Direct Patterning of Oriented Metal–Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions

[*] Prof. D. E. De Vos, R. Ameloot, Dr. E. Gobechiya, Prof. J. A. Martens, Dr. L. Alaerts, Prof. B. F. Sels Department of Microbial and Molecular Systems Center for Surface Chemistry and Catalysis Katholieke Universiteit Leuven Kasteelpark Arenberg 23, B-3001 Leuven (Belgium) E-mail: Dirk.DeVos@biw.kuleuven.be Dr. H. Uji-i, Prof. J. Hofkens Department of Chemistry Katholieke Universiteit Leuven Celestijnenlaan 200F, B-3001 Leuven (Belgium)

[1]  A. Stein,et al.  Growth patterns and shape development of zeolite nanocrystals in confined syntheses. , 2009, Journal of the American Chemical Society.

[2]  O. Shekhah,et al.  Controlling interpenetration in metal-organic frameworks by liquid-phase epitaxy. , 2009, Nature materials.

[3]  F. Biscarini,et al.  Towards all-organic field-effect transistors by additive soft lithography. , 2009, Small.

[4]  C. Serre,et al.  Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal–Organic Frameworks , 2009 .

[5]  Jan Fransaer,et al.  Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis , 2009 .

[6]  A. Feldhoff,et al.  Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework , 2009 .

[7]  F. Biscarini,et al.  Nanopatterning Soluble Multifunctional Materials by Unconventional Wet Lithography , 2009 .

[8]  R. Fischer,et al.  Nanocrystals of [Cu3(btc)2] (HKUST-1): a combined time-resolved light scattering and scanning electron microscopy study. , 2009, Chemical communications.

[9]  Wenlong Cheng,et al.  Nanopatterning self-assembled nanoparticle superlattices by moulding microdroplets. , 2008, Nature nanotechnology.

[10]  Giampiero Ruani,et al.  Micro- and nanopatterning of spin-transition compounds into logical structures. , 2008, Angewandte Chemie.

[11]  Omar M. Yaghi,et al.  Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 , 2008 .

[12]  F. Kapteijn,et al.  Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina , 2008 .

[13]  F. Mertens,et al.  Proton and water activity-controlled structure formation in zinc carboxylate-based metal organic frameworks. , 2008, The journal of physical chemistry. A.

[14]  T. Bein,et al.  Directing the structure of metal-organic frameworks by oriented surface growth on an organic monolayer. , 2008, Angewandte Chemie.

[15]  S. Bernès,et al.  Trimesic acid dimethyl sulfoxide solvate: space group revision , 2008, Acta crystallographica. Section E, Structure reports online.

[16]  O. Shekhah,et al.  Step-by-step route for the synthesis of metal-organic frameworks. , 2007, Journal of the American Chemical Society.

[17]  R. Fischer,et al.  Deposition of microcrystalline [Cu3(btc)2] and [Zn2(bdc)2(dabco)] at alumina and silica surfaces modified with patterned self assembled organic monolayers: evidence of surface selective and oriented growth , 2007 .

[18]  T. Bein,et al.  Oriented growth of the metal organic framework Cu(3)(BTC)(2)(H(2)O)(3).xH(2)O tunable with functionalized self-assembled monolayers. , 2007, Journal of the American Chemical Society.

[19]  M. A. van der Veen,et al.  Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47. , 2007, Angewandte Chemie.

[20]  Yang Yang,et al.  Patterning organic single-crystal transistor arrays , 2006, Nature.

[21]  Gérard Férey,et al.  Metal-organic frameworks as efficient materials for drug delivery. , 2006, Angewandte Chemie.

[22]  K. B. Yoon,et al.  Facile monolayer assembly of fluorophore-containing zeolite rods in uniform orientations for anisotropic photoluminescence. , 2006, Angewandte Chemie.

[23]  Michael O’Keeffe,et al.  Exceptional chemical and thermal stability of zeolitic imidazolate frameworks , 2006, Proceedings of the National Academy of Sciences.

[24]  Ga‐Lai Law,et al.  A Highly Porous Luminescent Terbium–Organic Framework for Reversible Anion Sensing , 2006 .

[25]  M. Nielsen,et al.  Field-effect transistors based on self-organized molecular nanostripes. , 2005, Nano letters.

[26]  Zhongwei Chen,et al.  TEM investigation of formation mechanism of monocrystal-thick b-oriented pure silica zeolite MFI film. , 2004, Journal of the American Chemical Society.

[27]  J. Leng,et al.  Evaporation of liquids and solutions in confined geometry. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[28]  G. Calzaferri,et al.  Host-guest antenna materials. , 2003, Angewandte Chemie.

[29]  Michael O'Keeffe,et al.  Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage , 2002, Science.

[30]  George M. Whitesides,et al.  Control of crystal nucleation by patterned self-assembled monolayers , 1999, Nature.

[31]  Ian D. Williams,et al.  A chemically functionalizable nanoporous material (Cu3(TMA)2(H2O)3)n , 1999 .

[32]  George M. Whitesides,et al.  Micromolding in Capillaries: Applications in Materials Science , 1996 .

[33]  C. Kalidas,et al.  Ion-Solvation Studies of Some Substituted Copper(II) Benzoates in Water-DMSO Mixtures , 1994 .

[34]  George M. Whitesides,et al.  Structure and reactivity of alkylsiloxane monolayers formed by reaction of alkyltrichlorosilanes on silicon substrates , 1989 .

[35]  I. Persson Solvation and complex formation in strongly solvating solvents , 1986 .

[36]  I. Persson,et al.  Transfer thermodynamic study on the copper(II) ion from water to methanol, acetonitrile, dimethyl sulfoxide and pyridine , 1994 .

[37]  A. Lewandowski Ionic solvation—III. free energies of transfer of copper(II) ion from water to sulfolane, tetrahydrofuran, acetone, dioxan and dimethylsulphoxide and to their mixtures with water , 1986 .