New materials discovery for industrial applications

The rate of discovery of new zeolites and molecular sieves has increased rapidly over recent years, while the rate of introduction of new material structures into commercial applications has not paralleled this trend. This paper reviews some of the hurdles that occur between discovery and commercial implementation, as well as future enablers that are poised to accelerate both the discovery and commercialization processes.

[1]  John Meurig Thomas,et al.  Towards Rational Design of Solid Acid Catalysts , 1996 .

[2]  R. Prins,et al.  Microtopographic and molecular scale observations of zeolite surface structures: Atomic force microscopy on natural heulandite , 1996 .

[3]  S Bosnar,et al.  Mechanism and kinetics of the growth of zeolite microcrystals: Part 1: Influence of the alkalinity of the system on the growth kinetics of zeolite A microcrystals , 1999 .

[4]  Paul T. Barger,et al.  The characteristics of SAPO-34 which influence the conversion of methanol to light olefins , 1999 .

[5]  P. Jacobs,et al.  Aggregation Mechanism of Nanoslabs with Zeolite MFI-Type Structure , 1999 .

[6]  Arne Karlsson,et al.  Combinatorial Approach to the Hydrothermal Synthesis of Zeolites. , 1998, Angewandte Chemie.

[7]  Bein,et al.  Electron Microscopy Reveals the Nucleation Mechanism of Zeolite Y from Precursor Colloids. , 1999, Angewandte Chemie.

[8]  J. Rabo,et al.  Industrial catalytic applications of molecular sieves , 1992 .

[9]  Van Santen,et al.  In Situ Investigation of Si-TPA-MFI Crystallization Using (Ultra-) Small- and Wide-Angle X-ray Scattering , 1997 .

[10]  Thomas,et al.  Design, Synthesis, and In Situ Characterization of New Solid Catalysts. , 1999, Angewandte Chemie.

[11]  Tiehong Chen,et al.  Aluminium Coordinations in Zeolite Mordenite By 27Al Multiple Quantum MAS NMR Spectroscopy , 2000 .

[12]  Y. Iwasawa.  X-Ray Absorption Fine Structure for Catalysts and Surfaces , 1996 .

[13]  Chunshan Song,et al.  Shape-selective isopropylation of naphthalene over mordenite catalysts: Computational analysis using MOPAC , 1999 .

[14]  J. Hanson,et al.  In Situ Synchrotron X-ray Powder Diffraction Studies of Crystallization of Microporous Aluminophosphates and Me2+-Substituted Aluminophosphates , 1998 .

[15]  Yves Schuurman,et al.  The TAP-2 reactor as an alternative tool for investigating FCC catalysts , 1999 .

[16]  Golden,et al.  A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods , 1998, Science.

[17]  G. Froment,et al.  A TAP Reactor Investigation of C6 Reforming on Nonacidic and Acidic Supported Metal Catalysts , 1994 .

[18]  N. M. Rice,et al.  The temperature scanning reactor II: Theory of operation , 1997 .

[19]  J. Goodwin,et al.  Isotopic Transient Study of Multicomponent N2 and O2 Adsorption on CaX Zeolite , 1998 .

[20]  H. V. Bekkum,et al.  New organic chemical conversions over MCM-41-type materials , 1998 .

[21]  M. Pruski,et al.  Applications of 27Al multiple quantum magic angle spinning NMR to aluminophosphate molecular sieves , 1999 .

[22]  O. Terasaki,et al.  AFM observation of double 4-rings on zeolite LTA crystals surface , 1999 .

[23]  J D Sherman,et al.  Synthetic zeolites and other microporous oxide molecular sieves. , 1999, Proceedings of the National Academy of Sciences of the United States of America.

[24]  J. Goodwin,et al.  Characterization of Catalytic Surfaces by Isotopic-Transient Kinetics during Steady-State Reaction , 1995 .

[25]  Michael W Anderson,et al.  Crystallization in Zeolite A Studied by Atomic Force Microscopy , 1998 .

[26]  Bohdan W. Wojciechowski,et al.  The temperature scanning reactor I: Reactor types and modes of operation , 1997 .

[27]  J. Moulijn,et al.  TEOM: A Unique Technique for Measuring Adsorption Properties. Light Alkanes in Silicalite-1 , 1998 .

[28]  Douglas M. Ruthven,et al.  Diffusion in zeolites , 1995 .

[29]  J. Goodwin,et al.  Effect of Ca2+ Exchange on Adsorption of N2−O2 Mixtures by NaCaX Zeolite , 1998 .

[30]  A. Holmen,et al.  Methanol Conversion to Light Olefins over SAPO-34. Sorption, Diffusion, and Catalytic Reactions , 1999 .

[31]  Peter J.T. Verheijen,et al.  Modeling of industrial crystallizers for control and design purposes , 2000 .

[32]  Enrique Iglesia,et al.  Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts , 1997 .

[33]  Avelino Corma,et al.  From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis. , 1997, Chemical reviews.