Binuclear metal carbonyl DAB complexes X. Activation of h2-C=N coordinated DAB ligands towards C-C bond formation with alkynes. The X-ray structure of {2-phenyl-3-(tert-butylamino)-4-(tertbutyl-imino)-1-butene-1-yl}Ru2(CO)5. Application to the catalytic cyclotrimerization of alkynes