Quantile regression of indoor air concentrations of volatile organic compounds (VOC).

There are many factors determining the concentration of volatile organic compounds (VOCs) in indoor air. On the basis of 601 population-based measurements we develop an explicit exposure model that includes factors, such as renovation, furniture, flat size, smoking, and education level of the occupants. As a novel method for the evaluation of concentrations of indoor air pollutants we use quantile regression, which has the advantages of robustness against non-Gaussian distributions (and outliers) and can adjust for unbalanced frequencies of observations. The applied bi- and multivariate quantile regressions provide (1) the VOC burden that is representative for the population of Leipzig, Germany, and (2) an inter-comparison of the effects of the studied factors and their levels. As a result, we find strong evidence for factors of general impact on most VOC components, such as the season, flooring, the type of the room, and the size of the apartment. Other impact factors are very specific to the VOC components. For example, wooden flooring (parquet) and new furniture increase the concentration of terpenes as well as the modifying factors high education and sampling in the child's room. Smokers ventilate their flats in an extent that in general reduces the VOC concentrations, except for benzene (contained in tobacco smoke), which is still higher in smoking than in non-smoking flats. Very often dampness is associated with an increased VOC burden in indoor air. An investigation of mixtures emphasises a high burden of co-occurring terpenes in very small and very large apartments.

[1]  Chunrong Jia,et al.  Distributions of personal VOC exposures: a population-based analysis. , 2008, Environment international.

[2]  Uwe Schlink,et al.  Seasonal cycle of indoor-VOCs: comparison of apartments and cities , 2004 .

[3]  Erik Lebret,et al.  Air Pollution Exposure in European Cities: The "Expolis" Study. , 1998 .

[4]  Lance Wallace,et al.  HUMAN EXPOSURE TO VOLATILE ORGANIC POLLUTANTS: Implications for Indoor Air Studies ⁄ , 2001 .

[5]  Charles J. Weschler,et al.  Comparisons among VOCs Measured in Three Types of U.S. Commercial Buildings with Different Occupant Densities , 1996 .

[6]  Keming Yu,et al.  Quantile regression: applications and current research areas , 2003 .

[7]  R. Bono,et al.  Volatile halogenated hydrocarbons in urban atmosphere and in human blood. , 1990, Archives of environmental health.

[8]  H. Wichmann,et al.  Indoor and outdoor BTX levels in German cities. , 2001, The Science of the total environment.

[9]  Uwe Schlink,et al.  Spatiotemporal distribution of airborne mould spores in apartments. , 2003, Mycological research.

[10]  Jonathan I Levy,et al.  Measured and modeled personal exposures to and risks from volatile organic compounds. , 2007, Environmental science & technology.

[11]  L. Mølhave,et al.  Human reactions to low concentrations of volatile organic compounds , 1986 .

[12]  Gavin C. Cawley,et al.  Statistical models to assess the health effects and to forecast ground-level ozone , 2006, Environ. Model. Softw..

[13]  M. Hippelein Background concentrations of individual and total volatile organic compounds in residential indoor air of Schleswig-Holstein, Germany. , 2004, Journal of environmental monitoring : JEM.

[14]  Peder Wolkoff Volatile Organic Compounds Sources, Measurements, Emissions, and the Impact on Indoor Air Quality , 1995 .

[15]  Passive sampling for volatile organic compounds (VOCs) in air at environmentally relevant concentration levels , 1995 .

[16]  O. Herbarth,et al.  Seasonal cycle of VOCs in apartments. , 2003, Indoor air.

[17]  Aromatic hydrocarbons in the atmospheric environment – Part II: univariate and multivariate analysis and case studies of indoor concentrations , 2001 .

[18]  Christine Schulz,et al.  Seasonal variation of concentrations of volatile organic compounds in selected German homes , 1989 .

[19]  P. Sly,et al.  Increased asthma and respiratory symptoms in children exposed to petrochemical pollution. , 2009, The Journal of allergy and clinical immunology.

[20]  P. Lioy,et al.  Current State of the Science: Health Effects and Indoor Environmental Quality , 2007, Environmental health perspectives.

[21]  S. Batterman,et al.  Ethnicity, housing and personal factors as determinants of VOC exposures , 2009 .

[22]  O. Herbarth,et al.  Pollution profiles at different kindergarten sites in Leipzig, Germany , 1999 .

[23]  Stephen K. Brown,et al.  Concentrations of Volatile Organic Compounds in Indoor Air – A Review , 1994 .

[24]  Chunrong Jia,et al.  VOCs in industrial, urban and suburban neighborhoods, Part 1: Indoor and outdoor concentrations, variation, and risk drivers , 2008 .

[25]  J. Bortz,et al.  Verteilungsfreie Methoden in der Biostatistik , 1982 .

[26]  G. Ananth,et al.  Human Activities as Sources of Volatile Organic Compounds in Residential Environments , 1992, Annals of the New York Academy of Sciences.

[27]  Chunrong Jia,et al.  VOCs in industrial, urban and suburban neighborhoods—Part 2: Factors affecting indoor and outdoor concentrations , 2008 .

[28]  J. Konz,et al.  Exposure factors handbook , 1989 .

[29]  R. Edwards,et al.  Benzene exposure in Helsinki, Finland , 2001 .

[30]  C Sparacino,et al.  The TEAM (Total Exposure Assessment Methodology) Study: personal exposures to toxic substances in air, drinking water, and breath of 400 residents of New Jersey, North Carolina, and North Dakota. , 1987, Environmental research.