Challenges in biodiesel industry with regards to feedstock, environmental, social and sustainability issues: a critical review.

This paper addresses the challenges in developing a sustainable biodiesel industry especially in Malaysia. The challenges discussed in this paper are divided into three main sections covering issues before, during and after biodiesel processing. The pre-processing problems concern the feedstock market, legislation through policies, fuel–food competition, deforestation issue and alternative feedstock conflict. Problems with regards to the uncontrollable glycerol production and its global market crisis are also reviewed. Besides, some suggestions on poising back the glycerol market stability are reviewed through several upgrading processes and methods that can convert glycerol to its functional chemicals. The last section covers the social issue of biodiesel in obtaining people׳s acceptance and capability of this industry to cultivate the sustainable practices along the processing line. Moreover, challenges in verifying its commercial value by fulfilling the global biofuel standards are also highlighted.

[1]  M. Othman,et al.  Etherification of glycerol to polyglycerols over hydrotalcite catalyst prepared using a combustion method , 2013 .

[2]  M. V. Sivaiah,et al.  Recent developments in acid and base-catalyzed etherification of glycerol to polyglycerols , 2012 .

[3]  Michele Aresta,et al.  A study on the carboxylation of glycerol to glycerol carbonate with carbon dioxide: The role of the catalyst, solvent and reaction conditions , 2006 .

[4]  Rosaria Ciriminna,et al.  Recent advances in the conversion of bioglycerol into value-added products. , 2009 .

[5]  Sharifah Rafidah Wan Alwi,et al.  Issues of social acceptance on biofuel development , 2014 .

[6]  Tick Hui Oh,et al.  Green progress and prospect in Malaysia , 2011 .

[7]  Wei Wang,et al.  Microbial production of 1,3-propanediol by Klebsiella pneumoniae using crude glycerol from biodiesel preparations , 2006, Biotechnology Letters.

[8]  P. Mohanan,et al.  POTENTIAL OF WASTE COOKING OIL AS BIODIESEL FEEDSTOCK , 2007 .

[9]  Brent H. Shanks,et al.  Effect of sulfur and temperature on ruthenium-catalyzed glycerol hydrogenolysis to glycols , 2005 .

[10]  Andreas Martin,et al.  Glycerol upgrading over zeolites by batch-reactor liquid-phase oligomerization: heterogeneous versus homogeneous reaction. , 2008, ChemSusChem.

[11]  I. Henson,et al.  Physiological analysis of an oil palm density trial on a peat soil. , 2003 .

[12]  Josep G. Canadell,et al.  Current and future CO 2 emissions from drained peatlands in Southeast Asia , 2009 .

[13]  R. Howard-Hildige,et al.  The effect of steam treating waste cooking oil on the yield of methyl ester , 2002 .

[14]  Zlatica J. Predojevic,et al.  The production of biodiesel from waste frying oils: A comparison of different purification steps , 2008 .

[15]  Muhammad Ayoub,et al.  Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry , 2012 .

[16]  C. Hall,et al.  Energy and the U.S. Economy: A Biophysical Perspective , 1984, Science.

[17]  Jyh-Shyong Chang,et al.  Optimization on the etherification of glycerol with tert-butyl alcohol , 2011 .

[18]  A. Faaij,et al.  Steps towards the development of a certification system for sustainable bio-energy trade , 2006 .

[19]  Subhash Bhatia,et al.  Current status and policies on biodiesel industry in Malaysia as the world's leading producer of palm oil , 2009 .

[20]  Md. Abul Kalam,et al.  An Overview of Biofuel as a Renewable Energy Source: Development and Challenges , 2013 .

[21]  Bishnu Raj Upreti,et al.  Conflict over biomass energy development in the United Kingdom: some observations and lessons from England and Wales , 2004 .

[22]  Haji Hassan Masjuki,et al.  A review on energy pattern and policy for transportation sector in Malaysia , 2012 .

[23]  D. Leung,et al.  A review on biodiesel production using catalyzed transesterification , 2010 .

[24]  Francis X. Johnson,et al.  A review of environmental issues in the context of biofuel sustainability frameworks , 2011 .

[25]  M. Pagliaro,et al.  From glycerol to value-added products. , 2007, Angewandte Chemie.

[26]  S. Zailani,et al.  Green supply chain initiatives among certified companies in Malaysia and environmental sustainability: Investigating the outcomes , 2011 .

