Review of Developments in Electrometallurgy 1982

Few papers appeared in 1981 on new or improved plants, reflecting the lower rate of expansion of the electrometallur­ gical industry in the late 1970s. There were some useful reviews of the state of the art, and fundamental research continued at a healthy level. The second volume of the "Comprehensive Treatise of Electrochemistry," edited by Bockris et aI., is welcome; it features two excellent chapters on electrometallurgy. Ettel and Tilak1 deal with electrolytic refining and winning in aqueous solutions, and Haupin and Frank2 discuss the electrometallurgy of aluminum. Reviews of advances in the smelting of aluminum3 and magnesium4 and the production of titanium, zirconium, and hafnium5 were presented at the U.S.A.-China Bilat­ eral Conference on metallurgy. Jacobi6 discussed recent developments and future prospects for electrolytic processes in hydrometallurgy. ELECTRO REFINING An issue of EMJ high current efficiency and low labor costs were achieved in a small conventional plant through automation and improved technology . There were significant developments and continuous prog­ ress at older existing refineries. Perry et al.9 reported the successful use of permanent stainless steel cathodes and the automatic stripping at the Copper Refinery Pty., Ltd. plant in Australia. Tobback et al.lO described the auto­ matic stripping and the handling of starting sheets at Metallurgie Hoboken Overpelt in Belgium, and Dompas et al. 11 updated their previous report on the casting of anodes with integral lugs at the same plant. McCririck12 discussed the relative merits of periodic current reversal versus direct current from the viewpoints of operating costs and capital costs for new copper refineries. Braun13 calculated the energy balance and showed its rela­ tion to the water balance in refining or electrowinning tank houses. Somers et al. 14 discussed energy conservation opportunities in copper refining facilities and their poten­ tial economic return.

[1]  N. Penazzi,et al.  Zinc Electrocrystallization from impurity-containing sulphate baths , 1982 .

[2]  D. Fray,et al.  The conductivity of aqueous zinc chloride solutions , 1982 .

[3]  C. Wan,et al.  An Experimental Study of a Packed Bed Electrode with Copper Particles , 1982 .

[4]  G. Sedahmed,et al.  Mass transfer characteristics of a novel gas-evolving electrochemical reactor , 1981 .

[5]  C. Wan,et al.  Effect of particle conductivity of a packed bed reactor on the electrowinning of copper , 1982 .

[6]  F. Coeuret The fluidized bed electrode for the continuous recovery of metals , 1980 .

[7]  V. I. Konstantinov,et al.  Cathodic processes at electrolysis of chloride—fluoride and oxyfluoride melts of niobium , 1981 .

[8]  D. C. Price,et al.  The anodic reactions of bornite in sulphuric acid solution , 1981 .

[9]  A. Bonomi,et al.  Exploratory Studies on Electrolysis of AlN Dissolved in Molten Salts , 1982 .

[10]  B. Welch,et al.  Chemical and electrochemical oxidation of heterogeneous carbon anodes , 1980 .

[11]  E. Chassaing,et al.  Electrochemical reduction of ZrCl4 in molten NaCl, CsCl and KCl-LiCl and chemical reactions coupled to the electrodeposition of zirconium , 1981 .

[12]  H. Kvande Structural species in cryolite—alumina melts as determined from vapour phase studies , 1980 .

[13]  G. Janz,et al.  Electrodeposition of tantalum and tantalum-chromium alloys , 1981 .

[14]  R. Winand,et al.  Zinc electrowinning — a comparison of adherence-reducing pretreatments for aluminium cathode blanks , 1980 .

[15]  M. Slater Extraction metallurgy '81: IMM, London, price £40 (£36 to members) , 1982 .

[16]  W. Capitaine Modernization of Aluminum Smelters by the Alusuisse Retrofit Concept , 1982 .

[17]  H. Vogt A hydrodynamic model for the ohmic interelectrode resistance of cells with vertical gas evolving electrodes , 1981 .

[18]  T. O’keefe,et al.  Evaluation of zinc sulphate electrolytes containing certain impurities and additives by cyclic voltammetry , 1980 .

[19]  D. C. Price,et al.  The electroleaching of bornite and chalcopyrite , 1980 .

[20]  Yarong Wang,et al.  Voltammetric Evaluation of Zinc Electrowinning Solution Containing Nickel , 1980 .

[21]  E. Ghali,et al.  Electrodissolution of synthetic covellite in hydrochloric acid , 1982 .

[22]  J. Mcbreen,et al.  Substrate Effects on Zinc Deposition from Zincate Solutions , 1981 .

[23]  E. Ghali,et al.  The Nature of Passivation of Lead Sulfide during Anodic Dissolution in Hydrochloric Acid , 1982 .

[24]  W. W. Harvey Material balance as the basis for process control in electrowinning and electrorefining , 1980 .

[25]  L. Janssen,et al.  Bubble behaviour on and mass transfer to an oxygen-evolving transparent nickel electrode in alkaline solution , 1981 .

