Phosphorus removal from a real anaerobic supernatant by struvite crystallization.

In this paper the phosphorus removal from a real anaerobic supernatant through the crystallization of struvite and or hydroxyapatite was investigated. A comparison between experimental results on phosphorus crystallization carried out in a fluidized-bed reactor (FBR) on a bench-scale and on a half-scale plant is presented, together with a double saturational model able to describe all experimental results, independent of the different geometry of the reactors, the distinct contact times and the unlike products obtained. Experimental results show that removal efficiencies are very satisfactory, and the maximum phosphorus removal is of 80%.

[1]  A. H. Dirkzwager,et al.  Full-Scale Experiences with Phosphate Crystallisation in a Crystalactor , 1991 .

[2]  David Jenkins,et al.  The applied microbiology of enhanced biological phosphate removal : accomplishments and needs , 1991 .

[3]  Paolo Pavan,et al.  Struvite crystallization: a feasible and reliable way to fix phosphorus in anaerobic supernatants , 2000 .

[4]  E. Arnold,et al.  Standard methods for the examination of water and wastewater. 16th ed. , 1985 .

[5]  K. R. Reddy,et al.  Solubility of inorganic phosphorus in stream water as influenced by pH and calcium concentration , 1994 .

[6]  R. Ángel Removal of Phosphate from Sewage as Amorphous Calcium Phosphate , 1999 .

[7]  S. Kaneko,et al.  Phosphorus removal by crystallization using a granular activated magnesia clinker , 1988 .

[8]  M. Seckler,et al.  Calcium phosphate precipitation in a fluidized bed in relation to process conditions: A black box approach , 1996 .

[9]  M. Seckler,et al.  Phosphate removal in a fluidized bed—I. Identification of physical processes , 1996 .

[10]  P. Battistoni,et al.  Phosphate removal in anaerobic liquors by struvite crystallization without addition of chemicals: Preliminary results , 1997 .

[11]  D. Jenkins,et al.  Effects of MCRT on Enhanced Biological Phosphorus Removal , 1992 .

[12]  G. H. Nancollas,et al.  A ph study of calcium phosphate seeded precipitation , 1984 .

[13]  P. Battistoni,et al.  Effect of composition of anaerobic supernatants from an anaerobic, anoxic and oxic (A2O) process on struvite and hydroxyapatite formation , 1998 .

[14]  J. V. Dijk,et al.  Phosphate Removal by Crystallization in a Fluidized Bed , 1985 .

[15]  Marcelo Martins Seckler,et al.  Phosphate removal in a fluidized bed—II. Process optimization , 1996 .

[16]  J. Ferguson,et al.  Chemical processes for phosphate removal , 1971 .

[17]  A. V. Haandel,et al.  Removal of pathogenic organisms from the effluent of an upflow anaerobic digester using waste stabilization ponds , 1995 .

[18]  I. Joko Phosphorus Removal from Wastewater by the Crystallization Method , 1985 .

[19]  R. Schulze-Rettmer,et al.  The Simultaneous Chemical Precipitation of Ammonium and Phosphate in the form of Magnesium-Ammonium-Phosphate , 1991 .