[27]  L. Reijnders Conditions for the sustainability of biomass based fuel use , 2006 .

[28]  A. Corma,et al.  Synthesis of hyacinth, vanilla, and blossom orange fragrances: the benefit of using zeolites and delaminated zeolites as catalysts , 2004 .

[29]  Guanyi Chen,et al.  Biodiesel production from waste cooking oil via alkali catalyst and its engine test , 2008 .

[30]  Teuku Meurah Indra Mahlia,et al.  Prospects of dedicated biodiesel engine vehicles in Malaysia and Indonesia , 2011 .

[31]  T. Buchholz,et al.  Sustainability criteria for bioenergy systems: results from an expert survey , 2009 .

[32]  Tomohisa Miyazawa,et al.  Glycerol conversion in the aqueous solution under hydrogen over Ru/C + an ion-exchange resin and its reaction mechanism , 2006 .

[33]  Pedro Felizardo,et al.  Production of biodiesel from waste frying oils. , 2006, Waste management.

[34]  Andreas Martin,et al.  Homogeneously catalyzed batch reactor glycerol etherification by CsHCO3 , 2008 .

[35]  Philippe Soucaille,et al.  Metabolic engineering of Clostridium acetobutylicum for the industrial production of 1,3-propanediol from glycerol. , 2005, Metabolic engineering.

[36]  Z. Mouloungui,et al.  Catalytic carbonylation of glycerin by urea in the presence of zinc mesoporous system for the synthesis of glycerol carbonate , 2003 .

[37]  Haji Hassan Masjuki,et al.  Prospects of biodiesel from Jatropha in Malaysia , 2012 .

[38]  Wolter Prins,et al.  Gasification of Model Compounds and Wood in Hot Compressed Water , 2006 .

[39]  J. C. Thompson,et al.  Characterization of crude glycerol from biodiesel production from multiple feedstocks. , 2006 .

[40]  K. Chua,et al.  PRODUCTION OF ETHYL ESTER (BIODIESEL) FROM USED FRYING OIL: OPTIMIZATION OF TRANSESTERIFICATION PROCESS USING MICROWAVE IRRADIATION , 2004 .

[41]  M. Stelmachowski Utilization of glycerol, a by-product of the transestrification process of vegetable oils: a review , 2011 .

[42]  Haji Hassan Masjuki,et al.  A comprehensive review on biodiesel as an alternative energy resource and its characteristics , 2012 .

[43]  Ramon Gonzalez,et al.  Anaerobic fermentation of glycerol by Escherichia coli: a new platform for metabolic engineering. , 2006, Biotechnology and bioengineering.

[44]  T. Foglia,et al.  Fuel properties and nitrogen oxide emission levels of biodiesel produced from animal fats , 2005 .

[45]  Hans Joosten,et al.  Greenhouse gas fluxes from tropical peatlands in south‐east Asia , 2009 .

[46]  A. Phan,et al.  Biodiesel production from waste cooking oils , 2008 .

[47]  Steven Lim,et al.  Recent trends, opportunities and challenges of biodiesel in Malaysia: An overview , 2010 .

[48]  B. Weckhuysen,et al.  Glycerol etherification over highly active CaO-based materials: new mechanistic aspects and related colloidal particle formation. , 2008, Chemistry.

[49]  C. Cleveland Net energy from the extraction of oil and gas in the United States , 2005 .

[50]  Arno Behr,et al.  Improved utilisation of renewable resources: New important derivatives of glycerol , 2008 .

[51]  Anwar Johari,et al.  A source of renewable energy in Malaysia, why biodiesel? , 2014 .

[52]  Kevin Kendall,et al.  Steam reforming of biodiesel by-product to make renewable hydrogen. , 2008, Bioresource technology.

[53]  Carlos Araujo,et al.  Biodiesel production from used cooking oil: A review , 2013 .

[54]  Yusof Basiron,et al.  An evaluation of the sustainability of some biofuel feedstocks. , 2013 .

[55]  Jürgen Krahl,et al.  The Biodiesel Handbook , 2005 .

[56]  Andreas Martin,et al.  Oligomerization of glycerol – a critical review , 2011 .

[57]  Ekko C. van Ierland,et al.  A holistic sustainability assessment tool for bioenergy using the Global Bioenergy Partnership (GBEP) sustainability indicators , 2014 .

[58]  R. Lago,et al.  Acid-catalyzed oligomerization of glycerol investigated by electrospray ionization mass spectrometry , 2009 .