[26]  W. Gumowska,et al.  Zinc, nickel and lead in copper deposited from copper(II) ammine sulphate electrolytes , 1982 .

[27]  L. Polyakova,et al.  Cathodic processes at electrolysis of chloride and chloride-fluoride melts of zirconium , 1982 .

[28]  H. Beer The Invention and Industrial Development of Metal Anodes , 1980 .

[29]  J. Mcbreen,et al.  Substrate Effects on Zinc Deposition from Zincate Solutions I . Deposition on Cu, Au, Cd and Zn , 1981 .

[30]  D. Ziegler,et al.  A preliminary investigation of some anodes for use in fluidized-bed electrodeposition of metals , 1981 .

[31]  Ralph E. White,et al.  Comprehensive Treatise of Electrochemistry , 1981 .

[32]  A. Johnson Alumina Crusting and Dissolution in Molten Electrolyte , 1982 .

[33]  H. A. Øye,et al.  Viscosity of NaF?AlF3?Al2O3 melt mixtures , 1980 .

[34]  T. Biegler,et al.  Influence of oxygen reduction in the electrowinning of zinc , 1981 .

[35]  M. Pavlović,et al.  Dendritic electrocrystallization and the mechanism of powder formation in the potentiostatic electrodeposition of metals , 1981 .

[36]  A. Storck,et al.  Improvement of copper recovery in electrochemical reactors using turbulence promoters , 1981 .

[37]  William G. Davenport,et al.  Densities, electrical conductivities and viscosities of CuSO4/H2SO4 solutions in the range of modern electrorefining and electrowinning electrolytes , 1980 .

[38]  W. Lamb,et al.  Dry Scrubbing of Aluminum Cell Gases: Design and Operating Characteristics of a Novel Gas/Solids Reactor , 1982 .

[39]  A. Ratel,et al.  Application of volumetric electrodes to the recovery of silver in sulphuric acid solutions. I. Mass transfer and electrochemical rate , 1982 .

[40]  M. Chemla,et al.  Analyse des gaz et processus reactionnels anodiques dans les bains cryolithe—alumine , 1981 .

[41]  M. C. Kuhn Process and fundamental considerations of selected hydrometallurgical systems , 1981 .

[42]  M. Wong,et al.  Ferric chloride leach-electrolysis process for production of lead. , 1980, American journal of industrial medicine.

[43]  G. Rao,et al.  Mechanism of electrodeposition of silicon from K2SiF6-flinak , 1982 .

[44]  G. Bewer,et al.  Titanium for Electrochemical Processes , 1982 .

[45]  S. Glarum,et al.  An Admittance Study of the Copper Electrode , 1981 .

[46]  M. Rolin,et al.  L'electrolyse de l'alumine dans la cryolithe fondue. Etude du mecanisme de decharge cathodique a l'aide de l'electrode a disque tournant , 1981 .

[47]  K. Scott Metal recovery using a moving-bed electrode , 1981 .

[48]  M. I. Ismail,et al.  Morphological characteristics of copper deposition on stainless steel cathodes , 1981 .

[49]  W. Haupin,et al.  Electrometallurgy of Aluminum , 1981 .

[50]  Barry J. Welch,et al.  Impact of Alternative Processes for Aluminum Production on Energy Requirements , 1981 .

[51]  G. Thorsen,et al.  Recovery of Zinc from Zinc Ash and Flue Dusts by Hydrometallurgical Processing , 1981 .

[52]  James W. Johnson,et al.  The anodic dissolution of ZnS electrodes in sulfuric acid solutions , 1982 .

[53]  G. Power The electrochemistry of the nickel sulfides—2. Ni3S2 , 1982 .

[54]  James B. Todd,et al.  Energy Reduction in Hall-Héroult Cells with Conventional and Special Electrodes , 1981 .

[55]  T. Østvold,et al.  The solubility of magnesium metal and the recombination reaction in the industrial magnesium electrolysis , 1980 .

[56]  D. Gilroy The breakdown of PbO2-Ti anodes , 1982 .

[57]  R. Keller Energy conservation in an optimized electrochemical process , 1980 .

[58]  R. Kammel,et al.  Electrolytic Recovery of Precious Metals From Dilute Solutions , 1981 .

[59]  D. Fray,et al.  The effect of additives on the morphology of zinc electrodeposited from a zinc chloride electrolyte at high current densities , 1981 .

[60]  K. Scott,et al.  Metal deposition in diaphmgmless fluidized-bed electrolytic cells , 1981 .

[61]  J. D. Cusminsky,et al.  The Influence of the Anion on Copper Electrocrystallization , 1981 .

[62]  V. I. Lakshmanan,et al.  The effects of chloride ion and organic extradants on electrowon zinc deposits , 1980 .

[63]  A. Pelton,et al.  Computer analysis of phase diagrams and thermodynamic properties of cryolite based systems: I. The AIF3-LiF-NaF system , 1980 .

