Significant cost and energy savings opportunities in industrial three phase reactor for phenol oxidation

Abstract Energy saving is an important consideration in process design for low cost sustainable production with reduced environmental impacts (carbon footprint). In our earlier laboratory scale pilot plant study of catalytic wet air oxidation (CWAO) of phenol (a typical compound found in wastewater), the energy recovery was not an issue due to small amount of energy usage. However, this cannot be ignored for a large scale reactor operating around 140–160 °C due to high total energy requirement. In this work, energy savings in a large scale CWAO process is explored. The hot and cold streams of the process are paired up using 3 heat exchangers recovering significant amount of energy from the hot streams to be re-used in the process leading to over 40% less external energy consumption. In addition, overall cost (capital and operating) savings of the proposed process is more than 20% compared to that without energy recovery option.

[1]  Iqbal M. Mujtaba,et al.  Modelling and Optimization of Crude Oil Hydrotreating Process in Trickle Bed Reactor: Energy Consumption and Recovery Issues , 2011 .

[2]  Hamza Abdulmagid Khalfalla,et al.  MODELLING AND OPTIMISATION OF OXIDATIVE DESULPHURIZATION PROCESS FOR MODEL SULPHUR COMPOUNDS AND HEAVY GAS OIL , 2009 .

[3]  Robin Smith,et al.  Chemical Process: Design and Integration , 2005 .

[4]  Ian C. Kemp,et al.  Pinch Analysis and Process Integration: A User Guide on Process Integration for the Efficient Use of Energy , 2007 .

[5]  Aysar Talib Jarullah Lecturer Shymaa Ali Hameed Optimal Design of Ammonia Synthesis Reactor , 2013 .

[6]  Iqbal M. Mujtaba,et al.  Minimisation of fuel energy wastage by improved heat exchanger network design—an industrial case study , 2007 .

[7]  Felix Garcia-Ochoa,et al.  Study of the copper leaching in the wet oxidation of phenol with CuO-based catalysts: Causes and effects , 2005 .

[8]  Mariano Martín,et al.  Optimal Production of Dimethyl Ether from Switchgrass-Based Syngas via Direct Synthesis , 2015 .

[9]  John R. Flower,et al.  Synthesis of heat exchanger networks: II. Evolutionary generation of networks with various criteria of optimality , 1978 .

[10]  Pardeep Kumar Remediation of high phenol concentration using chemical and biological technologies , 2010 .

[11]  Aysar T. Jarullah,et al.  OPTIMAL DESIGN OF INDUSTRIAL REACTOR FOR NAPHTHA THERMAL CRACKING PROCESS , 2017 .

[12]  Iqbal M. Mujtaba,et al.  Optimal design and operation of an industrial three phase reactor for the oxidation of phenol , 2016, Comput. Chem. Eng..

[13]  Christophe Bengoa,et al.  Aqueous phase catalytic oxidation of phenol in a trickle bed reactor: effect of the pH , 1999 .

[14]  W. Luyben,et al.  Optimum Economic Design and Control of a Gas Permeation Membrane Coupled with the Hydrodealkylation (HDA) Process , 2008 .