[59]  Naoko Ellis,et al.  Perspectives on biodiesel as a sustainable fuel , 2010 .

[60]  Ján Cvengroš,et al.  Used frying oils and fats and their utilization in the production of methyl esters of higher fatty acids , 2004 .

[61]  K. Obidzinski,et al.  Withering before full bloom? Bioenergy in Southeast Asia. , 2012 .

[62]  A. Javidialesaadi,et al.  Biodiesel Production from High Free Fatty Acid-Content Oils: Experimental Investigation of the Pretreatment Step , 2013 .

[63]  Andreas Martin,et al.  Dehydration of glycerol in gas phase using heteropolyacid catalysts as active compounds , 2008 .

[64]  G. Hutchings,et al.  Oxidation of glycerol using supported Pt, Pd and Au catalysts , 2003 .

[65]  Wolf-Dieter Deckwer,et al.  Microbial conversion of glycerol to 1,3-propanediol , 1995 .

[66]  C. Piantadosi,et al.  The Preparation of Cyclic Glycerol Acetals by Transacetalation1 , 1958 .

[67]  H. Lieske,et al.  Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetals , 2007 .

[68]  C. Márquez-Álvarez,et al.  Solid Catalysts for the Synthesis of Fatty Esters of Glycerol, Polyglycerols and Sorbitol from Renewable Resources , 2004 .

[69]  Saad Mekhilef,et al.  A review on palm oil biodiesel as a source of renewable fuel , 2011 .

[70]  Rolf Wüstenhagen,et al.  Social acceptance of renewable energy innovation: An introduction to the concept , 2007 .

[71]  R. Moreno-Tost,et al.  Etherification of glycerol to polyglycerols over MgAl mixed oxides , 2011 .

[72]  Antonio Valero,et al.  Assessment of biodiesel energy sustainability using the exergy return on investment concept , 2012 .

[73]  Sharifah Rafidah Wan Alwi,et al.  Energy Efficiency Award system in Malaysia for energy sustainability , 2010 .

[74]  H. Kimura Poly(ketomalonate) by catalytic oxidation of glycerol(4)anionic polymerization , 1998 .

[75]  James A. Dumesic,et al.  A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts , 2005 .

[76]  M. Guerrero-Pérez,et al.  Recent Inventions in Glycerol Transformations and Processing , 2009 .

[77]  M. G. Kulkarni,et al.  PRODUCTION OF BIODIESEL FROM WASTE FRYER GREASE USING MIXED METHANOL/ETHANOL SYSTEM , 2007 .

[78]  Man Kee Lam,et al.  Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: a review. , 2010, Biotechnology advances.

[79]  A. Behr,et al.  Highly Selective Biphasic Telomerization of Butadiene with Glycols: Scope and Limitations , 2003 .

[80]  Martin Bajus,et al.  Etherification of glycerol and ethylene glycol by isobutylene , 2007 .

[81]  Fabio E. Sierra,et al.  Biodiesel Production from Waste Cooking Oil , 2011 .

[82]  M. Almeida,et al.  Comparison of the performance of different homogeneous alkali catalysts during transesterification of waste and virgin oils and evaluation of biodiesel quality , 2008 .

[83]  Jens J. Dahlgaard,et al.  Sustainability exploration and sustainability exploitation: from a literature review towards a conceptual framework , 2014 .

[84]  A. Showler,et al.  Condensation products of glycerol with aldehydes and ketones. 2-Substituted m-dioxan-5-ols and 1,3-dioxolane-4-methanols. , 1967, Chemical reviews.

[85]  R. Gonzalez,et al.  Anaerobic fermentation of glycerol: a path to economic viability for the biofuels industry. , 2007, Current opinion in biotechnology.

[86]  M. G. Kulkarni,et al.  WASTE COOKING OIL – AN ECONOMICAL SOURCE FOR BIODIESEL: A REVIEW , 2006 .

[87]  Julien Chaminand,et al.  Glycerol hydrogenolysis on heterogeneous catalysts , 2004 .

[88]  S. Vollenweider,et al.  3-Hydroxypropionaldehyde: applications and perspectives of biotechnological production , 2004, Applied Microbiology and Biotechnology.

[89]  A. Abdullah,et al.  Shape Selectivity Effects in Etherification of Glycerol to Diglycerol Isomers in a Solvent-Free Reaction System by Li–Mg/SBA-15 Catalyst , 2014, Catalysis Letters.