Catalytic performance of cellulose supported palladium complex for Heck reaction in water

Cellulose supported palladium complex was synthesized and characterized by XPS, TG/DTA etc. The complex was found to be an efficient catalyst for Heck reaction of acrylic acid or styrene with aryl iodides at low temperature in water under atmospheric condition, the substituted trans-cinnamic acid or 1,2-stilbene was obtained in stereoselectivity. Repeated tests showed that the catalyst have good reusability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008

[1]  B. Sreedhar,et al.  Cellulose supported palladium(0) catalyst for Heck and Sonogashira coupling reactions , 2006 .

[2]  Lei Zhang,et al.  Synthesis of chitosan derivatives supported palladium complexes and their catalytic behavior in the Heck reaction , 2005 .

[3]  H. Doucet,et al.  Heck Reaction of Protected Allyl Alcohols with Aryl Bromides Catalyzed by a Tetraphosphanepalladium Complex , 2005 .

[4]  V. Farina High‐Turnover Palladium Catalysts in Cross‐Coupling and Heck Chemistry: A Critical Overview , 2004 .

[5]  Mingzhong Cai,et al.  Synthesis of silica-supported bidentate arsine palladium complex and its catalytic properties for amidation/butoxycarbonylation of aryl halides , 2004 .

[6]  Mingzhong Cai,et al.  Synthesis of silica-supported poly-γ-diphenylarsinopropylsiloxane palladium complex and its catalytic behavior for Heck carbonylation of aryl halides , 2004 .

[7]  Ashley J. Wilson,et al.  Chitosan-based heterogeneous catalysts for Suzuki and Heck reactions , 2004 .

[8]  Chih-An Lin,et al.  Polystyrene-supported recyclable palladacycle catalyst for Heck, Suzuki and Sonogashira reactions , 2003 .

[9]  Hong Zhao,et al.  Silica-supported bidentate arsine palladium(0) complex: a highly active and stereoselective catalyst for arylation of conjugated alkenes , 2003 .

[10]  D. Bergbreiter,et al.  Palladium-Catalyzed C−C Coupling under Thermomorphic Conditions , 2000 .

[11]  Schwarz,et al.  Polymer-supported carbene complexes of palladium: well-defined, air-stable, recyclable catalysts for the Heck reaction , 2000, Chemistry.

[12]  R. Heck Palladium‐Catalyzed Vinylation of Organic Halides , 2005 .