Fulvene having substituents only on 1-, 4-, and 6-positions: a key intermediate for novel ansa-metallocene complexes

[1]  In Su Lee,et al.  Synthesis of [2,2‘-Methylenebis(1,3-dimethylcyclopentadienyl)]zirconium Dichloride and Its Reactivity in Ethylene−Norbornene Copolymerization , 2002 .

[2]  G. Erker,et al.  Formation of sp3-C1-Bridged Cp/Amido Titanium and Zirconium “CpCN” Constrained-Geometry Ziegler−Natta Catalyst Systems , 2002 .

[3]  J. Barluenga,et al.  New reaction pathways for Fischer carbene complexes: [6 + 3] cycloaddition of chromium alkenyl carbene complexes with fulvenes. , 2001, Journal of the American Chemical Society.

[4]  A. Lützen,et al.  A Novel Route to Fulvene Complexes of Titanium-Diastereoselective Complexation of Pentafulvenes to Cyclopentadienyltitanium Fragments. , 2001, Angewandte Chemie.

[5]  In Su Lee,et al.  Synthesis of titanium trichloride complexes of 1,2,3-trisubstituted cyclopentadienyls and their use in styrene polymerization , 2001 .

[6]  E. Hey‐Hawkins,et al.  Unexpected P-Si or P-C Bond Cleavage in the Reaction of Li2[(C5Me4)SiMe2-PR] (R = Cyclohexyl, 2,4,6-Me3C6H2) and Li[(C5H4)CMe2-PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]: Formation and Molecular Structure of the ansa-Metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2] (M = Ti, Zr) , 2000 .

[7]  Soon W. Lee,et al.  SYNTHESIS OF BIS(1,2,3-SUBSTITUTED CYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE DERIVATIVES AND THEIR USE IN ETHYLENE POLYMERIZATION , 1999 .

[8]  C. Lee,et al.  Synthesis of palladium and platinum complexes containing the multidentate ligands PPh2CH2(tBu)NNC(R)Q (R=H, Me; Q=2-pyridine, 2-thiophene, o-BrC6H4). Crystal structure of [PtMe{PPh2CHC(tBu)NNCMe(2-py)-κ3N,N′,P}] and [PdBr{PPh2CH2C(tBu)NNCHC6H4}-κ3C,N,P] , 1999 .

[9]  J. Eisch,et al.  Novel Synthesis of ansa-Metallocenes via the Reductive Dimerization of Fulvenes with Group 4 Metal Divalent Halides1 , 1998 .

[10]  H. Alt,et al.  C1-Bridged fluorenylidene cyclopentadienylidene complexes of the type (C13H8–CR1R2–C5H3R)ZrCl2 (R1, R2=alkyl, phenyl, alkenyl; R=H, alkyl, alkenyl, substituted silyl) as catalyst precursors for the polymerization of ethylene and propylene , 1998 .

[11]  P. Fanwick,et al.  Trimerization of tert-Butylacetylene to 1,3,6-Tri(tert-butyl)fulvene Catalyzed by Titanium Aryloxide Compounds , 1997 .

[12]  A. Segre,et al.  Full assignment of the 13C NMR spectra of regioregular polypropylenes : Methyl and methylene region , 1997 .

[13]  H. Alt,et al.  Syndiospezifische polymerisation von propylen: Neue metallocenkomplexes des typs (C13H8−nRnCR′R″C5H4)MCl2n = 0,2; R = Alkyl, Aryl, Hal; R′, R″ = H, Alkyl, Aryl; M = Zr, Hf) unter besonderer berücksichtigung verschiedener brückensubstituenten , 1996 .

[14]  W. Kaminsky,et al.  A Tailor‐Made Metallocene for the Copolymerization of Ethene with Bulky Cycloalkenes , 1995 .

[15]  I. Erden,et al.  Scope and Limitations of Fulvene Syntheses. Preparation of 6-Vinyl-Substituted and -Functionalized Fulvenes. First Examples of Nucleophilic Substitution on a 6-(Chloromethyl)fulvene , 1995 .

[16]  J. Atwood,et al.  Preparation and crystal structures of the complexes (η5-C5H4CPh2-η5-C13H8) MCl2 (M Zr, Hf) and the catalytic formation of high molecular weight high tacticity syndiotactic polypropylene , 1993 .

[17]  G. Erker,et al.  Synthesis of ansa-metallocenes by intramolecular photochemical [2 + 2] cycloaddition of bis(alkenylcyclopentadienyl)zirconium complexes , 1993 .

[18]  R. L. Halterman Synthesis and Applications of Chiral Cyclopentadienylmetal Complexes , 1992 .

[19]  H. N. Cheng Comonomer sequence distribution in ethylene/1-hexene copolymers , 1991 .

[20]  M. Garst,et al.  A new synthesis of substituted fulvenes , 1990 .

[21]  N. Taylor,et al.  General synthetic routes to chiral, ethylene-bridged ansa-titanocene dichlorides , 1990 .

[22]  D. Mallin,et al.  rac-[Ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)]dichlorotitanium and its homopolymerization of propylene to crystalline-amorphous block thermoplastic elastomers , 1990 .

[23]  R. Little,et al.  An exceptionally simple and efficient method for the preparation of a wide variety of fulvenes , 1984 .

[24]  P. Hodge,et al.  Protective groups in organic synthesis , 1981 .

[25]  P. Wovkulich,et al.  An efficient synthesis of α-substituted α,β-unsaturated ketones employing a versatile latent α-ketovinyl anion equivalent , 1978 .