[64]  Barry J. Welch,et al.  Influence of Cell Operation on Cathode Life in Aluminum Reduction , 1982 .

[65]  C. Castellano,et al.  The reaction occurring between gaseous CF4 and oxides dissolved in different molten fluorides. Some practical aspects , 1982 .

[66]  N. Penazzi,et al.  Effect of nickel impurities on zinc electrodeposition , 1980 .

[67]  M. Kolodney Preparation of the First Electrolytic Plutonium and of Uranium from Fused Chlorides , 1982 .

[68]  M. Ariel,et al.  Selective recovery of gold from spent gold sulphite solutions by electrodeposition on graphite cloth electrodes , 1982 .

[69]  B. Tilak,et al.  Electrolytic Refining and Winning of Metals , 1981 .

[70]  A. Storck,et al.  Mass transfer and pressure drop performance of turbulence promoters in electrochemical cells , 1981 .

[71]  J. Thonstad,et al.  On the migration of dissolved aluminium in NaFAlF3Al2O3 melts , 1980 .

[72]  N. Ono Sumitomo's New Process for Nickel and Cobalt Recovery from Their Sulfide Mixtures , 1979 .

[73]  C. Comninellis,et al.  The preparation and behaviour of Ti/Au/PbO2 anodes , 1982 .

[74]  Etude du dégagement anodique de chlore sur anode de graphite en milieu de sels fondus halogénés , 1982 .

[75]  M. Fleischmann,et al.  Application of the trickle tower to problems of pollution control. I. The scavenging of metal ions , 1982 .

[76]  R. Tunold,et al.  Kinetics of aluminium deposition from aluminium chloride—alkali chloride melts , 1982 .

[77]  R. Walker The role of ultrasound in the electrowinning and electro-refining of metals , 1979 .

[78]  D. J. Mackinnon,et al.  Evaluation of organic additives as levelling agents for zinc electrowinning from chloride electrolytes , 1982 .

[79]  K. Carleton,et al.  A Semipermeable Anode for Silicon Electrorefining , 1981 .

[80]  R. Feigelson,et al.  Electrowinning of Silicon from K 2SiF6 ‐ Molten Fluoride Systems , 1980 .

[81]  F. Walsh,et al.  Development of the Eco-Cascade- cell reactor , 1982 .

[82]  M. Farooque,et al.  Anodic coal reaction lowers energy consumption of metal electrowinning , 1979, Nature.

[83]  P. D. Parker,et al.  Chloride electrometallurgy : proceedings of a symposium sponsored by the Electrolytic Processes Committee of the Metallurgical Society of AIME, held at the 111th AIME annual meeting, Dallas, Texas, February 15-16, 1982 , 1982 .

[84]  R. C. Dorward Decomposition voltage for the electrolysis of alumina at low temperatures , 1982 .

[85]  N. Yao,et al.  The electrolysis of Al2S3 in AlCl3-MgCl2-NaCl-KCl melts , 1982 .

[86]  E. Ghali,et al.  Concentration effects of hydrochloric acid on the anodic behaviour of lead sulphide , 1982 .

[87]  E. Ghali,et al.  Anodic behaviour of lead sulphide in hydrochloric acid , 1980 .

[88]  M. Dubrovsky,et al.  An investigation of fluidized bed electrowinning of cobalt using 50 and 1000 Amp cells , 1982 .

[89]  Allen S. Russell,et al.  Pitfalls and pleasures in new Aluminum process development , 1981 .

[90]  S. Venkatachalam,et al.  Studies on the anodic dissolution of copper matte , 1982 .

[91]  John R. Stone,et al.  A Case Study of Energy Conservation Opportunities in Copper Refining , 1982 .

[92]  J. W. Evans,et al.  Fluidized bed electrowinning of copper; experiments using 150 ampere and 1,000 ampere cells and some mathematical modeling , 1982 .

[93]  G. Kreysa,et al.  Optimal design of packed bed cells for high conversion , 1982 .

[94]  A Mathematical model for prediction of currents, magnetic fields, melt velocities, melt topography and current efficiency in Hall-Héroult cells , 1981 .

[95]  R. Paramguru,et al.  Direct electrowinning of lead from galena concentrate anodes , 1981 .

[96]  E. Ghali,et al.  Electrodissolution de la millérite en milieu chlorhydrique , 1980 .

[97]  U. Cohen High Rate Electrodeposition of Niobium from Molten Fluorides Using Periodic Reversal Steps and the Effects on Grain Size , 1981 .

[98]  G. Kreysa Normalized space velocity—a new figure of merit for waste water electrolysis cells , 1981 .

[99]  Joe B. Rosenbaum Titanium Technology Trends , 1982 .

[100]  E. Ghali,et al.  Electrodissolution de la Heazlewoodite en milieu chlorhydrique , 1981 .

[101]  D. C. Price Application of chronopotentiometric analysis to the anodic treatment of copper sulphides , 1981 .