Thermal Properties of Residual Agroforestry Biomass of Northern Portugal

Biomass from forestry and agricultural sector provides an important contribution to encounter the government’s targets for increasing bioenergy production and utilization. Characterization of agricultural and forest wastes are critical for exploiting and utilizing them for energy purpose. In the present work agricultural and forest wastes and shrubs were sampled in two sites in north Portugal (Ave and Sabor basin) and subjected to Higher Heating Value (HHV) and chemical composition quantification. The HHV was evaluated according to the methodology described in Standard DD CEN/TS14918:2005. For the lignin content, the procedure was made by the Klason method and the extractives content was determined with the Soxhlet method. For agricultural and forest wastes the HHV values are identical with a range of 17 to 21 MJ·kg−1. However, shrubs biomass presentx slightly higher and statistically different values from agricultural and forest wastes, varying between 19 and 21 MJ·kg−1. Forest wastes contain higher levels of holocellulose compared to agricultural wastes and, with respect to extractive contents, this trend is the reverse. There is a general tendency for the woody components present thermo-chemical properties more suited for energy purposes, than the residues formed by the branches and leaves.

[1]  G. Tsoumis,et al.  Characteristics of Briarwood , 1988 .

[2]  J. Lousada,et al.  Fuel characterization and biomass combustion properties of selected native woody shrub species from central Portugal and NW Spain , 2012 .

[3]  Ilias P. Tatsiopoulos,et al.  Logistics issues of biomass: The storage problem and the multi-biomass supply chain , 2009 .

[4]  K. Varmuza,et al.  Prediction of heating values of biomass fuel from elemental composition , 2005 .

[5]  P. Abdul Salam,et al.  Estimation of higher heating value of biomass from proximate analysis: A new approach , 2012 .

[6]  F. Kačík,et al.  Chemical Profiles of Wood Components of Poplar Clones for Their Energy Utilization , 2012 .

[7]  Ayhan Demirbas,et al.  Relationships between lignin contents and heating values of biomass , 2001 .

[8]  Isabel Cabrita,et al.  The study of reactions influencing the biomass steam gasification process , 2003 .

[9]  J. Bilbao,et al.  Fast characterization of biomass fuels by thermogravimetric analysis (TGA) , 2015 .

[10]  M. Leoni,et al.  Exploring Ulex europaeus to Produce Nontoxic Binderless Fibreboard , 2017 .

[11]  Radu Godina,et al.  Evaluation of the Physical, Chemical and Thermal Properties of Portuguese Maritime Pine Biomass , 2018, Sustainability.

[12]  C. Somerville,et al.  The Implications of Lignocellulosic Biomass Chemical Composition for the Production of Advanced Biofuels , 2014 .

[13]  D. Athanassiadis,et al.  Basic chemical composition of the biomass components of pine, spruce and birch , 2013 .

[14]  José Lousada,et al.  The explained variation by lignin and extractive contents on higher heating value of wood , 2011 .

[15]  C. Gourdon,et al.  Assessing the suitability of recovering shrub biowaste involved in wildland fires in the South of Europe through torrefaction mobile units. , 2019, Journal of environmental management.

[16]  U. Rova,et al.  Lignin from Hardwood and Softwood Biomass as a Lubricating Additive to Ethylene Glycol , 2018, Molecules.

[17]  J. Marcos-Robles,et al.  Valorization of Cistus ladanifer and Erica arborea shrubs for fuel: Wood and bark thermal characterization , 2017 .

[18]  H. Pirayesh,et al.  Using almond (Prunus amygdalus L.) shell as a bio-waste resource in wood based composite , 2012 .

[19]  J. Reith,et al.  Biomass valorisation by staged degasification: A new pyrolysis-based thermochemical conversion option to produce value-added chemicals from lignocellulosic biomass , 2009 .

[20]  João A. Queiroz,et al.  Response surface optimization of enzymatic hydrolysis of Cistus ladanifer and Cytisus striatus for bioethanol production , 2009 .

[21]  G. S. Miguel,et al.  Improved fuel properties of whole table olive stones via pyrolytic processing , 2016 .

[22]  R. Santana,et al.  Structural differences between wood species: Evidence from chemical composition, FTIR spectroscopy, and thermogravimetric analysis , 2012 .

[23]  C. R. Becer,et al.  Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers , 2015, 1602.01684.

[24]  Y. Kojima,et al.  Selection criteria of Eucalyptus globulus Labill. for production of chemithermomechanical pulps (CTMP) , 2007 .

[25]  Arkadiusz Dyjakon Harvesting and baling of pruned biomass in apple orchards for energy production. , 2018 .

[26]  D. Adhikari,et al.  Biomass-based energy fuel through biochemical routes: A review , 2009 .

[27]  J. V. Dam,et al.  Gorse (Ulex europaeus) as a possible source of xylans by hydrothermal treatment , 2011 .

[28]  H. Pereira,et al.  The Variation of Chemical Composition and Pulping Yield With Age and Growth Factors in Young Eucalyptus Globulus , 2007 .

[29]  Anja Oasmaa,et al.  Fast Pyrolysis of Forestry Residue. 2. Physicochemical Composition of Product Liquid , 2003 .

[30]  H. Pereira Variability in the chemical composition of plantation eucalypts (Eucalyptus globulus Labill.) , 1988 .

[31]  Julio L. Bueno,et al.  Evaluation of Tree Species for Biomass Energy Production in Northwest Spain , 2018 .

[32]  Ramadan A. Nasser,et al.  Fuel Characteristics of Vine Prunings (Vitis vinifera L.) as a Potential Source for Energy Production , 2013 .

[33]  J. Colodette,et al.  OPTIMIZATION OF ECF BLEACHING AND REFINING OF KRAFT PULPING FROM OLIVE TREE PRUNING , 2012 .

[34]  Robert H. White EFFECT OF LIGNIN CONTENT AND EXTRACTIVES ON THE HIGHER HEATING VALUE OF WOOD , 1987 .

[35]  Ruzhu Wang,et al.  Urban biomass and methods of estimating municipal biomass resources , 2017 .

[36]  C. Ververis,et al.  Fiber dimensions, lignin and cellulose content of various plant materials and their suitability for paper production , 2004 .

[37]  A. Demirbas,et al.  Calculation of higher heating values of biomass fuels , 1997 .

[38]  M. J. Negro,et al.  Production of fuel ethanol from steam-explosion pretreated olive tree pruning , 2008 .

[39]  P. F. Trugilho,et al.  Characterization of residues from plant biomass for use in energy generation , 2011 .

[40]  M Zamorano,et al.  Analysis of the relation between the cellulose, hemicellulose and lignin content and the thermal behavior of residual biomass from olive trees. , 2013, Waste management.

[41]  J. Azevedo,et al.  Estimating the higher heating value of biomass fuels from basic analysis data , 2005 .

[42]  S. Pedrazzi,et al.  Vine prunings biomass as fuel in wood stoves for thermal power production , 2017 .

[43]  J. Parajó,et al.  Invasive biomass valorization: environmentally friendly processes for obtaining second generation bioethanol and saccharides from Ulex europæus , 2013 .

[44]  Roberto García,et al.  Characterization of Spanish biomass wastes for energy use. , 2012, Bioresource technology.

[45]  T. Sonoda,et al.  Non-destructive Determination of Wood Constituents by Fourier Transform Raman Spectroscopy , 1997 .