and thermal characteristics , 1995 .

[21]  E. Woo,et al.  Soluble copolyimides with high modulus and low moisture absorption , 1993 .

[22]  Andre Knop,et al.  Phenolic Resins: Chemistry, Applications, Standardization, Safety and Ecology , 1985 .