Reactions of chelating alkali metal amides with the Grignard reagent nBuMgCl: crystal structures and solution 1H NMR spectroscopic studies of the expected mono(amido)-product [PhCH2(Me2NCH2CH2)NMgnBu]2 and the unexpected bis(amido)-product {[Ph(2-Pyr)N]2M9 · (THF)2}

[1]  R. Boese,et al.  Heterocyclen als Liganden: XII. Synthese und Struktur von (C28H40N)MgC2H5·2C4H8O—stabilisierung eines monomeren organylmagnesiumamids durch sterische überfrachtung☆☆☆ , 1991 .

[2]  D. Baker,et al.  Isostructural potassium and sodium di-nitrogen functionalized amides: Syntheses and crystal structures of [Ph(2-Pyr)NK·TMEDA]2 and [Me(2-Pyr)NNa·TMEDA]2 , 1991 .

[3]  P. Schleyer,et al.  Structures of Organonitrogen—Lithium Compounds: Recent Patterns and Perspectives in Organolithium Chemistry , 1991 .

[4]  Robert E. Mulvey,et al.  Lewis-Basen-gesteuerte Strukturvarianten in der Natriumamid-Chemie: Röntgenstrukturanalysen von Phenyl(2-pyridyl)natriumamid-Addukten mit Hexamethylphosphorsäuretriamid und mit Pentamethyldiethylentriamin† , 1990 .

[5]  P. Andrews,et al.  Lewis‐Base‐Dictated Structural Variations in Sodium Amide Chemistry: X‐Ray Crystal Structures of Phenyl(2‐pyridyl)amidosodium with Hexamethylphosphoric Triamide (HMPA) and with Pentamethyldiethylenetriamine (PMDETA) , 1990 .

[6]  D. C. Bradley,et al.  Synthesis and chemistry of the bis(trimethylsilyl)amido bis-tetrahydrofuranates of the group 2 metals magnesium, calcium, strontium and barium. X-ray crystal structures of Mg[N(SiMe3)2]2·2THF and related Mn[N(SiMe3)2]2·2THF , 1990 .

[7]  H. Lange,et al.  Stickstoffverbindungen von Elementen der dritten Hauptgruppe mit intra- und intermolekularen Donor-Akzeptor-Bindungen. - IV : Polycyclische Alumina-, Lithia-, Magnesia- und Sodia-Silazane , 1987 .

[8]  C. Raston,et al.  Highly Hindered Amido-Lithium and Amido-Magnesium Complexes. Crystal-Structures of [Li(Mu-N(SiMe3)2)(Tetrahydrofuran)]2 and [MgBus(Mu-N(SiMe3)2)]2 , 1986 .

[9]  P. Hitchcock,et al.  “Dibutylmagnesium”, a convenient reagent for the synthesis of useful organic magnesium reagents MgA2 including cyclopentadienyls, aryloxides, and amides. Preparation of Zr(C5H5)Cl3. X-ray structure of [{μ-N(SiMe)3C6H4N}(SiMe3)-o(OEt2)]2 , 1985 .

[10]  G. D. Piero,et al.  The direct synthesis of magnesium amides and the crystal structure of an unusual magnesium tert-butylamide , 1980 .

[11]  A. Pinkus Three-coordinate magnesium , 1978 .

[12]  R. Hughes,et al.  Synthesis, stereochemistry, and bonding of tetrapyridinemagnesium(II) bis(.pi.-cyclopentadienyltricarbonylmolybdate(I-)) and related compounds , 1973 .

[13]  V. R. Magnuson,et al.  Stereochemistry of polynuclear compounds of the main group elements. 8 - The crystal structure of bis 2-dimethylaminoethyl /methyl/amino di/methylmagnesium/ , 1969 .