论文信息 - A new method for the electrochemical preparation of highly crystalline poly (p-phenylene) films and their structural characterisation

A new method for the electrochemical preparation of highly crystalline poly (p-phenylene) films and their structural characterisation

Regular well-faceted crystals located on the inner side of homogeneous poly(p-phenylene) films with a relatively large degree of polymerisation have been prepared by electrochemical oxidation of benzene in concentrated H2SO4 without adding Lewis catalysts.

A. I. Danilov | E. Y. Pisarevskaya | E. B. Molodkina | M. D. Levi

[1] P. Lacaze,et al. Electropolymerization of benzene and biphenyl in organic media: Influence of different parameters (solvent, water, acidity, salt) on the formation of polyparaphenylene films (PPP) , 1989 .

[2] M. Delamar,et al. Electrosynthesis and spectroscopic characterization of poly-para-phenylene films prepared by oxidation of benzene in liquid sulfur dioxide , 1988 .

[3] G. Zotti,et al. An electroactive nickel containing polymeric film obtained by electrochemical reduction of an aryl-nickel derivative , 1984 .

[4] I. Rubinstein. Electrochemistry of Polyphenylene Films Deposited Anodically on Platinum or Glassy Carbon Electrodes in HF ‐ Benzene System , 1983 .

[5] R. Jasinski,et al. The electrochemistry of hydrocarbons in HF/SbF/sub 5/: some mechanistic conclusions concerning the super acid ''catalyzed'' condensation of hydrocarbons , 1982 .