Using a superconducting tunnel junction detector to measure the secondary electron emission efficiency for a microchannel plate detector bombarded by large molecular ions

An energy-sensitive superconducting tunnel junction (STJ) detector was used to measure the secondary electron emission efficiency, epsilon(e), for a microchannel plate (MCP) detector bombarded by large (up to 66 kDa), slow moving (<40 km/s) molecular ions. The method used is new and provides a more direct procedure for measuring the efficiency of secondary electron emission from a surface. Both detectors were exposed simultaneously to nearly identical ion fluxes. By exposing only a small area of the MCP detector to ions, such that the area exposed was effectively the same as the size of the STJ detector, the number of ions detected with each detector were directly comparable. The STJ detector is 100% efficient for detecting ions in the energy regime investigated and therefore it can be used to measure the detection efficiency and secondary electron emission efficiency of the MCP. The results are consistent with measurements made by other groups and provide further characterization of the loss in sensitivity noted previously when MCP detectors have been used to detect high-mass ions. Individual molecular ions of mass 66 kDa with 30 keV kinetic energy were measured to have about a 5% probability of producing one or more electrons when impacting the MCP. When ion energy was reduced to 10 keV, the detection probability decreased to 1 %. The secondary electron yield was calculated from the secondary electron emission efficiency and found to scale linearly with the mass of the impinging molecular ion and to about the fourth power of ion velocity. Secondary electrons were observed for primary ion impacts >5 km/s, regardless of mass, and no evidence of a velocity (detection) threshold was observed. Copyright 2000 John Wiley & Sons, Ltd.

[1]  Frank,et al.  Investigating ion-surface collisions with a niobium superconducting tunnel junction detector in a time-of-flight mass spectrometer , 2000, Rapid communications in mass spectrometry : RCM.

[2]  F. Dubois,et al.  An ion-to-photon conversion detector for mass spectrometry , 1997 .

[3]  M. Frank,et al.  Simultaneous measurement of flight time and energy of large matrix-assisted laser desorption ionization ions with a superconducting tunnel junction detector , 1997 .

[4]  P. Chaurand,et al.  Secondary Electron Emission Yields from a CsI Surface Under Impacts of Large Molecules at Low Velocities (5 × 103-7 × 104 ms-1) , 1997 .

[5]  W. Ens,et al.  Secondary ion and electron yield measurements for surfaces bombarded with large molecular ions , 1996 .

[6]  P. Chaurand,et al.  Surface secondary electron and secondary ion emission induced by large molecular ion impacts , 1993 .

[7]  D. Kirsch,et al.  The detection of large molecules in matrix‐assisted UV‐laser desorption , 1990 .

[8]  P. Geno,et al.  Secondary electron emission induced by impact of low-velocity molecular ions on a microchannel plate , 1989 .

[9]  A. Hedin,et al.  On the detection of large organic ions by secondary electron production , 1987 .

[10]  R. Beuhler A comparison of secondary electron yields from accelerated water cluster ions (M/z<50 000) striking Al2O3 and copper surfaces , 1983 .

[11]  L. Friedman,et al.  Threshold studies of secondary electron emission induced by macro-ion impact on solid surfaces , 1980 .

[12]  M. Frank,et al.  Energy-sensitive cryogenic detectors for high-mass biomolecule mass spectrometry. , 1999, Mass spectrometry reviews.

[13]  W. H. Benner,et al.  High-efficiency Detection of 66 000 Da Protein Molecules Using a Cryogenic Detector in a Matrix-assisted Laser Desorption/Ionization Time-of-flight Mass Spectrometer , 1996 .

[14]  K. Wien,et al.  Detection of large cluster ions by ion-to-ion conversion , 1996 .

[15]  W. H. Benner,et al.  Molecular weight determination of megadalton DNA electrospray ions using charge detection time-of-flight mass spectrometry. , 1995, Rapid communications in mass spectrometry : RCM.