Performance of nano- and nonnano-catalytic electrodes for decontaminating municipal wastewater.

This research is intended to decompose organic substances in municipal wastewater with nano- and nonnano-scale electrocatalytic electrodes. As an anode, the nano-scale electrodes included lab-made TiO(2) and Cu(2)O electrodes; the nonnano-scale electrodes were a commercial TiO(2) and graphite plate. According to experimental results, the nano- and nonnano-scale catalytic electrodes can effectively remove the organic pollutants in the municipal wastewater. The perforated TiO(2) electrode is the best for eliminating the chemical oxygen demand (COD), and its efficiency is about 90% (COD decreases from 400 to 40 mg L(-1)). The conductivity of municipal wastewater and the electro-catalytic process will increase the pH and eventually remains in the neutral range. The conductivity of municipal wastewater can be lowered to some degrees. The most attractive discovery of electro-catalytic process is that the dissolved oxygen (DO) in the municipal wastewater can be increased by the TiO(2) electrode (nonnano-scale) around 4-6 mg L(-1), but few DO is produced by the nano-scale electrocatalytic electrode.

[1]  Norio Sugiura,et al.  Development of a high performance electrochemical wastewater treatment system. , 2003, Journal of hazardous materials.

[2]  M. Panizza,et al.  Electrocatalytic materials for the electrochemical oxidation of synthetic dyes , 2007 .

[3]  R. Houk,et al.  Electrochemical incineration of benzoquinone in aqueous media using a quaternary metal oxide electrode in the absence of a soluble supporting electrolyte , 1998 .

[4]  W. Verstraete,et al.  Electrochemical degradation of surfactants by intermediates of water discharge at carbon-based electrodes , 2003 .

[5]  Zucheng Wu,et al.  A novel fluidized electrochemical reactor for organic pollutant abatement , 2004 .

[6]  M. Oturan An ecologically effective water treatment technique using electrochemically generated hydroxyl radicals for in situ destruction of organic pollutants: Application to herbicide 2,4-D , 2000 .

[7]  Ying Yu,et al.  PREPARATION OF HIGHLY PHOTOCATALYTIC ACTIVE NANO-SIZE TIO2-CU2O PARTICLE COMPOSITES WITH A NOVEL ELECTROCHEMICAL METHOD , 2004 .

[8]  S. Kaul,et al.  Performance of electrochemical reactor for treatment of tannery wastewaters , 2001 .

[9]  M. Panizza,et al.  Electrochemical oxidation of phenol at boron-doped diamond electrode. Application to electro-organic synthesis and wastewater treatment. , 2001, Annali di chimica.

[10]  V. L. Rhun Electrocatalysis on nanoscale ruthenium-based material manufactured by carbonyl decomposition , 2000 .

[11]  Dennis C. Johnson,et al.  Direct electrochemical degradation of organic wastes in aqueous media , 2000 .

[12]  C. Comninellis,et al.  Anodic oxidation of phenol in the presence of NaCl for wastewater treatment , 1995 .

[13]  Wonyong Choi,et al.  Linear correlation between inactivation of E. coli and OH radical concentration in TiO2 photocatalytic disinfection. , 2004, Water research.

[14]  Giacomo Cerisola,et al.  Electrochemical treatment of wastewater containing polyaromatic organic pollutants , 2000 .

[15]  C. Bock,et al.  The Anodic Oxidation of p‐Benzoquinone and Maleic Acid , 1999 .

[16]  Lidia Szpyrkowicz,et al.  Electrochemical treatment of tannery wastewater using TiPt and Ti/Pt/Ir electrodes , 1995 .

[17]  Shengshui Hu,et al.  Characterization and electrochemical studies of Nafion/nano-TiO2 film modified electrodes , 2004 .

[18]  Edward J. Wolfrum,et al.  Application of the Photocatalytic Chemistry of Titanium Dioxide to Disinfection and the Killing of Cancer Cells , 1999 .

[19]  Liang Hong,et al.  Physicochemical and electrochemical characterization of anatase titanium dioxide nanoparticles , 2005 .

[20]  K. Palanivelu,et al.  Electrochemical treatment of industrial wastewater. , 2004, Journal of hazardous materials.