论文信息 - Self-association based on orthogonal C=O...C=O interactions in the solid and liquid state.

Self-association based on orthogonal C=O...C=O interactions in the solid and liquid state.

A network of orthogonal C=O...C=O interactions was identified in the X-ray crystal structure of an alpha,alpha-difluorocyclopentanone derivative. This finding inspired investigations of self-association driven by these weak dipolar interactions in apolar solvents, which was proven by (1)H NMR spectroscopy.

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