Supercritical carbon dioxide cleaning of metal parts for remanufacturing industry

The cleaning of metal parts, as stage of a remanufacturing process, should be environmentally benign and it is therefore essential to propose a new cleaning technology which can reduce or remove environmental contamination. Therefore the research presented in this paper investigates the feasibility of using supercritical carbon dioxide (SC–CO2) as a cleaning agent, here on a laboratory scale. The effect on the cleaning performance of different parameters – including cleaning temperature (65–75 °C); pressure (22.0–25.0 MPa); flow rate of CO2 (4.8–6.8 L/h); cleaning time (30–40 min); and with or without dehydrated ethyl alcohol as a co-solvent – was examined, using the fractional factorial design of experiments. Based on the experimental data, a second order polynomial model was established to analyse the interaction between distinct variables, which was beneficial in optimising system performance. In addition, degreasing processes of remanufacturing metal parts were also tested. The experimental results indicated that supercritical carbon dioxide was excellent at decontamination during the remanufacturing cleaning process, but it was easily affected by variations of the operating parameters. In the tested range, with dehydrated ethyl alcohol as co-solvent, a calculated cleaning performance index could be up to 89.30% under the temperature 75 °C and pressure 25.0 MPa, respectively. Therefore, it is concluded that supercritical carbon dioxide can be used in the remanufacturing process for removing contamination from the surface of used metal parts.

[1]  N. Robert Sorensen,et al.  Corrosive effects of supercritical carbon dioxide and cosolvents on metals , 1996 .

[2]  M. Seitz A critical assessment of motives for product recovery: the case of engine remanufacturing , 2007 .

[3]  C. Erkey,et al.  Thermodynamic Control of Metal Loading and Composition of Carbon Aerogel Supported Pt–Cu Alloy Nanoparticles by Supercritical Deposition , 2013 .

[4]  O. Çiftçi,et al.  Continuous production of fatty acid methyl esters from corn oil in a supercritical carbon dioxide bioreactor , 2011 .

[5]  R. Shubkin Synthetic lubricants and high-performance functional fluids , 1992 .

[6]  D. Prajapati,et al.  Recent advances in the application of supercritical fluids for carbon–carbon bond formation in organic synthesis , 2004 .

[7]  Douglas C. Montgomery,et al.  Applied Statistics and Probability for Engineers, Third edition , 1994 .

[8]  Leon P.B.M. Janssen,et al.  Supercritical carbon dioxide as a green solvent for processing polymer melts: Processing aspects and applications , 2006 .

[9]  Ernesto Reverchon,et al.  Supercritical cleaning of rollers for printing and packaging industry , 2006 .

[10]  M. I. Barrena,et al.  The removal of lubricating oils from metallic contacts with supercritical CO2 , 2013 .

[11]  J. Sherman,et al.  Solvent replacement for green processing. , 1998, Environmental health perspectives.

[12]  Z. S. Hu,et al.  Preparation of nanometer titanium oxide with n-butanol supercritical drying , 1999 .

[13]  Woo-Sik Kim,et al.  Separation of astaxanthin from red yeast Phaffia rhodozyma by supercritical carbon dioxide extraction , 2002 .

[14]  Elisabeth Badens,et al.  Supercritical CO2 extraction of neutral lipids from microalgae: Experiments and modelling , 2013 .

[15]  K. Zosel Separation with Supercritical Gases: Practical Applications , 1978 .

[16]  Olivier Renault,et al.  Copper cleaning in supercritical CO2 for the microprocessor interconnects , 2008 .

[17]  Surendra M. Gupta,et al.  Remanufacturing Modeling and Analysis , 2012 .

[18]  F. Hernández‐Fernández,et al.  Understanding the chemical reaction and mass-transfer phenomena in a recirculating enzymatic membrane reactor for green ester synthesis in ionic liquid/supercritical carbon dioxide biphasic systems , 2007 .

[19]  J. Hannay,et al.  I. On the solubility of solids in gases , 1880, Proceedings of the Royal Society of London.

[20]  Eric J. Beckman,et al.  Supercritical and near-critical CO2 in green chemical synthesis and processing , 2004 .

[21]  Wei-Wei Liu,et al.  An environmentally friendly approach for contaminants removal using supercritical CO2 for remanufacturing industry , 2014 .

[22]  N. Foster,et al.  Antioxidant activity, yield and chemical composition of lavender essential oil extracted by supercritical CO2 , 2012 .

[23]  B. Simándi,et al.  Supercritical carbon dioxide extraction and fractionation of fennel oil. , 1999, Journal of agricultural and food chemistry.

[24]  María Teresa Lamata,et al.  Selection of a cleaning system for engine maintenance based on the analytic hierarchy process , 2009, Comput. Ind. Eng..

[25]  E. Bok,et al.  SUPERCRITICAL FLUIDS FOR SINGLE WAFER CLEANING , 1992 .

[26]  H. Inomata,et al.  A kinetic study of organic compounds (acetone, toluene, n-hexane and n-decane) adsorption behavior on activated carbon under supercritical carbon dioxide conditions at temperature from 313 to 353 K and at pressure from 4.2 to 15.0 MPa , 2014 .

[27]  A. W. Francis Ternary aqueous systems , 1967 .

[28]  Bin Zhang,et al.  Study on Remanufacturing Cleaning Technology in Mechanical Equipment Remanufacturing Process , 2013 .

[29]  Minghui Hong,et al.  Laser surface cleaning of carbonaceous deposits on diesel engine piston , 2013 .

[30]  Geert-Jan Witkamp,et al.  Dry-cleaning with high-pressure carbon dioxide—the influence of mechanical action on washing-results , 2003 .

[31]  H. J. Arnold Introduction to the Practice of Statistics , 1990 .

[32]  S. Hawthorne,et al.  Introducing selective supercritical fluid extraction as a new tool for determining sorption/desorption behavior and bioavailability of persistent organic pollutants in sediment. , 2000, Journal of biochemical and biophysical methods.

[33]  Jiju Antony,et al.  Design of experiments for engineers and scientists , 2003 .

[34]  Yasunori Kikuchi,et al.  Analysis of risk trade-off relationships between organic solvents and aqueous agents: case study of metal cleaning processes , 2011 .

[35]  M. Matthews,et al.  Comparison between supercritical carbon dioxide extraction and aqueous surfactant washing of an oily machining waste. , 1999, Journal of hazardous materials.

[36]  R. Schlosberg,et al.  High stability esters for synthetic lubricant applications , 2001 .

[37]  Geert-Jan Witkamp,et al.  Dry-cleaning with high-pressure carbon dioxide—the influence of process conditions and various co-solvents (alcohols) on cleaning-results , 2003 .

[38]  Douglas H. Timmer,et al.  Modeling and optimization of the molten salt cleaning process , 2014 .

[39]  L. Rothman,et al.  Precision parts cleaning using supercritical fluids , 1993 .