Multiscale Modeling and Optimization of Nanoclearcoat Curing for Energy Efficient and Quality Assured Coating Manufacturing

Nanopaint is a new type of coating material that could offer significantly improved coating performance and/or a number of new functionalities, such as super-scratch-resistance, self-healing, surface texture alteration control, and toxic chemical/acid/corrosive agent repelling. However, how to ensure the achievement of the anticipated nanocoating performance and functionalities in coating manufacturing is a great challenge. In this paper, we introduce a multiscale modeling and analysis methodology for characterizing nanoclearcoat curing in a multistage manufacturing system. The methodology provides an opportunity to gain a deep understanding of the nanocoating formation process, which involves solvent evaporation, cross-linking reaction, and film thickness change at the presence of nanoparticles in the coating layer. The information provided by the integrated model facilitates the analysis of nanocoating quality and the development of optimal operation strategies for energy efficient coating manufacturing...

[1]  S. Moradian,et al.  The Effect of Weathering on Tribological Properties of an Acrylic Melamine Automotive Nanocomposite , 2012, Tribology Letters.

[2]  Jie Xiao,et al.  Computational design of thermoset nanocomposite coatings: Methodological study on coating development and testing , 2010 .

[3]  P. Ajayan,et al.  Nanocomposite Science And Technology , 2003 .

[4]  J. L. Duda,et al.  Modeling of multicomponent drying of polymer films , 1999 .

[5]  David R. Bauer,et al.  Modeling paint and adhesive cure in automotive applications 1 This paper was presented at the 212th , 1997 .

[6]  S. Moradian,et al.  The weathering performance of acrylic melamine automotive clearcoats containing hydrophobic nanosilica , 2014, Journal of Coatings Technology and Research.

[7]  J. Vergnaud,et al.  Process of drying a polymeric paint by diffusion-evaporation and shrinkage. Determination of the concentration-dependent diffusivity , 1995 .

[8]  J. Vergnaud,et al.  Modelling of drying of coatings: Effect of the thickness, temperature and concentration of solvent , 1987 .

[9]  Wayne R. Falla,et al.  Estimating diffusion through flake-filled membranes , 1996 .

[10]  J. Vergnaud,et al.  Modeling the drying process of coatings with various layers , 1987 .

[11]  Richard A. Cairncross,et al.  Optimization of single‐zone drying of polymer solution coatings using mathematical modeling , 2000 .

[12]  M. Gu,et al.  Effects of nano-sized carborundum particles and amino silane coupling agent on the cure reaction kinetics of DGEBA/EMI-2,4 system , 2005 .

[13]  Douglas E. Hirt,et al.  A three-dimensional simulation of barrier properties of nanocomposite films , 2005 .

[14]  Stella Papasavva,et al.  Life cycle environmental assessment of paint processes , 2002 .

[15]  D. Shonnard,et al.  Assessment of the Automobile Assembly Paint Process for Energy, Environmental, and Economic Improvement , 2004 .

[16]  P. Henshaw,et al.  A model for the dehydration of waterborne basecoat , 2006 .

[17]  S. Picken,et al.  Waterborne nanocomposite resins for automotive coating applications , 2007 .

[18]  Helen H. Lou,et al.  Integrated Modeling and Simulation for Improved Reactive Drying of Clearcoat , 2000 .

[19]  B. Bilyeu,et al.  EPOXY THERMOSETS AND THEIR APPLICATIONS III . KINETIC EQUATIONS AND MODELS , 2001 .

[20]  Joachim Domnick,et al.  Investigations of the drying process of a water based paint film for automotive applications , 2011 .

[21]  Edward L Cussler,et al.  Diffusion: Mass Transfer in Fluid Systems , 1984 .

[22]  John Aurie Dean,et al.  Lange's Handbook of Chemistry , 1978 .

[23]  Mark Edward Nichols,et al.  An Overview of the Scratch Resistance of Automotive Coatings: Exterior Clearcoats and Polycarbonate Hardcoats , 2012 .

[24]  C. Manke,et al.  Computational Design of Polymer Nanocomposite Coatings: A Multiscale Hierarchical Approach for Barrier Property Prediction , 2010 .

[25]  Lingyun Zhou,et al.  Homogeneous nanoparticle dispersion prepared with impurity-free dispersant by the ball mill technique , 2013 .

[26]  C. Brooks Computer simulation of liquids , 1989 .