Nanocrystalline dye‐sensitized solar cells having maximum performance

This paper presents an overview of the research carried out by a European consortium with the aim to develop and test new and improved ways to realise dye‐sensitized solar cells (DSC) with enhanced efficiencies and stabilities. Several new areas have been explored in the field of new concepts and materials, fabrication protocols for TiO2 and scatterlayers, metal oxide blocking layers, strategies for co‐sensitization and low temperature processes of platinum deposition. Fundamental understanding of the working principles has been gained by means of electrical and optical modelling and advanced characterization techniques. Cost analyses have been made to demonstrate the potential of DSC as a low cost thin film PV technology. The combined efforts have led to maximum non‐certified power conversion efficiencies under full sunlight of 11% for areas <0ċ2 cm2 and 10ċ1% for a cell with an active area of 1ċ3 cm2. Lifetime studies revealed negligible device degradation after 1000 hrs of accelerated tests under thermal stress at 80°C in the dark and visible light soaking at 60°C. An outlook summarizing future directions in the research and large‐scale production of DSC is presented. Copyright © 2006 John Wiley & Sons, Ltd.

[1]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[2]  A. Meyer,et al.  The photovoltaic stability of, bis(isothiocyanato)rlutheniurn(II)‐bis‐2, 2′bipyridine‐4, 4′‐dicarboxylic acid and related sensitizers , 1997 .

[3]  Andreas F. Meyer,et al.  Long‐term stability of dye‐sensitised solar cells , 2001 .

[4]  K. Tennakone,et al.  Enhanced Efficiency of a Dye-Sensitized Solar Cell Made from MgO-Coated Nanocrystalline SnO2 , 2001 .

[5]  W. Warta,et al.  Solar Cell Efficiency Tables (Version 20) , 2002 .

[6]  S. Haque,et al.  Slow charge recombination in dye-sensitised solar cells (DSSC) using Al2O3 coated nanoporous TiO2 films. , 2002, Chemical communications.

[7]  Joachim Luther,et al.  Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions , 2002 .

[8]  Peng Wang,et al.  Molecular‐Scale Interface Engineering of TiO2 Nanocrystals: Improve the Efficiency and Stability of Dye‐Sensitized Solar Cells , 2003 .

[9]  Peng Wang,et al.  A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte , 2003, Nature materials.

[10]  Michael Grätzel,et al.  Enhance the Performance of Dye-Sensitized Solar Cells by Co-grafting Amphiphilic Sensitizer and Hexadecylmalonic Acid on TiO2 Nanocrystals , 2003 .

[11]  M. Spath,et al.  Dye sensitised solar cells from laboratory scale to pre-pilot stage , 2003, 3rd World Conference onPhotovoltaic Energy Conversion, 2003. Proceedings of.

[12]  P. M. Sommeling,et al.  Reproducible manufacturing of dye‐sensitized solar cells on a semi‐automated baseline , 2003 .

[13]  M. Grätzel Dye-sensitized solar cells , 2003 .

[14]  Michael Grätzel,et al.  Investigation of Sensitizer Adsorption and the Influence of Protons on Current and Voltage of a Dye-Sensitized Nanocrystalline TiO2 Solar Cell , 2003 .

[15]  Emilio Palomares,et al.  Control of charge recombination dynamics in dye sensitized solar cells by the use of conformally deposited metal oxide blocking layers. , 2003, Journal of the American Chemical Society.

[16]  W. M. Campbell,et al.  Application of metalloporphyrins in nanocrystalline dye-sensitized solar cells for conversion of sunlight into electricity. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[17]  Michael Grätzel,et al.  Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films. , 2004, Journal of the American Chemical Society.

[18]  M. Grätzel,et al.  NEW CONCEPTS AND MATERIALS FOR WORLD-CLASS DYE SENSITIZED SOLAR CELLS , 2004 .

[19]  A. Hagfeldt,et al.  Are dye-sensitized nano-structured solar cells stable? an overview of device testing and component analyses , 2004 .

[20]  G. Tulloch,et al.  Light and energy—dye solar cells for the 21st century , 2004 .

[21]  Michael Dürr,et al.  Tandem dye-sensitized solar cell for improved power conversion efficiencies , 2004 .

[22]  H. Tributsch,et al.  Dye sensitization solar cells: a critical assessment of the learning curve , 2004 .

[23]  Peng Wang,et al.  Stable New Sensitizer with Improved Light Harvesting for Nanocrystalline Dye‐Sensitized Solar Cells , 2004 .

[24]  P. M. Sommeling,et al.  Long-term stability testing of dye-sensitized solar cells , 2004 .

[25]  Emilio Palomares,et al.  Charge separation versus recombination in dye-sensitized nanocrystalline solar cells: the minimization of kinetic redundancy. , 2005, Journal of the American Chemical Society.

[26]  Peng Wang,et al.  A high molar extinction coefficient sensitizer for stable dye-sensitized solar cells. , 2005, Journal of the American Chemical Society.

[27]  Emilio Palomares,et al.  Charge transport versus recombination in dye-sensitized solar cells employing nanocrystalline TiO2 and SnO2 films. , 2005, The journal of physical chemistry. B.

[28]  Peng Wang,et al.  Stable ⩾8% efficient nanocrystalline dye-sensitized solar cell based on an electrolyte of low volatility , 2005 .

[29]  Sarmimala Hore,et al.  Scattering spherical voids in nanocrystalline TiO2- enhancement of efficiency in dye-sensitized solar cells. , 2005, Chemical communications.

[30]  P. Liska,et al.  Acid versus base peptization of mesoporous nanocrystalline TiO2 films: functional studies in dye sensitized solar cells , 2005 .

[31]  Qing Wang,et al.  Electrochemical impedance spectroscopic analysis of dye-sensitized solar cells. , 2005, The journal of physical chemistry. B.

[32]  A. Hinsch,et al.  Spatial electron distribution and its origin in the nanoporous TiO2 network of a dye solar cell. , 2005, The journal of physical chemistry. B.

[33]  Liyuan,et al.  High Efficiency of Dye-Sensitized Solar Cells , 2005 .

[34]  P. Liska,et al.  Synthesis of novel ruthenium sensitizers and their application in dye-sensitized solar cells , 2005 .

[35]  Emilio Palomares,et al.  Supermolecular control of charge transfer in dye-sensitized nanocrystalline TiO2 films: towards a quantitative structure-function relationship. , 2005, Angewandte Chemie.

[36]  Martin A. Green,et al.  Solar cell efficiency tables (version 27) , 2006 .